崔勇 - 上海交通大学 - 化学化工学院

个人简介

荣誉与奖励国家杰出青年基金（2010）长江学者特聘教授（2012）国家万人计划领军人才（2016）上海市自然科学奖一等奖（2017）(1/2）国家自然科学奖二等奖（2020）(1/5) 个人简历 1993年—1999年博士/物理化学，中国科学院福建物质结构研究所 1999年—2000年博士后，中国科学技术大学 2001年—2002年博士后，美国北卡罗莱纳大学-教堂山分校 2003年—2005年博士后，美国芝加哥大学 2005年—2011年教授/博导，ssss上海交通大学化学化工学院 2011年—2019年特聘教授/博导，上海交通大学化学化工学院 2019年—至今 sss讲席教授/博导，上海交通大学化学化工学院

研究领域

手性金属-有机框架金属-有机框架材料(MOFs)，作为一类新型的可编程的多孔晶态材料，由于迷人的结构以及在多个领域潜在的应用引起了人们的极大兴趣。我们课题组长期致力于通过手性MOF的策略来实现手性小分子催化剂的固相化，以克服传统固体催化剂的瓶颈。基于优势手性配体(M(salen)/Biphenol/Spinol)，我们设计合成了一系列手性配体，继而与不同的金属离子组装得到具有不同拓扑结构和活性位点的手性MOFs。这些手性MOFs可以作为非均相催化剂高效的催化许多不对称转化，比如环氧化/氰化/缩醛和F-C反应。此外，它们还可以作为手性固体分离剂实现外消旋分子和药物的手性分离，比如醇/胺/亚砜。此外，我们还发展了自下而上分级组装/配体交换/超分子积木/多组分的策略来构筑手性MOFs。手性共价有机框架共价有机框架 (COFs)，特别手性共价有机框架 (CCOFs) 因具有规整的孔道结构、大的比表面积、易于调控的功能等优点，在催化、传感、光电等领域具有巨大的潜在应用价值。由于要充分考虑到手性单体的不对称性和CCOFs结晶性的平衡关系CCOFs的合成一直是研究的难点。我们聚焦于新型CCOFs的设计合成与及功能应用，以手性优势配体作为平台，开发出结构新颖、性能独特的CCOFs，并对它们的催化、分离等性能进行研究。手性超分子框架手性超分子框架化合物由于拥有限域的空腔，为其在手性分离、传感以及催化等领域的应用提供了良好的平台。与其他多孔材料相比，这类材料由于其限域空腔的手性微环境与酶的空腔极为相似，往往体现出更为出色的性能。我们旨在利用配位组装的方法将优势手性配体与金属组装并制备出手性的金属-有机组装体。我们的中心任务是理解在液相体系中手性限域空间中的主客体作用并为制备新颖的功能材料提供更多指导。

