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个人简介

厦门大学教授(2007.9 - ) 美国科罗拉多州立大学(Colorado State University), 化学系博士后 (2005.11 - 2007.8) 德国哥廷根大学(Goettingen University), 无机化学学院博士后 (2005.7 - 2005.10) 中科院福建物质结构研究所, 助理研究员 (1998.11 - 2001.9) 中科院福建物质结构研究所, 研究实习员 (1992.8 - 1995.4) 德国哥廷根大学博士(2005) 中科院福建物质结构研究所硕士(1998) 厦门大学学士(1992)

研究领域

金属有机合成化学; 金属有机官能团反应化学; 烯烃,官能团烯烃,环氧化物,环己内酯等有机单体的聚合催化; 聚合催化反应动力学; 聚合催化反应机理。

近期论文

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Zhu, H.; Chen, E.Y.-X.* “Group 13 and Lanthanide Complexes Supported by Tridentate Tripodal Triamine Ligands: Structural Diversity and Polymerization Catalysis”, Organometallics 2007, 26, 5395-5405. Zhu, H.; Chen. E.Y.-X.* “Tripodal Amido Boron and Aluminum Complexes”, Inorg. Chem., 2007, 46, 1481-1487. Zhu, H.; Oswald, R.B.; Fan, H.; Roesky, H.W.;* Ma, Q.; Yang, Z.; Schmidt, H.-G.; Noltemeyer, M.; Starke, K.; Hosmane, N. S. “Aluminacyclopropene: Syntheses, Characterization, and Reactivity toward Terminal Alkynes”, J. Am. Chem. Soc., 2006, 128(15), 5100-5108. Zhu, H.; Yang, Z.; Magull, J.; Roesky, H.W.;* Schmidt, H.-G.; Nltemeyer, M. “Syntheses and Structural Characterization of a LAl(N3)N[mu-Si(N3)(tBu)]2NAl(N3)L and a Monomeric Aluminum Hydride Amide LAlH(NHAr) (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3)”, Organometallics, 2005, 24(26), 6420 – 6425. . Zhu, H.; Chai, J.; Jancik, V.; Roesky, H. W.;* Merrill W. A.; Power, P. P. “The Selective Preparation of an Aluminum Oxide and Its Isomeric C-H-activated Hydroxide”, J. Am. Chem. Soc., 2005, 127(29), 10170-10171. Zhu, H.; Chai, J.; Fan, H.; Roesky, H. W.;* He, C.; Jancik, V.; Schmidt, H.-G.; Noltemeyer, M.; Merrill, W. A.; Power, P. P. “A Stable Aluminacyclopropene LAl(η2-C2H2) and Its End-on Insertion of Azide to Aluminaazocyclobutene”, Angew. Chem., Int. Ed., 2005, 44(32), 5090-5093. Zhu, H.; Chai, J.; Fan, H.; Roesky, H. W.;* Umesh, N.; Schmidt, H.-G.; Noltemeyer, M. “A Rearrangement of Azobenzene by Interaction with Aluminum(I) Monomer LAl (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3)”, Eur. J. Inorg. Chem., 2005, (11), 2147-2150. Zhu, H.; Chai, J.; He, C.; Roesky, H. W.;* Jancik, V.; Schmidt, H.-G.; Noltemeyer, M. “The Stepwise Hydrolysis of Aluminum Chloride Iodide LAlClI (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) in the Presence of N-heterocyclic Carbene”, Organometallics, 2005, 24(3), 380-384. Zhu, H.; Chai, J.; Stasch, S.; Roesky, H. W.;* Blunk, T.; Vidovic, D.; Magull, J.; Schmidt, H.-G.; Noltemeyer, M. “Reactions of Aluminum(I) Monomer LAl (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) with Imidazol-2-ylidene and Diphenyldiazomethane. A Hydrogen Transfer of the L Ligand to the Central Aluminum Atom and a Formation of a Diiminyl Aluminum Compound LAl(N=CPh2)2”, Eur. J. Inorg. Chem. , 2004, (20), 4046-4051. Zhu, H.; Chai, J.; Ma, Q.; Jancik, V.; Roesky, H. W.;* Fan, H.; Herbst-Irmer, R. “A Seven-Membered Aluminum Sulfur Allenyl Heterocycle Arising from the Conversion of an Aluminacyclopropene with CS2”, J. Am. Chem. Soc., 2004, 126(33), 10194-10195. Zhu, H.; Chai, J.; Chandrasekhar, V.; Roesky, H. W.;* Magull, J.; Vidovic, D.; Schmidt, H.