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个人简介

郑思珣教授、博士生导师。1997年获中国科技大学高分子化学与物理专业博士学位。1992年7月起任中国科技大学高分子科学与工程系助教、讲师(1995年)、副教授(1998年)。分别于1996年和1998年两次赴香港科技大学化学工程系做访问学者。1999年1月, 获德意志研究联合会资助,赴德国高分子研究所(Deutsches Kunststoff-Institut, Darmstadt, Germany)及达姆施塔特工业大学(Technische Universitaet Darmstadt, Germany)物理系从事博士后研究。1999年9月转至美国加州大学欧文分校(University of California, Irvine, USA)化学系,为National Science Foundation (NSF)博士后研究员。2001年9月加入上海交通大学任高分子科学与工程系教授。先后承担或参加国家自然科学基金、中科院院长基金以及国家部委科研基金的研究工作; 2002年获“教育部优秀青年教师资助计划”基金支持,2004年获上海市“曙光学者”称号,2009年获上海市“育才”奖

研究领域

1、热固性聚合物的结构与性能:反应诱致微相分离、自组装行为以及材料断裂力学; 2、含笼型硅氧烷(Polyhedral Oligomeric Silsesquioxanes, POSS)的聚合物的结构与性能; 3、有机-无机复合聚合物水凝胶的微结构与凝胶行为; 4、具有拓扑结构高分子的合成及其微结构研究; 5、高分子固体核磁共振波谱研究(H-1、H-2、Si-29、C-13 CP/MAS NMR等):a)多组分高分子体系的 相结构及其大分子动力学研究;b)有机/无机纳米复合材料中的组分间相互作用研究。

