近期论文
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"Enantioselective Synthesis of CF3S-containing Compounds via Ir-Catalyzed Allylic Alkylations of CF3S-substituted Functionalized Methylene Derivatives" Tao Song, Xiaoming Zhao*, Xiaolin Wang The Journal of Organic Chemistry,2019, 84, 15648-15654.
"Chemoselective, Regioselective and Enantioselective Allylations of NH2OH under Ir Catalysis", Jiteng Chen, Qingchun Liang,Xiaoming Zhao* Organic Letters,2019, 21, 5383-5386 (Selected as supplementary cover and reproted by CBG资迅).
"Selectfluor-promoted regioselective chlorination/bromination of 2-aminopyridines and 2-aminodiazines using LiCl/LiBr", Jiao Hu, Gang Zhou, Yawei Tian,Xiaoming Zhao*, Organic & Biomolecular Chemistry,2019, 17, 6342-6345.
"Enantioselective copper-catalyzed desymmetrization of 1,3-diketones involving borylation of styrenes", Purui Zheng, Xioyu Han, Jiao Hu,Xiaoming Zhao*, Tao XU* Organic Letters,2019, 21, 6040-6044.
"Ag-catalyzed selective fluorination of 6-substituted 2-aminopyrazines" Yawei Tian, Mingzhu Zhao,Xiaoming Zhao*, Gang Zhou Journal of Fluorine Chemistry,2019, 218, 111-115.
"Silver-promoted selective fluorination of 2-aminopyrimidines: synthesis of 5-fluoro 2-aminopyrimidine derivatives", Mingzhu Zhao, Juewang Cai,Xiaoming Zhao* Organic Chemistry Frontiers,2019, 6, 426-431 (Selected as Front Cover).
"Palladium-catalyzed cross-coupling of gem-bis(boronates) with aryl halides: an alternative to access quaternary a-aryl aldehydes", Purui Zheng, Yujie Zhai,Xiaoming Zhao*, and Tao XU* Organic Letters,2019, 21, 393-396.
"Selective Fluorination of 4-Substituted 2-Aminopyridines and Pyridin-2(1H)-ones in Aqueous Solution", Gang Zhou, Yawei Tian,Xiaoming Zhao*, Jiao Hu, Wenyan Dan, Organic Letters,2018, 20, 4858-4861.
"Difunctionalization of ketones via gem-bis(boronates) to synthesize quaternary carbon with high selectivity", Purui Zheng, Yujie Zhai,Xiaoming Zhao*, Tao XU* Chemical Communications,2018, 54, 13375-13378.
"Selective fluorination of 2-aminopyrazine derivatives in aqueous phase", Yawei Tian, Gang Zhhou,Xiaoming Zhao*, Wenyan Dan, Acta Chim. Sinica,2018, 76, 962-966 (Invited paper).
"Diastereoselective and Enantioselective Palladium-Catalyzed Allylic Substitution of Substituted Fluorinated Methylene Derivatives", Tao Song,Xiaoming Zhao*, Jiao Hu, Wenyan Dan, European Journal of Organic Chemistry,2018, 9, 1141-1144 (Highlighted as Outstanding Organics).
"Diasteroselective and enantioselective Ir-catalyzed allylic substitutions of 1-substituted 1-fluoro-1-(arenesulfonyl)methylene derivatives", Jiteng Chen,Xiaoming Zhao*, Wenyan Dan The Journal of Organic Chemistry,2017, 82, 10693-10698.
"Ag-assisted fluorination of unprotected 4,6-disubstituted 2-aminopyrimidines with Selectfluor" , Chenxi Wang, Juewang Cai, Min Zhang, andXiaoming Zhao*, The Journal of Organic Chemistry,2017, 82, 1260-1265.
"Cu-mediated oxidative trifluoromethylthiolation of arylboronic acids with (bpy)CuSCF3", Mingzhu Zhao,Xiaoming Zhao*, Purui Zheng, Yawei Tian Journal of Fluorine Chemistry,2017, 194, 73-79.
"Chiral Sulfinamide Ligands, Pd-Catalyzed Asymmetric Allylic Alkylations Of Ethyl 2-Fluoroacetoacetate", Mingzhu Zhao,Xiaoming Zhao*, Yawei Tian Synlett,2017, 28, 1801-1806.