近期论文

查看导师新发文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

Chiral Reticular Chemistry: A Tailored Approach Crafting Highly Porous and Hydrolytically Robust Metal–Organic Frameworks for Intelligent Humidity Control W. Gong, X. Chen, M. Wahiduzzaman, H. Xie, K. O. Kirlikovali, J. Dong, G. Maurin, O. K. Farha and Y. Cui, J. Am. Chem. Soc., 2024, (doi.org/10.1021/jacs.3c11733) Mixed-Linker Chiral 2D Covalent Organic Frameworks with Controlled Layer Stacking for Electrochemical Asymmetric Catalysis C. Yuan, S. Fu, X. Kang, C. Cheng, C. Jiang, Y. Liu and Y. Cui, J. Am. Chem. Soc., 2023, (doi.org/10.1021/jacs.3c10478) Rational Design and Reticulation of Infinite qbe Rod Secondary Building Units into Metal–Organic Frameworks through a Global Desymmetrization Approach for Inverse C3H8/C3H6 Separation W. Gong, Y. Xie, A. Yamano, S. Ito, E. W. Reinheimer, J. Dong, C. D. Malliakas, D. M. Proserpio, Y. Cui and O. K. Farha, Angew. Chem. Int. Ed., 2023, e202318475. Recent Progress of Chiral Hierarchical Assemblies from a Chinese Perspective W. Gong, W. Wang, J. Dong, X. Pan, Y. Liu, H. Yang, X. Fu and Y. Cui, CCS Chem., 2023, 5, 2736–2759 Modulator-Dependent Dynamics Synergistically Enabled Record SO2 Uptake in Zr(IV) Metal–Organic Frameworks Based on Pyrene-Cored Molecular Quadripod Ligand W. Gong, Y. Xie, A. Yamano, S. Ito, X. Tang, E. W. Reinheimer, C. D. Malliakas, J. Dong, Y. Cui and O. K. Farha, J. Am. Chem. Soc., 2023, (doi:10.1021/jacs.3c09648) The future of metal-organic frameworks and covalent organic frameworks: rational synthesis and customized applications X. Han, W. Zhang, Z. Chen, Y. Liu and Y. Cui, Materials Horizons, 2023, 10, 5337-5342 Cyclodextrin Incorporation into Covalent Organic Frameworks Enables Extensive Liquid and Gas Chromatographic Enantioseparations C. Yuan, Z. Wang, W. Xiong, Z. Huang, Y. Lai, S. Fu, J. Dong, A. Duan, X. Hou, L. Yuan and Y. Cui, J. Am. Chem. Soc., 2023, 145, 34, 18956–18967 Molecular weaving of chicken-wire covalent organic frameworks X. Han, T. Ma, B. L. Nannenga, X. Yao, S. E. Neumann, P. Kumar, J. Kwon, Z. Rong, K. Wang, Y. Zhang, J. A.R. Navarro, R. O. Ritchie, Y. Cui and O. M. Yaghi, Chem, 2023, 9, 2509–2517 Porous metal-organic cage-based membranes L. Jia, X. Tang, Y. Cui and Y. Liu, Sci China Chem, 2023, 66, 8, 2169–2180 Reticular Chemistry in Its Chiral Form: Axially Chiral Zr(IV)-Spiro Metal-Organic Framework as a Case Study W. Gong, X. Chen, K. M. Fahy, J. Dong, Y. Liu, O. K. Farha and Y. Cui, J. Am. Chem. Soc., 2023, 145, 25, 13869–13878 Construction of Monophosphine-Metal Complexes in Privileged Diphosphine-Based Covalent Organic Frameworks for Catalytic Asymmetric Hydrogenation Z. Zheng, C. Yuan, M. Sun, J. Dong, Y. Liu and Y. Cui, J. Am. Chem. Soc., 2023, 145, 11, 6100–6111 Programmed Polarizability Engineering in a Cyclen-Based Cubic Zr(IV) Metal–Organic Framework to Boost Xe/Kr Separation W. Gong, Y. Xie, X. Wang, K. O. Kirlikovali, K. B. Idrees, F. Sha, H. Xie, Y. Liu, B. Chen, Y. Cui and O. K. Farha, J. Am. Chem. Soc., 2023, 145, 4, 2679–2689 Homochiral Porous Metal–Organic Polyhedra with Multiple Kinds of Vertices X. Tang, C. Meng, N. Rampal, A. Li, X. Chen, W. Gong, H. Jiang, D. Fairen-Jimenez, Y. Cui, and Y. Liu, J. Am. Chem. Soc., 2023, 145, 4, 2561–2571 Troger's Base Chemistry in Solution and in Zr(IV)-Based Metal–Organic Frameworks W. Gong, M. Kazem-Rostami, F. A. Son, S. Su, K. M. Fahy, H. Xie, T. Islamoglu, Y. Liu, J. F. Stoddart, Y. Cui