龚和贵 - 上海大学

个人简介

Professor of Chemistry, Shanghai University, China (since Dec. 2008) Postdoctoral Fellow, University of North Carolina at Chapel Hill (2005-2008) Ph.D., University of Texas at Austin (1999-2005) M.S., Tsinghua University, China (1995-1998) B.S., Zhengzhou University of Light Industry, China (1991-1995)

研究领域

1. Over the past few years, our group has been working on the development of reductive coupling of two different electrophiles 2. The second research field in our group emphasizes the design of robust H-bond/ion pair-mediated building blocks in aqueous media useful for functional materials and biological studies

近期论文

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Gong, Y.; Qian, Q.; Tong, W.; Gong, H.* “Forging Unactivated Tertiary Alkyl C-O bonds via Zinc-Catalyzed Coupling of Tertiary Alkyl Bromides with Alcohols”. Org. Lett. 2021, In press Xue, W.;* Jia, X.; Wang, X.; Yin, Z.; Gong, H.* “Nickel-catalyzed all-carbon quaternary centers formation with tertiary alkyl electrophiles”, Chem. Soc. Rev. 2021, In Press Liu, J.; Gong, H.;* Zhu, S.* “Nickel-Catalyzed, Regio- and Enantioselective Benzylic Vinylation of Olefins with Vinyl Bromide”, Angew. Chem. Int. Ed. 2021, 59, In Press Ye, Y.; Ma, G.; Yao, K.; Gong, H* "Zn-Mediated Hydrodeoxygenation of Tertiary Alkyl Oxalates", Synlett. 2021, in press (Cluster: Modern Ni-Catalyzed Reactions) DOI: 10.1055/a-1328-0352 Tao, X.; Chen, Y.; Guo, J.; Wang, X.;* Gong, H.* “Preparation of α-Amino Acids via Ni-Catalyzed Reductive Vinylation and Arylation of α-Pivaloyloxy Glycine”, Chem. Sci. 2021, 10, in press (doi.org/10.1039/D0SC05452F) Liu, J.; Ye, Y.; Sessler, J. L.; Gong, H.* “Cross-electrophile Coupling of Activated and Sterically Hindered Alkyl Halides and C-O bonds”, Acc. Chem. Res. 2020, 53, 1833–1845 (DOI:10.1021/acs.accounts.0c00291) Ma, G.; Chen, C.; Talukdar, S.; Zhao, X.; Lei, C.; Gong, H. “Metal Catalyst-Free Photo-Induced Alkyl C-O Bond Borylation of Tertiary Alkyl Oxalates”, Chem. Commun. 2020, 57, 10219-10222 Ye, Y.; Chen, H.; Ma, G.; Gong, H.* “Iron-Catalyzed Reductive Vinylation of Tertiary Alkyl Oxalates with Vinyl Bromides”, Org. Lett. 2020, 22, 2070 Sun, Y.; Gu, J.; Wang, H.; Sessler, J. L.;* Thordason, P.;* Lin, Y.-J.; Gong, H.* "AAAA-DDDD Quadruple H-Bond-Assisted Ionic Interactions: Robust Bis(Guanidinium)/DiCarboxylate Heteroduplexes in Water", J. Am. Chem. Soc. 2019, 141, 20146-20154 Liu, J.; Lei, C.; Gong, H.* "Nickel-Catalyzed Reductive Coupling of Glucosyl Halides with Aryl/Vinyl Halides Enabling β-Selective Preparation of C-Aryl/Vinyl Glucosides", Sci. Chin. Chem., 2019, 62, 1492–1496 Pan, Y.; Gong, Y.; Song, Y.; Tong, W.; Gong, H.* "Deoxygenative Cross-Electrophile Coupling of Benzyl Chloroformates with Aryl Iodide", Org. Biomol. Chem., 2019, 17, 4230–4233 Chen, Y.; Su, L.; Gong, H.* "Cu-Catalyzed and In-Mediated Ester Formation via Carbonylative Coupling of Alkyl Iodides under Balloom CO", Org. Lett., 2019, 21, 4689–4693 Gao, M.; Sun, D.; Gong, H.* "Ni-Catalyzed Reductive C–O Bond Arylation of Oxalates Derived from α-Hydroxy Esters with Aryl Halides", Org. Lett., 2019, 21, 1645–1648 Chen, H.; Ye, Y.; Tong, W.; Fang, J.; Gong, H.* "Formation of Allylated Quaternary Carbon Centers via C–O/C–O Bond Fragmentation of Oxalates and Allyl Carbonates", Chem. Commun., 2020, 56, 454-457 Ye, Y.; Chen, H.; Sessler, J. L.; Gong, H.* "Zn-Mediated Fragmentation of Tertiary Alkyl Oxalates Enabling Formation of Alkylated and Arylated Quaternary Carbon Centers", J. Am. Chem. Soc., 2019, 141, 820–824 Luo, L.; Zhai, X.-Y.; Wang, Y.-W.; Peng, Y.;* Gong, H.* "Divergent Total Syntheses of C3a–C7’ Linked Diketopiperazine Alkaloids (+)-Asperazine and (+)-Pestalazine A Enabled by a Ni-Catalyzed Reductive Coupling of Tertiary Alkyl Chloride", Chem. – Eur. J. , 2019, 25, 989–992 Liu, J. Gong, H.* "Stereoselective Preparation of α‑C‑Vinyl/Aryl Glycosides via Nickel Catalyzed Reductive Coupling of Glycosyl Halides with Vinyl and Aryl Halides", Org. Lett., 2018, 20, 7991–7995 Wang, X.; Ma, G.; Peng, Y; Pitsch, C. E.; Moll, B. J.; Ly, T. D.; Wang, X.;* Gong, H.* "Ni-Catalyzed Reductive Coupling of Electron-Rich Aryl Iodides with Tertiary Alkyl Halides", J. Am. Chem. Soc., 2018, 140, 14490–14497 Yu, Y.; Chen, H.; Qian, Q.; Yao, K.; Gong, H. "An extension of nickel-catalyzed reductive coupling between tertiary alkyl halides with allylic carbonates", Tetrahedron, 2018, 74, 5651–5658 Chen, Y.; Ma, G.;* Gong, H.* "Copper-Catalyzed Reductive Trifluoromethylation of Alkyl Iodides with Togni's Reagent", Org. Lett., 2018, 20, 4677–4680