关正辉 - 西北大学 - 化学与材料科学学院

个人简介

关正辉，西北大学二级教授，博士生导师，获国家基金委“优青”基金资助，入选国家高层次人才特支计划，获得中国化学会青年化学奖、全国优秀博士学位论文提名奖、中科院“西部之光”访问学者、陕西省技术发明奖一等奖等荣誉，为中共陕西省“羰基化合成”三秦英才创新团队带头人、陕西省羰基化合成创新团队带头人、陕西高校一碳化学转化创新团队带头人、陕西省优秀博士学位论文指导教师。获得兰州大学学士学位，兰州大学和美国Rutgers University 联合培养理学博士学位。2011年被遴选为博士生导师；现已在JACS、Angew. Chem.、CCS Chemistry、Science Bulletin、Science China Chemistry、ACS Catalysis 等国际著名期刊发表论文100余篇，授权国家发明专利6项。关正辉教授获得西北大学优秀教师、西北大学优秀共产党员、陕西省青年科技新星、首届陕西化学优秀青年奖、Thieme Chemistry Journal Award、西北大学优秀研究生学位论文指导教师，陕西高校科学技术奖一等奖等奖励和荣誉。现任《化学学报》编委，陕西省化学会理事。指导的研究生中，有多名研究生获得陕西省优秀博士学位论文、西北大学优秀博士学位论文、西北大学优秀硕士学位论文，多名研究生在学期间获得研究生国家奖学金；指导的博士生Usman获得中国政府优秀来华留学生奖学金和西北大学“国际学生之星——学习之星”。

研究领域

有机合成，不对称催化，羰基化反应等；有机光电功能材料（OLED材料）、高分子材料的合成与应用，人工智能材料、柔性机器人

近期论文

查看导师新发文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

A Light-responsive Poly(urethane-urea) Actuator with Room Temperature Self-Healing Performance. Zhishuai Cui, Xiaolei Yue, Yucheng Wang, Yujie Zhang, Zhi-Hui Ren, Zheng-Hui Guan*, Chemical Engineering Journal, 2024, 479, 147538. Palladium-catalyzed regiodivergent hydrochlorocarbonylation of alkenes for formation of acid chlorides. Fei Wu, Bo Wang, Na-Qi Li, Hui-Yi Yang, Zhi-Hui Ren, Zheng-Hui Guan*, Nature Communications, 2023, 14, 3167. C(alkyl)–C(vinyl) bond cleavage enabled by Retro-Pallada-Diels-Alder reaction Qing-Yang Zhao, Le Yu, Yao-Du Zhang, Yong-Qiang Guo, Ming Chen, Zhi-Hui Ren， Zheng-Hui Guan*, Nature Communications, 2023, 14, 2572. Three birds with one stone: Design and synthesis of polyurethane actuator for executing heat, light and humidity triggered deformation. Xiaolei Yue, Chen Dong, Yucheng Wang, Zhishuai Cui, Zhi-Hui Ren, Zheng-Hui Guan *, Chemical Engineering Journal 2023, 457, 141290. Synthesis of Self-healing and Light-, Thermal-, and Humidity-induced Deformative Polyurethane Actuator. Chen Dong, Xiao-lei Yue, Yao-du Zhang, Yu-cheng Wang, Zhi-Hui Ren, Zheng-Hui Guan*, Macromolecular Rapid Communications, 2023, 44, 2300281. Copper-Catalyzed Synthesis of β-Alkynyl Ketones from Propargylic Alcohols and Enamides. Yu-cheng Wang, Bo Wang, Zhi-hui Ren, Zheng-Hui Guan*, Asian Journal of Organic Chemistry, 2023, 12, e2023000. Enantioselective Palladium-Catalyzed Domino Carbonylative Heck Esterification of o-Iodoalkenylbenzenes with Arylboronic Acids. Yao-Du Zhang, Ming Chen, Yang Li, Bo-Wen Liu, Zhi-Hui Ren, Zheng-Hui Guan*, Organic Letters, 2023, 25, 45, 8110–8115. Palladium-Catalyzed Hydroalkoxycarbonylation and Hydroxycarbonylation of Cyclopent-3-en-1-ols: Divergent Synthesis of Bridged Cyclic Lactones and β,γ-Unsaturated Carboxylic Acids. Ming Chen, Yang Li, Zheng-Hui Guan*, Organic Letters, 2023, 25, 15, 2571–2576. Palladium-Catalyzed 3,4-Hydroaminocarbonylation of Conjugated Dienes for Formation of β,γ-Unsaturated Amide. Hui-Yi Yang, Liang-Quan Lin, Na-Qi Li, Zhi-Hui Ren, Zheng-Hui Guan *, Sci. China Chem. 2023, 66, 1474-1481. Postsynthetically modified hydrophobic covalent organic frameworks for enhanced oil/water and CH4/C2H2 separation. Yucheng Wang, Jingshen Xie, Zhi-Hui Ren, Zheng-Hui Guan *, Chemical Engineering Journal 2022, 448, 137687. Highly Enantioselective Three-Component Povarov Reaction for Direct Construction of Azaspirocycles. Nan-Fang Mo, Ying Zhang, and Zheng-Hui Guan*, Org. Lett. 2022, 24, 6397−6401. endo-5-Norbornene-2,3-dimethanol-promoted asymmetric Heck/Suzuki cascade reaction of N-(2-bromophenyl)acrylamides. Ming Chen, Xing-Xing Xu, Xucai Wang, Zhi-Hui Ren and Zheng-Hui Guan*, Org. Chem. Front. 2022, 9, 5557-5563. Palladium-Catalyzed Markovnikov Hydroaminocarbonylation of 1,1-Disubstituted and 1,1,2-Trisubstituted Alkenes for Formation of Amides with Quaternary Carbon. Hui-Yi Yang, Ya-Hong Yao, Ming Chen, Zhi-Hui Ren, and Zheng-Hui Guan*, J. Am. Chem. Soc. 2021, 143 (19), 7298−7305. Asymmetric Markovnikov Hydroaminocarbonylation of Alkenes Enabled by Palladium-Monodentate Phosphoramidite Catalysis. Ya-Hong Yao, Hui-Yi Yang, Ming Chen, Fei Wu, Xing-Xing Xu, and Zheng-Hui Guan*, J. Am. Chem. Soc. 2021, 143 (1), 85-91. Palladium-Catalyzed Asymmetric Markovnikov Hydroxycarbonylation and Hydroalkoxycarbonylation of Vinyl Arenes: Synthesis of 2-Arylpropanoic Acids, Ya-Hong Yao, Xian-Jin Zou, Yuan Wang, Hui-Yi Yang, Zhi-Hui Ren, and Zheng-Hui Guan* Angew. Chem. Int. Ed. 2021, 60, 23117–23122. Palladium-Catalyzed Asymmetric Domino Heck/Carbocyclization/Suzuki Reaction: A Dearomatization of Nonactivated Naphthalenes. Ming Chen, Xucai Wang, Zhi-Hui Ren, and Zheng-Hui Guan*, CCS Chem. 2021, 3, 69-77. Rhodium-Catalyzed Enantioselective and Desymmetrizative Pauson−Khand Reaction: Access to Tricyclo[6.2.1.04,11]undecenes. Pengfei Yang, Yaodu Zhang, Ming Chen, Qingyang Zhao, Zhi-Hui Ren, Zheng-Hui Guan*, Org. Lett. 2021, 23, 9241−9245. Asymmetric Spirocyclization Enabled by Iridium and Brønsted Acid-Catalyzed Formal Reductive Cycloaddition. Nan-Fang Mo, Le Yu, Ying Zhang, Ya-Hong Yao, Xun Kou, Zhi-Hui Ren, Zheng-Hui Guan*, CCS Chem. 2020, 2, 1775-1786. Palladium-Catalyzed Enantioselective Heck Carbonylation with a Monodentate Phosphoramidite Ligand: Asymmetric Synthesis of (+)-Physostigmine, (+)-Physovenine, and (+)-Folicanthine. Ming Chen, Xucai Wang, Pengfei Yang, Xun Kou, Zhi-Hui Ren, Zheng-Hui Guan*, Angew. Chem. Int. Ed., 2020, 59, 12199-12205 (Hot Paper). IBX-Promoted Oxidative Cyclization of N-Hydroxyalkyl Enamines: A Metal-Free Approach toward 2,3-Disubstituted Pyrroles and Pyridines. Peng Gao*, Huai-Juan Chen, Zi-Jing Bai, Mi-Na Zhao, Desuo Yang, Juan Wang*, Ning Wang, Lele Du, and Zheng-Hui Guan*, J. Org. Chem., 2020, 85, 7939–7951. A Rh(III)-Catalyzed Regioselective Intermolecular oxa-Pauson-Khand Reaction of Alkynes, Arylboronic Acids and CO to form Butenolides. Mi-Na Zhao, Ying Zhang, Ning Ge, Le Yu, Shun Wang, Zhi-Hui Ren, Zheng-Hui Guan*, Org. Chem. Front., 2020, 7, 763-767. Copper-Catalyzed Asymmetric Dearomative Alkynylation of Isoquinolines. Xun Kou, Qingyang Zhao, Zheng-Hui Guan*, Org. Chem. Front., 2020, 7, 829-833. 炔基吡喃酮的环异构化合成酚类化合物（亮点评述）, 关正辉*，祝海涛，有机化学，2020, 40, 1398～1399. Palladium-Catalyzed 5-Exo-trig Hydroamidation of β,γ-Unsaturated Hydrazones for Synthesis of Dihydropyrazoles. Xucai Wang, Ming Chen, Wei Zhang, Yao-Du Zhang, Zhi-Hui Ren, Zheng-Hui Guan*, 有机化学, 2020, 40, 1618-1624. Application of dialkyl azodicarboxylate frameworks featuring multi-functional properties. Muhammad Usman, Xiao-Wen Zhang, Di Wu, Zheng-Hui Guan* and Wen-Bo Liu*, Org. Chem. Front., 2019, 6, 1905-1928. Synthesis of 2,3-Diaryl-2H-azirines via Cs2CO3-Mediated Cyclization of Ketoxime Acetates. Mi-Na Zhao, Zheng-Hui Guan*, Org. Synth., 2019, 96, 66-79 Palladium-Catalyzed Oxidative Cyclopropanation of Enamides and Norbornenes Initiated by C-H Activation. Ming Chen, Mi-Na Zhao, Yao-Du Zhang, Zhi-Hui Ren, Zheng-Hui Guan*, Science China: Chem, 2018, 61: 695-701 (Cover Page). K2S2O8/TEMPO-Induced Cascade Oxidative Cyclization/1,2-Migration of Electron-Deficient Groups: Strategy for the Construction of 1H‑Pyrrol-2(3H)‑ones. Peng Gao, Juan Wang, Zijing Bai, Ming-Jin Fan, De-Suo Yang, Zheng-Hui Guan*, Org. Lett. 2018, 20, 3627−3630. Copper-Promoted 6-endo-trig Cyclization of β,γ-Unsaturated Hydrazones for the Synthesis of 1,6-Dihydropyridazines. Yong-Qiang Guo, Mi-Na Zhao, Zhi-Hui Ren, Zheng-Hui Guan*, Org. Lett., 2018, 20, 3337-340. Copper-Catalyzed Oxidative Cyclization/1,2-Amino Migration Cascade Reaction. Mi-Na Zhao, Zhi-Jing Zhang, Zhi-Hui Ren, De-Suo Yang, Zheng-Hui Guan*, Org. Lett., 2018, 20, 3088-3091. Iron-Catalyzed Radical Cycloaddition of 2H-Azirines and Enamides for the Synthesis of Pyrroles. Mi-Na Zhao, Zhi-Hui Ren, De-Suo Yang, Zheng-Hui Guan*, Org. Lett., 2018, 20, 1287-1290. Modular 2,3-diaryl-2H-azirine synthesis from ketoxime acetates via Cs2CO3-mediated cyclization. Mi-Na Zhao, Wei Zhang, Xu-Cai Wang Ying Zhang, De-Suo Yang, Zheng-Hui Guan*, Org. Biomol. Chem., 2018, 16, 4333-4337. Palladium-Catalyzed Regioselective Cyclocarbonylation of N-(3-Phenylprop-2-ynyl)anilines with Carbon Monoxide and Alcohols for the Synthesis of Quinoline-3-carboxylic Esters. Wei Zhang, Mi-Na Zhao, Ming Chen, Zhi-Hui Ren, Zheng-Hui Guan*, Asian J. Org. Chem., 2018, 7, 1605-1608.