Crabtree, Robert H. - Yale University - Department of Chemistry

个人简介

DuPont Young Faculty Fellow, 1977 A.P. Sloan Foundation Fellow, 1981 Junior Faculty Fellow, Yale, 1981 Dreyfus Teacher-Scholar, 1982 Corday-Morgan Medal, 1984 Esso Lectureship, Toronto, 1986 Albright and Wilson Visiting Prof., Warwick, 1986 Editorial Board, Chemical Reviews, 1990 Organometallic Chemistry Prize of RSC, 1991 Organometallic Chemistry Prize of ACS, 1993 Mack Award, Ohio State Univ., 1994 Editorial Board, J. Mol. Catal., 1995 Assoc. Ed., Americas, New J. Chem., 1998 Chair, Div. of Inorg. Chem., ACS., 1998 Ed. Board, Comptes Rendues (Paris), 1998 Dow Lecturer, Univ. of Ottowa, 1999 ISI Highly Cited Author Award, 2000 Bailar Medal, Univ. of Illinois, 2001 Rh Bicentennial Award; Ed. Board, Coor. Chem. Rev., 2002 Dow Lecturer, Berkeley, Williams Lecture, Oxford, 2004 Sabatier Lecture, Toulouse; Brewster Lecture, Kansas, 2006 Board of Regional Editors, Science, 2006-present Karcher Medal (Oklahoma), 2007 Pedersen Lecture (duPont), Lutz Lecture (U Va), 2008 John Osborn Lecturer (Strasbourg); Mond Lecture Series, Roy. Soc. Chem; Shore Lecture (Ohio State U), 2009 Kosolapoff Award (ACS and Auburn Univ), 2010 Rothchild Lecture (Rochester U), 2010 Stauffer Lecture (USC), 2010 C.P. Whitehead Professor, Yale, 2010 King Lecture (U Ga), 2011 Fellow of ACS, 2011 Fellow of IUPAC, 2011 Fellow of the American Academy of Arts & Sciences, 2011 McElvain Lecture (U Wisc., Madison), 2013 Yale Postdoctoral Mentoring Award, 2013 Siedle Lecture (U Indiana), 2014 Centenary Award (Roy. Soc. Chem.), 2014