"Chiral carbon–sulfur center formation via Pdcatalyzed asymmetric allylic thioetherification: synthesis of allylic thioethers", Junmei Cai, Juewang Cai, Purui Zheng, Xiaorong Wang* andXiaoming Zhao* RSC Advances,2017, 7, 256-259.
"Synthesis of 2,3,6-trisubstituted pyridines by transition-metal free cyclization of 1,3-diynes with amino acids", Gang Zhou,Xiaoming Zhao*, Wenyan Dan Tetrahedron Letters,2017, 58, 3085-3088.
"Application of DMSO in the Synthesis of 1,4-Disubstituted (But-1-en-3-ynyl)methylthioethers", Chuanchuan Cao, Liang Zhang, Gang Zhou, Wenyan Dan, Xiaorong Wang,* and Xiaoming Zhao* ChemistrySelect,2017, 2, 2985-2988.
"Regioselective fluorination of 1-(2,2-dibromovinyl)benzene derivatives with wet tetran-bytylammonium fluoride: one-pot synthesis of (Z)-1-(2-bromo-1-fluorovinyl)benzenes", Mingzhu Zhao, Ling Ming, Jialiang Tang andXiaoming Zhao*, Organic Letters,2016, 18, 416-419 (This paper was highlighted byOrganic Chemistry Portal, 2017, Jan, see: www.organic-chemistry.org/abstracts/lit5/277.shtm).
"Enantioselective synthesis of fluorinated branched allylic compounds via Ir-catalyzed allylations of functionalized fluorinated methylene derivatives", Hongbo Zhang, Jiteng Chen,Xiaoming Zhao* Organic & Biomolecular Chemistry,2016, 14, 7183-7186 (This paper was highlighted in Synfacts, 2016, 16, 947).
"Synthesis of Chiral Fluorine-Containing Compounds via Pd-Catalyzed Asymmetrical Allylations of Dimethyl 2-fluoromalonate Using Sulfonamide-Pyridine Ligands", Min Zhang, Zhao Mingzhu, Zheng Purui, Zhang Hongbo,Xiaoming Zhao* Journal of Fluorine Chemistry,2016, 189, 13-21.
"Highly efficient cycloaddition reaction of 1,3-diynes with sodium azide: a new way to 5-substituted-4-acetylene-1H-1,2,3-triazoles", Jia-Liang Tang, Ling Ming, andXiao-Ming Zhao* J. Heterocyclic Chem.,2016, 53, 1367-1370.
"Synthesis of carbonyl 2-amino-pyrimidines via tandem regioselective heterocyclization of 1,3-diynes with guanidine and selective oxidation", Liang Zhang, Mingzhu Zhang andXiaoming Zhao*, Chemical Communications,2015, 51, 9370-9373.
"Regioselective formation of 2,4,5-trisubstituted oxazoles through transition-Metal free heterocyclization of 1,3-diynes withN,O-bis(trimethylsiyl)acetamide", Liang Zhang andXiaoming Zhao*, Organic Letters,2015, 17, 184-186.
"Enantioselective transformation of Na2SO3into allylic sulfonic acids under Pd catalysis", Wei Liu,Xiaoming Zhao*, Hong-bo Zhang, Liang Zhang, Chemical Communications,2015, 51, 655-657.
"Synthesis of allylic sulfonic acids via regioselective Pd-catalyzed allylic substitutions of Na2SO3", Wei Liu,Xiaoming Zhao*, Tetrahedron Letters,2015, 56, 6800-6802.
"Synthesis of Allyl Carbamates through the Regioselective Domino Reaction of Amines, CO2, and Unsymmetrical Allyl Chlorides under Pd Catalysis", Juewang Cai, Min Zhang, andXiaoming Zhao*, Eur. J. Org. Chem.2015, 5925-5928.
"Enantioselective synthesis of monofluorinated allylic compounds: Pd-catalyzed asymmetric allylations of dimethyl 2-fluoromalonate using newN-sulfinyl-based ligands," Ning Gao,Xiao-Ming Zhao,*Cheng-Si Cai and Jue-Wang Cai, Org. Biomol. Chem.,2015, 13, 9551-9558.
