袁立华 - 四川大学

个人简介

四川大学化学学院教授，理学博士，博士生导师。1998年晋升教授，1998年至2005年先后在香港大学和美国纽约州立大学从事研究工作。研究方向涉及有机化学、高分子合成、超分子自组装与功能材料以及放射化学领域。从事本科和研究生教学38年，主讲过《有机反应机理（双语）》、《高分子科学导论（双语）》、《高分子化学》、《精细化学品检测与剖析》、《大分子合成（英语）》、《趣味化学》、《合成化学》、《化学实验安全技术》等课程。工作经历 2006/01 - 至今四川大学化学学院教授 2002/01 - 2005/12 美国纽约州立大学研究科学家 1998/03 - 2002/12 香港大学化学系研究助理 1998/06 - 2002/12 四川大学化学学院教授 1993/11 - 1998/05 四川大学化学系副教授 1992/09 - 1993/10 四川大学化学系讲师 1984/07 - 1986/09 四川大学化学系助教

研究领域

主要研究与有机化学、高分子化学和放射化学相关的超分子功能材料，同时涉及材料化学、无机化学和环境化学。 1. 超分子组装与功能材料研究与含分子内三中心氢键的近平面芳酰胺大环和非环芳酰胺寡聚体相关的超分子组装行为和功能材料，包括非共价主-客体络合、纳米管组装、准轮烷及轮烷构筑、超分子凝胶调控、对金属离子萃取性能、离子对识别以及液晶行为调控等方面。 2. 有机功能材料在放射化学中的识别和分离应用研究以杯芳烃、柱芳烃、环芳酰胺为主的大环类配体对镧锕系离子的识别和萃取性能。其中，在国际上率先展开了用于镧锕系离子分离萃取的柱芳烃类萃取剂研究。

