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研究领域

1、共价有机框架物的功能化及其负载的过渡金属的催化性能研究 2、线性多齿配体与过渡金属的超分子组装研究

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Q.-D. Shu, S.-N. Kong, M.-H. Shu*, Dinuclear double helicates assembled from a bis-bidentate ligand and Cu(I), Cu(II), Ag(I) and Cd(II) salts, Polyhedron, 2014, 72, 103–109. Shuixia Gao, Nan Zhao, Mouhai Shu*, Shunai Che, Palladium nanoparticles supported on MOF-5: A highly active catalyst for a ligand- and copper-free Sonogashira coupling reaction, Applied Catalysis A: General, 2010, 388:196-201. Mouhai Shu,* Chunlai Tu, Weidong Xu, Haibao Jin, and Jie Sun, Reversible Anion Exchanges of Porous Metal-Organic Frameworks: Syntheses and Structures of Silver Complexes with Novel Rigid Tripodal Nitrogen Ligands. Cryst. Growth & Design, 2006, 1890. J. Fan, M.H. Shu, T. Okamura, at al, Solvent effect on the structure and topology of metal-organic frameworks with the rigid tripodal star ligand 1,3,5-tris (1-imidazolyl) benzene and lead(II) nitrate, New J. Chem, 2003, 1307. Shu MH, Walz R, Wu B, et al, New bis(mercaptoimidazolyl)(pyrazolyl) borate ligands and their zinc complex chemistry, Eur. J. Inorg. Chem., 2003, 2502 -2511. M. M. Ibrahim, MH Shu, H. Vahrenkamp, New Tris(thioimidazolyl)borate Ligands and Some Zinc Complexes There of, Eur. J. Inorg. Chem , 2005, 1388-1397. Tesmer M, Shu MH, Vahrenkamp H, Sulfur-rich zinc chemistry: New tris(thioimidazolyl) hydroborate ligands and their zinc complex chemistry related to the structure and function of alcohol dehydrogenase, Inorg. Chem., 2001, 4022-4029. Seebacher J, Shu MH, Vahrenkamp H, The best structural model of ADH so far: a pyrazolylbis(thioimidazolyl)borate zinc ethanol complex, Chem. Commun., 2001, 1026-1027. Shu MH, Sun WY, Duan CY, et al. The influence of the linkage mode between bipyridine units in oligobipyridine ligands on the formation of copper-(I) and -(II) helicates, J. Chem. Soc., Dalton Trans., 1999, 729-734. Shu MH, Duan CY, Sun WY, et al, Synthesis, structure and characterization of novel nickel(II) and iron(II) complexes with a 5,5'-bis[2-(2,2'-bipyridin-6-yl)-ethyl]- 2,2 '-bipyridine ligand, J. Chem. Soc. Dalton Trans., 1999, 2317-2321.

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