"Enantioselective transformation of allyl carbonates into branched allyl carbamates using amines and recycling CO2under iridium catalysis", Shengcai Zheng, Min Zhang, andXiaoming Zhao*, Chemistry a European Journal,2014, 20, 7216-7221 (highlighted by both a Frontispiece paper inChem.A -Eur. J. and by ChemViews).
"Enantioselective domino reaction of CO2, amine and allyl chloride under iridium catalysis: formation of allyl carbamates", Min Zhang,Xiaoming Zhao*, Shengcai Zheng, Chemical Communications,2014, 50, 4455-4458.
"Asymmetric Synthesis of Allylic Sulfonic Acids: Enantio- and Regioselective Iridium-Catalyzed Allylations of Na2SO3", Wei Liu,Xiaoming Zhao*, Hongbo Zhang, Mingzhu Zhao, Chemistry A European Journal,2014, 20, 16873-16876.
"Transition-Metal-Free Heterocyclization of 1,3-Diynes with Nitriles in the Presence of Aqueous Potassium Hydroxide: Synthesis of 2,4-Disubstituted 5-[(E)-2-Phenylethenyl]-1,3-oxazoles" Ming, Ling, Tang, Jialiang,Zhao, Xiaoming*, Synthesis,2014, 46, 2499-25025.
"Carbon–Phosphorus Bond Formation by Enantioselective Palladium-Catalyzed Allylation of Diphenylphosphine Oxide", Liang Zhang, Wei Liu, andXiaoming Zhao* Eur. J. Org. Chem.,2014, 6846-6849.
"Highly regioselective iridium-catalyzed and samarium-promoted coupling of allylic carbonates with ketones: New approach toward homoallylic alcohols", Wei Liu, Liang Zhang, Weikang Yang, andXiaoming Zhao* RSC Advances,2013, 3, 19917-19919.
"Carbon-Sulfur Bond Formation via Metal-Catalyzed Allylations of Sulfur Nucleophiles", Liu, Wei,Zhao, Xiaoming*, Synthesis,2013, 45, 2051-2069 (Invited review).
"Sulfur heterocyclization and 1,3-migration of silicon in reaction of 1,3-diynes with sodium triisopropylsilanethiolate: one-pot synthesis of 2,5-disubstituted 3-(triisopropylsilyl)thiophenes", Tang, Jialiang, Ming, Ling,Zhao, Xiaoming*, Synthesis,2013, 45, 1713-1718.
"Synthesis of Chiral Allylic Thioesters: Enantio- and Regioselective Iridium-Catalyzed Allylations of KSAc" Gao, Ning;Zhao, Xiaoming*, European Journal of Organic Chemistry,2013, 13, 2708-2714.
"Iridium-catalyzed allylic alkylationa of sodium phenyl selenide", Ruiming Cui, Xinwen Guo, Shengcai Zheng,Xiaoming Zhao* Chin. J. Chem.,2012, 30, 2647-2651.
"Iridium-catalyzed enantioselective allylation of sodium 2-aminobenzenethiolate: an access to chiral benzo-fusedN, S-heterocycles", Ning Gao, Xinwen Guo, Shengcai Zheng, Weikang Yang,Xiaoming Zhao* Tetrahedron,2012, 68, 9413-9418 (This paper was highlighted inSynfacts,2013, 1, 71).
"Enantioselective Iridium-catalyzed allylation of sodium benzotriazolide: an efficient way to chiral allylbenzotriazoles", Min Zhang, Xinwen Guo, Shengcai Zheng,Xiaoming Zhao* Tetrahedron Letters,2012, 53, 6995-6998.
"Synthesis of 2,5-disubstituted thiophenes via metal-free sulfur heterocyclization of 1,3-diynes with sodium hydrosulfide", Jialiang Tang, andXiaoming Zhao* RSC Advances,2012, 2, 5488–5490.
"One pot iridium-catalyzed asymmetrical double allylaitons of sodium Sulfide: a fast and economic way to construct chiral C2-symmetric bis(1-substituted-allyl)sulfane", Shengcai Zheng, Weiqing Huang, Ning Gao, Ruimin Cui, Min Zhang, andXiaoming Zhao* Chem. Commun.,2011, 45, 6969-6971.