-G.; Noltemeyer, M.; Power, P. P.; Merrill, W. A. “Two Types of Intramolecular Addition of an Al-N Multiple-Bonded Monomer LAlNAr' Arising from the Reaction of LAl with N3Ar' (L = HC[(CMe)(NAr)]2, Ar' = 2,6-Ar2C6H3, Ar = 2,6-iPr2C6H3)”, J. Am. Chem. Soc., 2004, 126(31), 9472-9473. Zhu, H.; Chai, J.; Roesky, H. W.;* Noltemeyer, M.; Schmidt, H.-G.; Vidovic, D.; Magull, J. “A bulky chelating diamidoaluminum monohydride: synthesis, structure and reactions with Me3SnF and heavy group 16 elements”, Eur. J. Inorg. Chem., 2003, (17), 3113-3119. Zhu, H.; Chen, C.; Zhang, X.; Liu, Q.;* Liao, D.; Li, L. “Several aggregates of V2O2(mu-S)2 units: Syntheses, structures and properties of (Et4N)3{[V2S2O2(Et2dtc)2]2K}, (Et4N)2(NH4){[V2S2O2(C5H10dtc)2]2Na}, and (Et4N)3{[V2S2O2(Me2dtc)2]3Na3(H2O)} (dtc = dithiocarbamate)”. Inorg. Chim. Acta, 2002, 328, 96-104. Garner, L.E.; Zhu, H.; Hlavinka, M.L.; Hagadorn, J.R.; Chen, E. Y.-X.* “Cationic Zinc Enolates as Highly Active Catalysts for Acrylate Polymerization”, J. Am. Chem. Soc., 2006, 128, 14822-14823. Chai, J.; Zhu, H.; Stückl, A. C.; Roesky, H. W.;* Magull, J.; Bencini, A.; Caneschi, A.; Gatteschi, D. “Synthesis and Reaction of[{HC(CMeNAr)2}Mn]2 (Ar = 2,6-iPr2C6H3): the First Complex Containing Three-coordinate Manganese(I) with a Mn-Mn Bond Exhibiting Unusual Magnetic Properties and Electronic Structure”, J. Am. Chem. Soc. 2005, 127(25), 9201-9206. Chai, J.; Jancik, V.; Singh, S.; Zhu, H.; Roesky, H. W.;* Schmidt, H.-G.; Noltemeyer, M.; Hosmane, N. S. “Synthesis of a New Class of Compounds Containing a Ln-O-Al Arrangement and Their Reactions and Catalytic Properties”, J. Am. Chem. Soc., 2005, 127(20), 7521-7528. Peng, Y.; Fan, H.; Zhu, H.; Roesky, H. W.;* Magull, J.; Hughes, C. E. “[{HC(CMeNAr)2}2Al2P4] (Ar = 2,6-iPr2C6H3): A reduction to a formal {P4}4- charged species”, Angew. Chem. Int. Ed., 2004, 43(26), 3443-3445. Chai, J.; Zhu, H.; Roesky, H. W.;* Yang, Z.; Jancik, V.; Herbst-Irmer, R.; Schmidt, H.-G.; Noltemeyer, M. “Synthesis and Structure of Allyl and Alkynyl Complexes of Manganese(II) Supported by a Bulky Diketiminate Ligand”, Organometallics, 2004, 23(21), 5003-5006. Chai, J.; Zhu, H.; Roesky, H. W.;* He, C.; Schmidt, H.-G.; Noltemeyer, M. “Synthesis, Structure, and Reactivity of Diketiminate Complexes of Manganese(II)”, Organometallics, 2004, 23(13), 3284-3289. Chai, J.; Zhu, H.; Fan, H.; Roesky, H. W.;* Magull, J. “Structurally Characterized Neutral Monoalkyl and -aryl Complexes of Manganese(II)”, Organometallics, 2004, 23(6), 1177-1179.

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