研究领域

Inorganic Chemistry/Organic Chemistry/Green Chemistry

近期论文

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Oana R. Luca, Daria L. Huang, Michael K. Takase, Robert H. Crabtree A Redox-Active Cyclopentadienyl Ni N-heterocyclic Carbene Complex for the Electrocatalytic Desaturation of Chemical Fuels New Journal of Chemistry 10.1039/C3NJ00276D. Oana R. Luca, Steven J. Konezny, Eric K. Paulson, Fatemah Habib, Kurt M. Luthy, Muralee Murugesu, Robert H. Crabtree, Victor S. Batista Study of an S=1 NiII Pincer Electrocatalyst Precursor for Aqueous Hydrogen Production Based on Paramagnetic 1H NMR Dalton Transactions 2013, 42, 8802-8807. Fatemah Habib, Oana R. Luca, Veacheslav Vieru, Serge I. Gorelsky, Michael K. Takase, Liviu F. Chibotaru, Steven Hill, Robert H. Crabtree, Muralee Murugesu Ligand Field Influence on Slow Magnetisation Relaxation versus Spin-Crossover in Mononuclear Cobalt Complexes, Angew. Chem. Intl. Ed. DOI: 10.1002/anie.201303005. Oana R. Luca, James D. Blakemore, Jeremy M. Praetorius, Timothy J. Schmeier, Glendon B. Hunsinger, Gary W. Brudvig, Nilay Hazari, and Robert H. Crabtree Organometallic Ni pincer complexes for the electrocatalytic production of hydrogen, Inorganic Chemistry, 2012, 51, 8704–8709. Peter Driscoll, Elise Deunf, Leah Rubin, Oana R. Luca, Robert H. Crabtree, Christopher Chidsey, John Arnold, and John Kerr, Redox Catalysis for Dehydrogenation of Liquid Hydrogen Carrier Fuels for Energy Storage and Conversion, ECS Transactions, 2011, 35, 3. Michael G. Manas, Jonathan Graeupner, Laura J. Allen, Graham E. Dobereiner, Kerry C. Rippy, Nilay Hazari, and Robert H. Crabtree Hydrogenation of Quinaldine and Benzylic Aldehydes both Separately and Combined in a Tandem Hydrogenation–Reductive Alkylation of Quinaldine by Aldehydes with Iridium Benzoquinoline Catalysts, Organometallics 2013, 32, 4501−4506 DOI: 10.1021/om400267n Crabtree RH, How far have we come (Editorial for 'Mechanisms' Special Issue), Dalton Trans, 2013, 42, 4104. Zhou M, Hintermair U, Hashiguchi BG, Parent AR, Hashmi SM, Elimelech M, Periana RA, Brudvig GW, Crabtree RH, Cp* Iridium Precatalysts for Selective C-H Oxidation with Sodium Periodate As the Terminal Oxidant, Organometallics, 2013, 32, 957-965. Brewster TP, Konezny SJ, Sheehan SW, Martini LA, Schmuttenmaer CA, Batista VS, Crabtree RH, Hydroxamate Anchors for Improved Photoconversion in Dye-Sensitized Solar Cells, Inorg Chem, 2013, ASAP. Blakemore JD, Mara MW, Kushner-Lenhoff MN, Schley ND, Konezny SJ, Rivalta I, Negre CFA, Snoeberger RC, Kokhan O, Huang J, Stickrath A, Tran LA, Parr ML, Chen LX, Tiede DM, Batista VS, Crabtree RH, Brudvig GW, Characterization of an amorphous iridium water-oxidation catalyst electrodeposited from organometallic precursors, Inorg Chem, 2013, 52, 1860-71. Luca OR, Thompson BA, Takase MK, Crabtree, RH, Synthesis and Electrochemistry of a Series of Cyclopentadienyl Ni N-Heterocyclic Carbene Compounds, J Organometal Chem, 730, 79-83, 2013. Luca OR, Crabtree, RH, Virtual hydrogen storage processes and related catalysts and systems, WO/2012/112758, Publication Date: 23 Aug, 2012. [World Patent] Schley ND, Halbert S, Raynaud C, Eisenstein O, Crabtree RH, Symmetrical Hydrogen Bonds in Iridium(III) Alkoxides with Relevance to Outer Sphere Hydrogen Transfer, Inorg. Chem., 2013, 42, 3617. Blakemore, JD, Hull, JF, Crabtree, RH, Brudvig, GW, Aqueous speciation and electrochemical properties of a water-soluble manganese phthalocyanine complex, Dalton Trans, 2012, 41, 7681-7688. Garand, E, Fournier, JA, Kamrath, MZ, Schley, ND, Crabtree, RH, Johnson, MA, Characterization of an activated iridium water splitting catalyst using infrared photodissociation of H-2 tagged ions, Phys Chem Chem Phys, 2012, 14, 10109-10113. Konezny, SJ, Doherty, MD, Luca, OR, Crabtree, RH, Soloveichik, GL, Batista, VS, Reduction of Systematic Uncertainty in DFT Redox Potentials of Transition-Metal Complexes, J Phys Chem C, 2012, 116, 6349-6356. Parent AR, Crabtree RH, Brudvig GW, Comparison of Primary Oxidants for Water-Oxidation Catalysis, Chem. Soc. Rev., 2013, 42, 2247-2252. Crabtree RH, Abnormal, Mesoionic and Remote N-Heterocyclic Carbene Complexes, Coord. Chem. Rev., 2013, 257, 755-766. Eisenstein O, Crabtree RH, Outer Sphere Hydrogenation Catalysis, New J Chem, 2013, 37, 21-27 (Invited Focus article). Sokolow JD, Trzop E, Chen Y, Tang JJ, Allen LJ, Crabtree RH, Benedict JB, Coppens P, Binding Modes of Carboxylate- and Acetylacetonate-Linked Chromophores to Homodisperse Polyoxotitanate Nanoclusters, J Am Chem Soc, 2012, 134, 11695-11700. Graeupner J, Brewster TP, Blakemore JD, Schley ND, Thomsen JM, Brudvig GW, Hazari N, Crabtree RH, Preparation of Electron-Rich CpIr(biphenyl-2,2’-diyl) Complexes with π Accepting Carbon Donor Ligands, Organometallics, 2012, 31, 7158–7164.