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有机合成方法学,天然产物的不对称全合成研究

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SmI2-Mediated Radical Cross-Couplings of ?-Hydroxylated Aza-Hemiacetals and N,S-Acetals with ?,?-Unsaturated Compounds: Asymmetric Synthesis of (+)-Hyacinthacine A2, (?)-Uniflorine A, and (+)-7-epi-Casuarine, Xue-Kui Liu, Shi Qiu, Yong-Gang Xiang, Yuan-Ping Ruan, Xiao Zheng,* and Pei-Qiang Huang*, J. Org. Chem. 2011, 76, 4952-4963. A New Method for the Construction of the Hydroxylated Tropane Skeleton: Asymmetric Synthesis of (?)-Bao Gong Teng A, Geng-Jie Lin, Xiao Zheng and Pei-Qiang Huang*, Chem. Commun. 2011, 1545-1547. Concise syntheses of two advanced intermediates for the asymmetric synthesis of polyhydroxylated indolizidine alkaloids, Xiao Zheng, Wen-Fang Zhu, Pei-Qiang Huang *, Sci. China Ser. B-Chem. 2010, 53, 1914-1920. Samarium diiodide-mediated reductive couplings of chiral nitrones with aldehydes/ketones and acyl chlorides, Shao-Feng Wu, Yuan-Ping Ruan, Xiao Zheng, Pei-Qiang Huang *, Tetrahedron 2010, 66 (9), 1653-1660. One-pot cross-coupling of N-acyl N,O-acetals with ?,?-unsaturated compounds, Yong-Gang Xiang, Xiang-Wu Wang, Xiao Zheng,* Yuan-Ping Ruana and Pei-Qiang Huang*, Chem. Commun. 2009, 7045–7047. Generation and a-Hydroxyalkylation of a Novel 3-Piperidinol N-a-Carbanion Intermediate, Xiao Zheng, * Guo Chen, Yuan-Ping Ruan,* and Pei-Qiang Huang, Sci. China Ser. B-Chem. 2009, 52, 1631-1638. A new approach to 3-hydroxyprolinol derivatives by samarium diiodide-mediated reductive coupling of chiral nitrone with carbonyl compounds, Shao-Feng Wu, Xiao Zheng,* Yuan-Ping Ruan and Pei-Qiang Huang,* Org. Biomol. Chem. 2009, 7, 2967–2975. Facile Syntheses of Three Ahp-type Building Blocks with Complementary Reactivities, Wen Chen, Xiao Zheng, Yuan-Ping Ruan, and Pei-Qiang Huang,* Heterocycles 2009, 79, 681-693.

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