胡满成 - 陕西师范大学 - 化学化工学院

研究领域

溶液化学；配位化学（1）铷、铯盐-混合溶剂体系相化学，已经完成了100多个三元及四元体系平衡溶解度的测定工作，提出了重稀碱金属专用化学品的检测方法和纯化分离技术，极大地丰富了非水溶剂的溶解度数据；（2）铷、铯盐-混合溶剂体系热力学，采用Pitzer电解质溶液理论模型以及在其基础上发展和完善了的Pitzer-Simonson-Clegg模型对电动势实验结果进行关联求得铷、铯离子的活度系数，从而计算出铷、铯盐在各体系中的标准迁移Gibbs自由能、总介质效应等热力学性质；（3）稀有碱金属配位化学，在对Rb/Cs盐类与NTO、ATZ等含能材料所形成配合物研究中发现，它们在新型高能钝感炸药和含能催化剂中具有重要作用。

近期论文

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Jing Tang, Shu'ni Li, Quanguo Zhai, Yucheng Jiang, Mancheng Hu*. Osmotic and activity coefficient investigation on the CsNO3+methanol + water and CsNO3+ ethanol + water ternary systems at 298.15 K. J. Mol. Liq., 2014, 195, 205. Ying Xu, Shu’ni Li, Quanguo Zhai, Yucheng Jiang, Mancheng Hu*. Investigation on the thermodynamic properties of KCl/CsCl + NaCl + CH3OH + H2O quaternary systems at 298.15 K. J. Ind. