邵黎雄 - 温州大学 - 化学与材料工程学院

研究领域

氮杂环卡宾-钯络合物的合成及其在芳基氯化物参与的C-C和C-N偶联反应中的应用。

近期论文

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Ji, Ya-Yun; Lu, Li-Li#; Shi, Yu-Chun#; Shao, Li-Xiong* Direct C-H Bond Arylation of Fluorenes with Aryl Chlorides Catalyzed by N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex and Further Transformation of the Products in A One-Pot Procedure. Org. Biomol. Chem. 2014, 12, 8488-8498. (#These two authors contributed equally.) Gu, Zheng-Song; Chen, Wen-Xin; Shao, Li-Xiong* N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex-Catalyzed Direct C-H Bond Arylation of (Benz)imidazoles with Aryl Chlorides. J. Org. Chem. 2014, 79, 5806-5811. Shen, Xiao-Bao; Zhang, Yun; Chen, Wen-Xin; Xiao, Zheng-Kang; Hu, Ting-Ting; Shao, Li-Xiong* Direct C-H Bond Arylation of (Benzo)oxazoles with Aryl Chlorides Catalyzed by N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex. Org. Lett. 2014, 16, 1984-1987. Chen, Wen-Xin; Zhang, Cai-Yun; Shao, Li-Xiong* Base-promoted N-alkylation using formamides as the N-sources in neat water. Tetrahedron 2014, 77, 880-885. Yin, Hui-Ying; Liu, Meng-Yuan; Shao, Li-Xiong* Two-component, Three-molecule Reactions between 2,3-Dihydroinden-1-ones and Aryl Chlorides Catalyzed by N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex. Org. Lett. 2013, 15, 6042-6045. Wang, Zhan-Yong; Ma, Qin-Na; Li, Ren-Hao; Shao, Li-Xiong* Palladium-catalyzed Suzuki-Miyaura coupling of aryl sulfamates with arylboronic acids. Org. Biomol. Chem. 2013, 11, 7899-7906. Xiao, Zheng-Kang; Yin, Hui-Ying; Shao, Li-Xiong* N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex Catalyzed alfa-Arylation of Oxindoles with Aryl Chlorides and Aerobic Oxidation of the Products in A One-Pot Procedure. Org. Lett. 2013, 15, 1254-1257. Shi, Min*; Lu, Jian-Mei, Wei, Yin; Shao, Li-Xiong* Rapid generation of molecular complexity in the Lewis or Br?nsted acid-mediated reactions of methylenecyclopropanes. Acc. Chem. Res. 2012, 45, 641-652. Wang, Zhan-Yong; Chen, Gao-Qi; Shao, Li-Xiong* N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex Catalyzed Suzuki-Miyaura Coupling of Aryl Sulfonates with Arylboronic Acids. J. Org. Chem. 2012, 77, 6608-6614. Chen, Wen-Xin; Shao, Li-Xiong* N-Heterocyclic Carbene-Palladium(II)-1-Methylimidazole Complex Catalyzed Amination between Aryl Chlorides and Amides. J. Org. Chem. 2012, 77, 9236-9239. Gao, Ting-Ting; Jin, Ai-Ping; Shao, Li-Xiong* N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed Mizoroki-Heck reaction of aryl chlorides with styrenes. Beilstein J. Org. Chem. 2012, 8, 1916-1919. Zhu, Lei; Ye, Yue-Mei; Shao, Li-Xiong* Well-defined NHC-Pd(II)-Im (NHC = N-heterocyclic carbene; Im = 1-methylimidazole) complex catalyzed C-N coupling of primary amines with aryl chlorides. Tetrahedron 2012, 68, 2414-2420. Xiao, Zheng-Kang; Shao, Li-Xiong* NHC-Pd(II)-Im (NHC = N-heterocyclic carbene; Im = 1-methylimidazole) complex catalyzed alfa-arylation of ketones with aryl chlorides. Synthesis 2012, 44, 711-716. Tang, Yi-Qiang; Chu, Chun-Yan; Zhu, Lei; Qian, Bin; Shao, Li-Xiong* N-Heterocyclic carbene-Pd(II) complex derived from proline for the Mizoroki-Heck reaction in water. Tetrahedron 2011, 67, 9479-9483. Zhu, Lei; Gao, Ting-Ting; Shao, Li-Xiong* Well-defined NHC-Pd(II)-Im (NHC = N-heterocyclic carbene; Im = 1-methylimidazole) complexes catalyzed amination of aryl chlorides. Tetrahedron 2011, 67, 5150-5155. Zhou, Xia-Xia; Shao, Li-Xiong* N-Heterocyclic carbene/Pd(II)/1-methylimidazole complex catalyzed Suzuki-Miyaura coupling reaction of aryl chlorides in water. Synthesis 2011, 3138-3142. Tang, Yi-Qiang; Lu, Jian-Mei; Shao, Li-Xiong* NHC-Pd(II)-Im (NHC = N-heterocyclic carbene; Im = 1-methylimidazole) complexes as efficient catalysts for Suzuki-Miyaura coupling reactions of aryl chlorides at room temperature. J. Organomet. Chem. 2011, 696, 3741-3744. Shen, Xiao-Bao; Gao, Ting-Ting; Lu, Jian-Mei; Shao, Li-Xiong* Imidazole-coordinated monodentate NHC-Pd(II) complex derived from proline and its application towards the coupling reaction of arylboronic acids with carboxylic acid anhydrides in water at room temperature. Appl. Organometal. Chem. 2011, 25, 497-501. Tang, Yi-Qiang; Lv, Huan; Lu, Jian-Mei; Shao, Li-Xiong* Palladium(II)-N-heterocyclic carbene complex derived from proline towards Suzuki-Miyaura coupling reaction in water at room temperature. J. Organomet. Chem. 2011, 696, 2576-2579. Tang, Yi-Qiang; Lv, Huan; He, Xiao-Na; Lu, Jian-Mei; Shao, Li-Xiong* N-Heterocyclic Carbene-Rhodium(I) Complexes Derived From Proline for the 1,4-Conjugate Addition of Arylboronic Acids to Enones in Neat Water. Catal. Lett. 2011, 141, 705-708.