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研究领域

金属蛋白和金属酶的化学仿生,对生物分子的手性识别,卟啉相关的光电磁材料等。目前致力于研究弱相互作用,如氢键,在以上领域中的作用。

近期论文

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Just a Proton: Distinguishing the Two Electronic States of Five-Coordinate High-Spin Iron(II) Porphyrinates with Imidazole/ate Coordination. C. J. Hu, C. D. Sulok, F. Paulat, N. Lehnert, A. I. Twigg, M. P. Hendrich, C. E. Schulz, and W. R. Scheidt. J. Am Chem. Soc. 2010, 132, 3737. Influence of Hydrogen Bonding on the Electronic Configuration of Five-Coordinate High-Spin Iron(II) Porphyrinates. C. J. Hu, B. C. Noll, P. M. B. Piccoli, A. J. Schultz, C. E. Schulz, and W. R. Scheidt. J. Am Chem. Soc. 2008,130,3127. Proton-Mediated Electron Configuration Change in High-Spin Iron(II) Porphyrinates. C. J. Hu, B. C. Noll, C. E. Schulz, and W. R. Scheidt, J. Am Chem. Soc. 2005, 127, 15018. Electronic Configuration Assignment and the Importance of Low-Lying Excited States in High-Spin Imidazole-Ligated Iron(II) Porphyrinates. C. J. Hu, A. Roth, M. K. Ellison, J. An, C. E. Schulz, W. R. Scheidt. J. Am Chem. Soc. 2005, 127, 5675. Nuclear Resonance Vibrational Spectra of Five-Coordinate Imidazole-ligated Iron(II) Porphyrinates. C. J. Hu*, A. Barabanschikov, M. K. Ellison, J. Zhao, E. E. Alp, W. Sturhahn, M. Z. Zgierski, J. T. Sage, and W. R. Scheidt, Inorg. Chem. In press. Electronic Configuration of Five-Coordinate High-Spin Pyrazole-Ligated Iron(II) Porphyrinates. C. J. Hu*, B. C. Noll, C. E. Schulz, and W. R. Scheidt. Inorg. Chem. 2010, 49, 10984. Hydrogen Bonding Influence of 1,10-phenathroline on the Electronic Configuration of Five-Coordinate High-Spin Iron(II) Porphyrinates. C. J. Hu, B. C. Noll, C. E. Schulz, and W. R. Scheidt. Inorg. Chem. 2008,47, 8884. Sulfoxide as a Ligand in Iron(II) Porphyrinates: S– or O–Bound? C. J. Hu, B. C. Noll and W. R. Scheidt. Inorg. Chem. 2007, 46, 8258. Four-Coordinate Iron(II) Porphyrinates: Electronic Configuration Change by Intermolecular Interaction. C. J. Hu, B. C. Noll, C. E. Schulz and W. R. Scheidt. Inorg. Chem. 2007, 46, 619. Electronic Configuration of High-Spin Imidazole-Ligated Iron(II) Octaethylporphyrinates. C. J. Hu, J. An, B. C. Noll, C. E. Schulz, and W. R. Scheidt. Inorg. Chem. 2006, 45, 4177. Low-spin Bis(2-methylimidazole)(octaethylporphyrinato) -iron(III) Chloride (Fe(OEP)(2-MeHIm)2]Cl). A Consequence of Hydrogen Bonding? C. J. Hu, B. C. Noll, C. E. Schulz, and W. R. Scheidt. Inorg. Chem. 2006, 45, 9721. Electronic Configuration of High-Spin Imidazole-Ligated Iron(II) Octaethylporphyrinates. C. J. Hu, J. An, B. C. Noll, C. E. Schulz, and W. R. Scheidt. Inorg. Chem. 2006, 45, 4177.

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