Hazari, Nilay - Yale University - Department of Chemistry

个人简介

Selected as a 'Rising Star' by the 41st International Conference on Coordination Chemistry, 2014 Camille and Henry Dreyfus Teacher Scholar Award, 2014 Alfred P. Sloan Research Fellow, 2013 Organometallics Fellow (from the American Chemical Society Journal Organometallics), 2012 National Science Foundation Career Award, 2012 Rhodes Scholarship for New South Wales, 2003

研究领域

Inorganic Chemistry/Organic Chemistry/Synthetic Chemistry/Green Chemistry/Organometallic Chemistry/Homogeneous Catalysis/Computational Chemistry

近期论文

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Chakraborty, S.; Lagaditis, P. O.; Förster, M.; Bielinski, E. A.; Hazari, N.; Holthausen, M. C.; Jones, W. D.; Schneider, S. 'Well-Defined Iron Catalysts for the Acceptorless Reversible Dehydrogenation-Hydrogenation of Alcohols and Ketones.' ACS Catal. 2014, 4, 3994-4003. Li, X.; Huang, J.-S.; Nejati, S.; Huang, S.; Osuji, C. O.; Hazari, N.; Taylor, A. D. 'Role of HF in Oxygen Removal from Carbon Nanotubes: Implications for High Performance Carbon Electronics.' Nano Lett. 2014, 14, 6179-6184. Selected as a Science and Technology Concentrate in Chemical & Engineering News. Bielinski, E. A.; Lagaditis, P. O.; Zhang, Y.; Mercado, B. Q.; Würtele, C.; Bernskoetter, W. H.; Hazari, N.; Schneider, S. 'Lewis Acid Assisted Formic Acid Dehydrogenation Using a Pincer Supported Iron Catalyst.' J. Am. Chem. Soc. 2014, 136, 10234-10237. Suh, H.-W.; Guard, L. M.; Hazari, N. 'Synthesis and Reactivity of a Masked PSiP Pincer Supported Nickel Hydride.' Polyhedron 2014, 84, 37-43. Invited contribution to 'John Bercaw' issue. Suh, H.-W.; Guard, L. M.; Hazari, N. 'A Mechanistic Study of Allene Carboxylation with CO2 Resulting in the Development of a Pd(II) Pincer Complex for the Catalytic Hydroboration of CO2.' Chem. Sci. 2014, 5, 3859-3872. Fillman, K. L.; Bielinski, E. A.; Schmeier, T. J.; Nesvet, J. C.; Woodruff, T. M.; Pan, C. J.; Takase, M. K.; Hazari, N.; Neidig, M. L. 'Flexible Binding of PNP Pincer Ligands to Monomeric Iron Complexes.' Inorg. Chem. 2014, 53, 6066-6072. Li, X.; Guard, L. M.; Jiang, J.; Sakimoto, K.; Huang, J.-S.; Wu, J.; Li, J.; Pokhrel, R.; Brudvig, G. W.; Ismail-Beigi, S.; Hazari, N.; Taylor, A. D. 'Controlled Doping of Carbon Nanotubes with Metallocenes for Application in Hybrid Carbon Nanotube/Si Solar Cells.' Nano Lett. 2014, 14, 3388-3394. Hruszkewycz, D. P.; Balcells, D.; Guard, L. M.; Hazari, N.; Tilset, M. 'Insight Into the Efficiency of Cinnamyl Supported Precatalysts for the Suzuki-Miyaura Reaction: the Observation of Pd(I) Dimers with Bridging Allyl Ligands During Catalysis.' J. Am. Chem. Soc. 2014, 136, 7300-7316. Wu, J.; Nova, A.; Balcells, D.; Brudvig, G. W.; Dai, W.; Guard, L. M.; Hazari, N.; Lin, P.-H.; Pokhrel, R.; Takase, M. K. 'Nickel(I) Monomers and Dimers with Cyclopentadienyl and Indenyl Ligands.' Chem. Eur. J. 2014, 20, 5327-5337. Koehne, I.; Schmeier, T. J.; Bielinski, E. A.; Pan, C. J.; Lagaditis, P. O.; Bernskoetter, W. H.; Takase, M. K.; Würtele, C.; Hazari, N.; Schneider, S. 