and O. K. Farha, J. Am. Chem. Soc., 2022, 144, 22574–22581. Conformational Control of Organocatalyst in Strongly Bronsted-Acidic Metal-Organic Frameworks for Enantioselective Catalysis H. Jiang, X. Zhao, W. Zhang, Y. Liu, H. Li and Y. Cui, Angew. Chem. Int. Ed., 2023, 62, e202214748 (Highlighted by Synfacts 2023, 19, 0186) Planar Chiral [2.2]Paracyclophane-Based Zr(IV) Metal–Organic Frameworks H. Jiang, W. Zhang, B. Hou, Y. Liu and Y. Cui, CCS Chem., 2023, 5, 1635–1643 Challenges and Opportunities for Chiral Covalent Organic Frameworks X. Kang, E. R. Stephens, B. M. Spector-Watts, Z. Li, Y. Liu, L. Liu and Y. Cui, Chem. Sci., 2022, 13, 9811-9832. 2D Covalent Organic Frameworks with cem Topology X. Wang, X. Han, C. Cheng, X. Kang, Y. Liu and Y. Cui, J. Am. Chem. Soc., 2022, 144, 7366-7373. Chiral Metal-Organic Frameworks G. Wei, Z. Chen, J. Dong, Y. Liu and Y. Cui, Chem. Rev., 2022, 122, 9078-9144. Recent Advances of Covalent Organic Frameworks for Chiral Separation B. Hou, Z. Li, X. Kang, H. Jiang, and Y. Cui, Chem. Res. Chin. Univ., 2022, 38, 350-355. Metal–Organic Macrocycles with Tunable Pore Microenvironments for Selective Anion Transmembrane Transport Y. Li, L. Jia, X. Tang, J. Dong, Y. Cui and Y. Liu, Mater. Chem. Front., 2022, 6, 1010-1020. Free-standing Homochiral 2D Monolayers by Exfoliation of Molecular Crystals. J. Dong, L. Liu, C. Tan, Q. Xu, J. Zhang, Z. Qiao, D. Chu, Y. Liu, Q. Zhang, J. Jiang, Y. Han, A. P. Davis and Y. Cui, Nature, 2022, 602, 606-611. (Highlighted by Nature 2022, 602, 582–583) Creating Optimal Pockets in a Clathrochelate-Based Metal-Organic Framework for Gas Adsorption and Separation: Experimental and Computational Studies W. Gong, Y. Xie, T. D. Pham, S. Shetty, F. A. Son, K. B. Idrees, Z. Chen, H. Xie, Y. Liu, R. Q. Snurr, B. Chen, B. Alameddine, Y. Cui and O. K. Farha, J. Am. Chem. Soc., 2022, 144, 3737-3745. Leveraging Chiral Zr(IV)-Based Metal–Organic Frameworks To Elucidate Catalytically Active Rh Species in Asymmetric Hydrogenation Reactions W. Gong, X. Chen, W. Zhang, K. O. Kirlikovali, B. Nan, Z. Chen, R. Si, Y. Liu, O. K. Farha and Y. Cui, J. Am. Chem. Soc., 2022, 144, 3117-3126. Water Sorption Evolution Enabled by Reticular Construction of Zirconium Metal–Organic Frameworks Based on a Unique [2.2]Paracyclophane Scaffold W. Gong, H. Xie, K. B. Idrees, F. A. Son, Z. Chen, F. Sha, Y. Liu, Y. Cui and O. K. Farha, J. Am. Chem. Soc., 2022, 144, 1826-1834. Are Highly Stable Covalent Organic Frameworks the Key to Universal Chiral Stationary Phases for Liquid and Gas Chromatographic Separations? C. Yuan, W. Jia, Z. Yu, Y. Li, M. Zi, L. Yuan and Y. Cui, J. Am. Chem. Soc., 2022, 144, 891-900. (Highlighted by J. Am. Chem. Soc. 2022, 144, 1473–1474) Artificial Biomolecular Channels: Enantioselective Transmembrane Transport of Amino Acids Mediated by Homochiral Zirconium Metal-Organic Cages Y. Li, J. Dong, W. Gong, X. Tang, Y. Liu, Y. Cui and Y. Liu, J. Am. Chem. Soc., 2021, 143, 20939-20951. Two-Dimensional Fluorinated Covalent Organic Frameworks with Tunable Hydrophobicity for Ultrafast Oil-Water Separation Y. Liu, W. Li, C. Yuan, L. Jia, Y. Liu, A. Huang and Y. Cui, Angew. Chem. Int. Ed., 2021, 61, e202113348. Artificial Metal–Peptide Assemblies: Bioinspired Assembly of Peptides and Metals through Space and across Length Scales J. Dong, Y. Liu and Y. Cui, J. Am. Chem. Soc., 2021, 143, 17316-17336. Efficient C2H2/CO2 Separation in Ultramicroporous Metal–Organic Frameworks