近期论文

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Yuan, X. Y.; Wang, Y.; Wu, P. C.; Ouyang, X.; Bai, W. K.; Wan, Y. S.; Yuan, L. H.*, Feng, W.*, High acidity- and radiation-resistant triazine-based POPs for recovery of Pd(II) from nuclear fission products, Chem. Eng. J., 2022, 430, 132618 Zhou, Y. D.#; Wu, J. Y. #; Liu, Z. J.; Xu, W. T.; Liu, M. L.; Jia, A. L.; Liu, Y. C.; Xiao, X.; Li, X. W.* and Yuan, L. H.*, Threading of three rings on two stations: a convergent approach to [4]rotaxane, Chem. Commun., 2021, 57, 13506-13509. Liu, Z. J.#; Kang, K. #; Zhou, Y. D.; Liu, R.; Cai, Y. M.; Feng, W.; and Yuan, L. H.*, Switchable supramolecular ensemble for anion binding with ditopic hydrogen-bonded macrocycles, Org. Chem. Front., 2021, 8, 5271-5279. Cai, Y. M.#; Yan, Q#; Wang, M. X.; Chen, J.; Fu, H. Y.; Ye, J. W.; Conradson, S. D.; Yuan, L. H.*; Xu, C.*; Feng, W.*, Endowing 2,6-bis-triazolyl-pyridine of poor extraction with superior efficiency for actinide/lanthanide separation at high acidity by anchoring to a macrocyclic scaffold, J. Hazard. Mater., 2021, 125745. Yang, Z. Y.; Liu, Z. J.; and Yuan, L. H.*, Recent Advances of Photoresponsive Supramolecular Switches, Asian J. Org. Chem., 2021, 10, 74-90. Ye, Z. C.; Wang, J.; Kothapalli, S. K.; Yang, Z. Y.; Chen, L.X.; Xu, W. T.; Cai, Y. M.; Zhang, T. H.; Xiao, X.; Deng, P. C.; Feng, W. and Yuan, L. H.*, Controlling the selective synthesis of [2]- and [3]rotaxanes by intermolecular steric hindrance between the macrocyclic hosts, Chem. Commun., 2020, 56, 1066-1069. Kothapalli, S. K.#; Kannekanti, V. K.#; Ye, Z. C.; Yang, Z. Y.; Chen, L.X.; Cai, Y. M.; Zhu, B. C.; Feng, W.; and Yuan, L. H.*, Light-controlled switchable complexation by a non-photoresponsive hydrogen-bonded amide, Org. Chem. Front., 2020, 7, 846 - 855. Ye, Z. C.; Yang, Z. Y.; Wang, L.; Chen, L. X.; Cai, Y. M.; Deng, P. C.; Feng, W.; Li, X. P.; Yuan, L. H.*, A Dynamic Hydrogen-Bonded Azo-Macrocycle for Precisely Photo-Controlled Molecular Encapsulation and Release, Angew. Chem. Int. Ed., 2019, 58, 12519-12523. Chen, L. X.; Cai, Y. M.; Feng, W.; Yuan, L. H.*, Pillararenes as macrocyclic hosts: a rising star in metal ion separation, Chem. Commun., 2019, 55, 7883-7898. Peng, Z. Y.; Guo, X. W.; Xu, W. T.; Li, J.; Deng, P. C.; Xiao, X.; Feng, W.; Yuan, L. H.*, Strong positive allosteric cooperativity in ternary complexes based on hydrogen-bonded aromatic amide macrocycles, Chem. Commun., 2019, 55, 4869-4872. Kang, K.; Lohrman, J. A.; Nagarajan, S.; Chen, L. X.; Deng, P. C.; Shen, X.; Fu, K. R.; Feng, W.*; Johnson, D. W.*; Yuan, L. H.*, Convergent ditopic receptors enhance anion binding upon alkali metal complexation for catalyzing Ritter reaction, Org. Lett., 2019. 21, 652-655. Guo, X. W.; Yang, Y. Z.; Peng, Z. Y.; Cai, Y. M.; Feng, W.; Yuan, L. H.*, Highly efficient synthesis of hydrogen-bonded aromatic tetramers as macrocyclic receptors for selective recognition of lithium ion, Org. Chem. Front., 2019, 6, 2654-2661. Sengupta, A.; Mohapatra, P.*; Fang, Y. Y.; Yuan, X. Y.; Feng, W.; Yuan, L. H.*. Extraction of Actinide Ions Using three CMPO-Functionalized Pillar[5]arenes in a Room Temperature Ionic Liquid, Sep. Purif. Technol., 2018, 195, 224-231. Pan, W.#; Mao, L. J.#; Shi, M. S.; Fu, Y. H.; Jiang, X. M.; Feng, W.; He, Y. Z.; Xu, D. G.*; Yuan, L. H.*, Cytochrome c - cyclo[6]aramide complex as supramolecular catalyst in methanol, New J. Chem., 2018, 42, 3857-3866. Li, X. W.; Yuan, X. Y.; Deng; P. C.; Chen, L. X.; Ren, Y.; Wang, C. Y.; Wu L. X.; Feng, W.; Gong, B.; Yuan, L. H.*, Macrocyclic shape-persistency of cyclo[6]aramide results in enhanced multipoint recognition for the highly efficient template-directed synthesis of rotaxanes, Chem. Sci., 2017, 8, 2091-2100. Yuan, X. Y.; Jia, Y. M.; Cai, Y. M.; Feng, W.*; Li, Y. M.; Li, X. P.*; Yuan, L. H.*, Unusual binding selectivity with non-selective homoditopic pillar[5]arene oxime: serendipitous discovery of a unique approach to heterobinuclear metalation in solution, Chem. Commun., 2017, 53, 2838-2841. Mao, L. J.; Pan, W.; Fu, Y. H.; Chen, L. X.; Xu, M.; Ren, Y.; Feng, W.; Yuan, L. H.*, Reversibly tunable lower critical solution temperature behavior induced by H-bonded aromatic amide macrocycle and imidazolium host-guest complexation, Org. Lett., 2017, 19, 18-21. Kang, K.; Huang W.; Fu, Y. H.; Chen, L. X.; Hu, J. C.; Ren, Y.; Feng, W.; Yuan, L. H.*, Pyridine-incorporated cyclo[6]aramide for recognition of urea and its derivatives with two different binding modes, Supramol. Chem., 2017, 29, 730-740. Li, C. X.; Wu, L.; Chen, L. X.; Yuan, X. Y.; Cai, Y. M.; Feng, W.*; Liu, N.; Ren, Y.; Sengupta, A.*; Murali, S. M.; Mohapatra, K. P.; Tao, G. H.; Zeng, H. Q.; Ding, S. D.; Yuan, L. H.*, Highly efficient extraction of actinides with pillar[5]arene-derived diglycolamides in ionic liquid via a unique mechanism involving competitive host-guest interactions, Dalton Trans., 2016, 45, 19299-19310. Shi, S. S.; Zhu, Y. M.; Li, X. W.; Yuan, X. Y.; Ma, T.; Yuan, W. L; Tao, G. H.; Feng, W.; Yuan, L. H.*, Ion-pair recognition of amidinium salts by partially hydrogen-bonded heteroditopic cyclo[6]aramide, RSC Adv., 2016, 6, 39839-39845. Chen, L.; Yuan, X. Y.; Wang, Z. X.; Luo, Y, R.; Huang, W.; Zhang, S.; Yuan, W. L.; Qin, S.; Tao, G. H.; Yuan, L. H.*, A redox-responsive complex system based on 2 D shape-persistent cyclo[6]aramide and ferrocenium, Asian J. Org. Chem., 2016, 5, 966-970.