'Synthesis and Structure of Six Coordinate Iron Borohydride Complexes Supported by PNP Ligands.' Inorg. Chem. 2014, 53, 2133-2143. Jin, D.; Williard, P. G.; Hazari, N.; Bernskoetter, W. H. 'An Unstabilized b-Nickelalactone Derived from CO2-Ethylene Coupling: the Effect of Sodium Cation on Metallacycle Isomerization.' Chem. Eur. J. 2014, 20, 3205-3211. Nova, A.; Suh, H.-W.; Schmeier, T. J.; Guard, L. M.; Eisenstein, O.; Hazari, N.; Maseras, F. 'An Unusual Example of Hypervalent Si: A Five-coordinate Silyl Group Bridging Two Pd or Ni Centers through a Non-symmetrical Four-center Two-electron Bond.' Angew. Chem., Int. Ed. 2014, 53, 1103-1108. Bartholomew, A. K.; Guard, L. M.; Hazari, N. 'Synthesis of Mg complexes Supported by Tris-(1-pyrazolyl)phosphine.' Aust. J. Chem. 2013, 66, 1455-1458. Dai, W.; Chalkley, M. J.; Brudvig, G. W.; Hazari, N.; Melvin, P. R.; Pokhrel, R.; Takase, M. K. 'Synthesis and Properties of NHC Supported Palladium(I) Dimers with Bridging Allyl, Cyclopentadienyl and Indenyl Ligands.' Organometallics 2013, 32, 5114-5127. Manas, M. G.; Graeupner, J.; Allen, L. J.; Dobereiner, G. E.; Rippy, K.; Hazari, N.; Crabtree, R. H. 'Hydrogenation of Quinaldine and Benzylic Aldehydes both Separately and Combined in a Tandem Hydrogenation-Reductive Alkylation of Quinaldine by Aldehydes with Iridium Benzoquinoline Catalysts.' Organometallics 2013, 32, 4501-4506. Chalkley, M. J.; Hruszkewycz, D. P.; Hazari, N.; Hofmann, P.; Schmeier, T. J.; Takase, M. K. 'Synthesis, Electronic Structure and Reactivity of Palladium(I) Dimers with Bridging Allyl, Cyclopentadienyl and Indenyl Ligands.' Organometallics 2013, 32, 4223-4238. Bielinski, E. A.; Dai, W.; Guard, L. M.; Hazari, N.; Takase, M. K. 'Synthesis, Properties and Reactivity Studies of Palladium and Nickel NHC Complexes Supported by Combinations of Allyl, Cyclopentadienyl, and Indenyl Ligands.' Organometallics 2013, 32, 4025-4037. Selected as the cover article. Guard, L. M.; Hazari, N. 'Synthesis and Reactivity of Magnesium Complexes Supported by Tris(2-dimethylaminoethyl)amine (Me6tren).' Organometallics 2013, 32, 2787-2794. Bernskoetter, W. H.; Hazari, N. 'A Computational Investigation of the Insertion of Carbon Dioxide into Four and Five Coordinate Iridium Hydrides.' Eur. J. Inorg. Chem. 2013, 4032-4041. Invited contribution to 'Small Molecule Activation by Reactive Metal Complexes' issue. Jin, D.; Schmeier, T. J.; Williard, P. G.; Hazari, N.; Bernskoetter, W. H. 'Lewis Acid Induced β-Elimination from a Nickelalactone-Efforts Toward Acrylate Production from CO2 and Ethylene.' Organometallics 2013, 32, 2152-2159. Huang, J.-S.; Goh, T.; Li, X.; Sfeir, M.; Bielinski, E. A.; Tomasulo, S.; Lee, M. L.; Hazari, N.; Taylor, A. D. 'Polymer Bulk Heterojunction Solar Cells Employing Förster Resonance Energy Transfer.'Nat. Photonics 2013, 7, 479-485. For more information on this work see: Dastoor, P. C. 'Solar Paint: Harvesting Light' Nat. Photonics 2013, 7,425-426.