近期论文

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Kun Wei, Lei Wang, Lei Li, Sixun Zheng*, Synthesis and Characterization of Bead-like Poly(N-isopropylacrylamide) with Double Decker Silsesquioxanes in the Main Chains, Polymer Chemistry, 2015, 6, 256-269 Houluo Cong, Jingang Li, Lei Li, Sixun Zheng*, Dielectric Constant Enhancement of Epoxy Thermosets via Formation of Polyelectrolyte Nanophases, Journal of Physical Chemistry B, 2014, 118, 14703 Jingang Li, Houluo Cong, Lei Li, Sixun Zheng*, Thermoresponse Improvement of Poly(N-isopropylacrylamide) Hydrogels via Formation of Poly(sodium p-styrene sulfonate) Nanophases, ACS Applied Materials & Interfaces, 2014, 16, 13677 Yulin Yi, Lei Li, Sixun Zheng*, Poly(epsilon-caprolactone)-block-poly(N-vinylpyrrolidone) Diblock Copolymers Grafted from Macrocyclic Oligomeric Silsesquioxane, Polymer, 2014, 55, 3925 Houluo Cong, Lei Li, Sixun Zheng*, Formation of Nanostructures in Thermosets Containing Block Copolymers: From Self-assembly to Reaction-induced Microphase Separation Mechanism, Polymer, 2014, 55, 1190 Chongyin Zhang, Lei Li, Houluo Cong, Sixun Zheng*, Poly(methyl methacrylate)-block-poly(N-vinyl pyrrolidone) Diblock Copolymer: a Facile Synthesis via Sequential Radical Polymerization Mediated by Isopropylxanthic Disulfide and Its Nanostructuring Polybenzoxazine Thermosets, Journal of Polymer Science, Part A: Polymer Chemistry, 2014, 52, 952 Kun Wei, Lei Li, Sixun Zheng*, Organic-Inorganic Random Copolymers from Methacrylate-terminated Poly(ethylene oxide) with 3-Methacryloxypropyl heptaphenyl Polyhedral Oligomeric Silsesquioxane: Synthesis via RAFT Polymerization and Self-assembly Behavior, Soft Matter, 2014, 10, 383 Kun Wei, Lei Wang, Sixun Zheng*, Organic-inorganic copolymers with double-decker silsesquioxane in the main chains by polymerization via click chemistry, Journal of Polymer Science, Part A: Polymer Chemistry, 2013, 51, 4221 Lei Wang, Chongyin Zhang, Houluo Cong, Lei Li, Sixun Zheng*, Xiuhong Li, Jie Wang, Formation of nanophases in epoxy thermosets containing amphiphilic block copolymers with linear and star-like topologies, Journal of Physical Chemistry B, 2013, 117(27), 8256 Chongyin Zhang, Lei Li, Sixun Zheng*, "Formation and Confined Crystallization of Polyethylene Nanophases in Epoxy Thermosets", Macromolecules, 2013, 46, 2740. Lei Wang, Jingang Li, Lei Li, Sixun Zheng*, Organic-inorganic Hybrid Diblock Copolymer Composed of Poly(ε-caprolactone) and Poly(MA POSS): Synthesis and Its Nanocomposites with Epoxy Resin, Journal of Polymer Science, Part A: Polymer Chemistry, 2013, 51, 2079 Kun Wei, Lei Wang, Sixun Zheng*, Organic-Inorganic Polyurethanes with 3,13-Dihydroxypropyloctaphenyl Double-Decker Silsesquioxane Chain Extender, Polymer Chemistry, 2013, 4, 1501 Houluo Cong, Lei Li, Sixun Zheng*, Poly(N-isopropylacrylamide)-block-poly(vinyl pyrrolidone) Block Copolymer Networks: Synthesis and Rapid Thermoresponse of Hydrogels, Polymer, 2013, 54, 1370. Rentong Yu, Sixun Zheng*, Xiuhong Li, Jie Wang, Reaction-induced Microphase Separation in Epoxy Thermosets Containing Block Copolymers Composed of Polystyrene and Poly(e-caprolactone): Influence of Copolymer Architectures on Formation of Nanophases, Macromolecules, 2012, 45, 9155. Liliang Zhu, Chongyin Zhang, Jin Han, Sixun Zheng*, Formation of Nanophases in Epoxy Thermosets Containing Organic-Inorganic Macrocyclic Molecular Brush with Poly(ε-caprolactone)-block-polystyrene Side Chains, Soft Matter, 2012, 8, 7062. Qinqin Zheng, Sixun Zheng*, From Poly(N-isopropylacrylamide)-block-poly(ethylene oxide)-block- poly(N-isopropylacrylamide) Triblock Copolymer to Poly(N-isopropylacrylamide)-block-poly(ethylene oxide) Hydrogels: Synthesis and Rapid Deswelling and Reswelling Behavior of Hydrogels, Journal of Polymer Science, Part A: Polymer Chemistry, 2012, 50, 1717 Lei Wang, Chongyin Zhang, Sixun Zheng*, Organic-inorganic Poly(hydroxyether of bisphenol A) with Double-decker Silsesquioxane in the Main Chains, Journal of Materials Chemistry, 2011, 21, 19344. Fangping Yi, Rentong Yu, Sixun Zheng*, Self-organized Thermosets from Epoxy and Poly(2,2,2-trifluoroethyl acrylate)-block-poly(glycidyl methacrylate) Diblock Copolymer: Demixing of Reactive Blocks and Thermomechanical Properties, Polymer, 2011, 52, 5669. Rentong Yu, Sixun Zheng*, Morphological Transition from Spherical to Lamellar Nanophases in Epoxy Thermosets Containing Poly(ethylene oxide)-block-poly(ε-caprolactone)-block-polystyrene Triblock Copolymer by Hardeners, Macromolecules, 2011, 44,8546. Ke Zeng, Lei Wang, Sixun Zheng*, Nanostructures and Surface Hydrophobicity of Epoxy Thermosets Containing Hepta(3,3,3-trifluropropyl) Polyhedral Oligomeric Silsesquioxane-capped Poly(hydroxyether of bisphenol A) Telechelics, Journal of Colloid and Interface Science, 2011, 363, 250.

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