with Record C2H2 Storage Density W. Gong, H. Cui, Y. Xie, Y. Li, X. Tang, Y. Liu, Y. Cui and B. Chen, J. Am. Chem. Soc., 2021, 143, 14869-14876. (Highlighted by ChemistryViews https://www.chemistryviews.org/details/news/11316859/MetalOrganic_Framework_with_Record_Acetylene_Storage_Density.html) Endohedral functionalization of chiral metal-organic cages for encapsulating achiral dyes to induce circularly polarized luminescence X. Tang, H. Jiang, Y. Si, N. Rampal, W. Gong, C. Cheng, X. Kang, D. F. Jimenez, Y. Cui and Y. Liu, Chem, 2021, 7, 2771–2786. Porous 2D and 3D Covalent Organic Frameworks with Dimensionality-Dependent Photocatalytic Activity in Promoting Radical Ring-Opening Polymerization K. Wang, X. Kang, Y. Chen, X. Han, Y. Liu and Y. Cui, Angew. Chem. Int. Ed., 2021, 60, 19466–19476. Fine-Tuning of Chiral Microenvironments within Triple-Stranded Helicates for Enhanced Enantioselectivity J. Jiao, J. Dong, Y. Li, and Y. Cui, Angew. Chem. Int. Ed., 2021, 60, 16568–16575. Boosting Enantioselectivity of Chiral Molecular Catalysts with Supramolecular Metal-Organic Cages D. Chu, W. Gong, H. Jiang, X. Tang, Y. Cui and Y. Liu, CCS Chem., 2022, 4, 1180–1189. Single-Crystalline Ultrathin 2D Porous Nanosheets of Chiral Metal-Organic Frameworks Y. Liu, L. Liu, X. Chen, Y. Liu, Y. Han and Y. Cui, J. Am. Chem. Soc., 2021, 143, 3509-3518. Metal-Organic Cages with Missing Linker Defects X. Tang, D. Chu, W. Gong, Y. Cui and Y. Liu, Angew. Chem. Int. Ed., 2021, 60, 9099–9105. Highly Specific Coordination-Driven Self-Assembly of 2D Heterometallic Metal-Organic Frameworks with Unprecedented Johnson-type (J51) Nonanuclear Zr-Oxocarboxylate Clusters W. Gong, H. Arman, Z. Chen, Y. Xie, F. A. Son, H. Cui, X. Chen, Y. Shi, Y. Liu, B. Chen, O. K. Farha and Y. Cui, J. Am. Chem. Soc., 2021, 143, 657-663. Crystalline C—C and C=C Bond-Linked Chiral Covalent Organic Frameworks C. Yuan, S. Fu, K. Yang, B. Hou, Y. Liu, J.Jiang and Y. Cui, J. Am. Chem. Soc., 2021, 143, 369-381. Highly Stable Zr(IV)-Based Metal-Organic Frameworks for Chiral Separation in Reversed-Phase Liquid Chromatography H. Jiang, K. Yang, X. Zhao, W. Zhang, Y. Liu, J.Jiang and Y. Cui, J. Am. Chem. Soc., 2021, 143, 390-398. Topological Strain-Induced Regioselective Linker Elimination in a Chiral Zr(IV)-Based Metal-Organic Framework W. Gong, W. Zhang, F. A. Son, K. Yang, Z. Chen, X. Chen, J. Jiang, Y. Liu, O. K. Farha and Y. Cui, Chem, 2021, 7, 190–201. Supramolecular Chirality in Metal–Organic Complexes J. Dong, Y. Liu and Y. Cui, Acc. Chem. Res., 2021, 54, 194-206. Confinement-Driven Enantioselectivity in 3D Porous Chiral Covalent Organic Frameworks B. Hou, S. Yang, K. Yang, X. Han, X. Tang, Y. Liu, J. Jiang and Y. Cui, Angew. Chem. Int. Ed., 2021, 60, 6086–6093. Chiral and Robust Zr(Ⅳ)-Based Metal–Organic Frameworks Built from Spiro Skeletons W. Gong, Y. Liu, and Y. Cui, Faraday Discuss., 2021, 231, 168–180. Synthesis, Structure and Property of Boron-based Metal–Organic Materials Q. Xia, J. Zhang, X. Chen, C. Cheng, D. Dan, X. Tang, H. Li and Y. Cui, Coord. Chem. Rev., 2021, 435, 213783. Coordination-Driven Self-Assembly of Anthraquinone-Based Metal–Organic Cages for Photocatalytic Selective [2 + 2] Cycloaddition Y. Jin, H. Jiang, X. Tang, W. Zhang, Y. Liu and Y. Cui, Dalton Trans., 2021, 50, 8533–8539. A Stable Biocompatible Porous Coordination Cage Promotes in vivo Liver Tumor Inhibition Y. Liang, Y. Fang, Y. Cui and H. Zhou, Nano Res., 2021, 14, 3407-3415.