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稀土金属有机化合物的合成、结构及其催化性质,导向有机合成的金属有机化学,不对称合成等

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Asymmetric Epoxidation of Unsaturated Ketones Catalyzed by Heterobimetallic Rare Earth-Lithium Complexes Bearing Phenoxy Functionalized Chiral Diphenylprolinolate Ligand Q. Q. Qian, Y. F. Tan, B. Zhao,* T. Feng, Q. Shen, Y. M. Yao*, Organic Letters, 2014, 16, 4516-4519. Synthesis and Characterization of Amidate Rare-Earth Metal Amides and Their Catalytic Activities toward Hydrophosphonylation of Aldehydes and Unactivated Ketones L. Zhao, H. Ding, B. Zhao,* C. R. Lu, Y. M. Yao, Polyhedron DOI: 10.1016/j.poly.2014.04.018 Asymmetric hetero-Diels-Alder reaction of Danishefsky’s dienes with a-carbonyl esters catalyzed by an indium(III)-PyBox complex B. Zhao, T. P. Loh, Organic Letters, 2013, 15, 2914-2917. Unexpected C−H bond activation promoted by bimetallic lanthanide amido complexes bearing a META-phenylene-bridged bis(β-diketiminate) ligand S. Sun, Q. Sun, B. Zhao*, Y. Zhang, Q. Shen, Y. M. Yao*, Organometallics, 2013, 32, 1876-1881. Bimetallic lanthanide amido complexes as highly active initiators for the ring-opening polymerization of lactides S. Sun, K. Nie, Y. F. Tan, B. Zhao*, Y. Zhang, Q. Shen, Y. M. Yao*, Dalton Trans., 2013, 42, 2870-2878. Synthesis and structural diversity of lanthanide amidate complexes and their catalytic activities for the ring-opening polymerization of rac-lactide X. L. Hu, C. R. Lu, B. Wu, H. Ding, B. Zhao*, Y. M. Yao*, Q. Shen, J. Organomet. Chem., 2013, 732, 92-101. Addition of terminal alkynes to aromatic nitriles catalyzed by divalent lnathanide amides supported by amidates: synthesis of ynones H. Ding, C. R. Lu, X. L. Hu, B. Zhao*, B. Wu, Y. M. Yao*, Synlett, 2013, 24, 1269-1274. Ring-opening polymerization of trimethylenecarbonate by the bridged diphenoxo ytterbium (II) complex, B. Zhao, X. L. Hu, C. R. Lu, J. Appl. Polym. Sci. 2011, 120, 2693. One-pot synthesis of salicylanilides by direct amide bond formation from salicyclic acid under microwave irradiation, C. R. Lu, B. Zhao*, Y. P. Jiang, H. Ding, S. Yang, Syn. Commun. 2011, 41, 1257. Ring-opening polymerization of trimethylenecarbonate and its copolymerization with e-caprolactone by lanthanide (II) aryloxide complexes, B. Zhao, C. R. Lu, Q. Shen, J. Appl. Polym. Sci., 2007, 106, 1383. Metallomacrocycle complexes of lanthanides with bridged amide ligands: syntheses and molecular structures of [{μ2-p-(Me3SiN)2C6H4}YbCl(THF)2]2 and [{μ2-p-(Me3SiN)2C6H4}Nd(μ2-Cl)(THF)]4•2PhMe, B. Zhao, H. H. Li, Q. Shen, Y. Zhang, Y. M. Yao, C. R. Lu, Organometallics 2006, 25, 1824. Polymerization of N-phenyl maleimide by lanthanide complexes, B. Zhao, Y. R. Wang, C. R. Lu, Q. Shen, M. Y. Deng, J. Polym. Sci. Polym. Chem., 2005, 43, 3966.

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