"Enantioselective Palladium-Catalyzed Allylic Substitution of Sodium Benzotriazoleide" , Wei Liu, Dazhi Zhang,Shengcai Zheng, Yinshuang Yue, Dongge Liu andXiaoming Zhao* Eur. J. Org. Chem.,2011, 6288-6293 (This paper was highlighted inSynfacts, 2012,8, 188).
"Carbon-sulfur bond formaton via Iridium-catalyzed asymmetrical allylation of aliphatic thiols" Ning Gao, Shengcai Zheng, Weikang Yang, andXiaoming Zhao* Organic Letters,2011,13, 1514-1516 (This paper was highlighted byOrganic Chemistry Portal,2011, Dec, see:www.organic-chemistry.org/abstracts/lit3/207.shtm).
"Iridium-Catalyzed Asymmetric Allylation of Sodium Triisopropylsilanethiolate: a New Way to Form Chiral Thiols" Weiqing Huang, Shengcai Zheng, Jialiang Tang, andXiaoming Zhao* Org. Biomol. Chem.,2011, 9, 7897-7903.
"Highly regioselective Pd-catalyzed allylic alkylation of fluorobis(phenylsulfonyl)methane", Xiaoming Zhao*, Dengge Liu, Shengcai Zheng, Ning Gao Tetrahedron Lett.,2011, 52, 665-667.
"Regio- and Enantioselective Iridium-Catalyzed Allylation of Thiophenol: Synthesis of Enantiopure Allyl Phenyl Sulfides" Shengcai Zheng, Ning Gao, Wei Liu, Dongge Liu,Xiaoming Zhao*,and Theodore Cohen Organic Letters,2010, 12, 4454-4457 (This paper was highlighted inSynfacts, 2010,12, 1400).
"Readily Prepared 3-Chloro-1-(phenylthio)propene, a Versatile Three-Carbon Annulating Agent" Taoping Liu,Xiaoming Zhao*, Long Lu, and Theodore Cohen* Organic Letters,2009, 11, 4576-4579.
"Iridium-catalyzed Regio- and Enantioselective Allylic Alkylation of Fluorobis(phenylsulfonyl)methane" Wenbo Liu, Shengcai Zheng, Hu He,Xiaoming Zhao*, Lixin Dai, and Shuli You * Chem. Commun.,2009, 43, 6604-6606.
"Iridium-Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A Csp3-H Bond Activation a to the Trifluoromethyl Group" Y. Guo;X. Zhao; D. Zhang; S-I. Murahashi Angew. Chem. Int. Ed.,2009, 48, 2047-2049.
"Efficient 1,4-addition of a-substituted fluoro(phenylsulfonyl)methane derivatives to a,b-unsaturated compounds" G. K. Surya Prakash,*Xiaoming Zhao, Sujith Chacko, Fang Wang, Habiba, Vaghoo, and George A. Olah* Beil. J. Org. Chem.,2008, 4, No. 17-20.
"2-Phenylthio-3-bromopropene, a Valuable Synthons, Easily Prepared by a Simple Rearrangement" Wenbo Chen,Xiaoming Zhao*, Long Lu and T. Cohen* Organic Letters,2006, 8, 2807-2090.
"A Platinum Acetylide Polymer with Sterically Demanding Substituents: Effect of Aggregation on the Triplet Excited State" Xiaoming Zhao, Thomas Cardolaccia, Richard Farley, Khalil A. Abboud and Kirk S. Schanze. Inorganic Chemistry,2005, 44, 2619-2627.
"Bis-silyl substituted ferrocenylenes, including dicyanovinyl electron-withdrawing groups, as potential non-linear optical materials" Xiaoming Zhao, Hemant Sharma, Francisco Cervantes-Lee and Keith H. Pannell, Gary J. Long, Ahmed M. Shahin J. Organomet. Chem.2003, 686, 235-241.
“Synthesis, and Crystal Growth and Structure ofN-(2-nitro-4-cyano-phenyl)-L-serine and Investigation of SHG activity”, Xiaoming Zhao, Xing Chen, Lubai Cheng* Mol. Cry. Liq. Cry., Sci. Technol., Sect. A,1998, 325, 7-11.
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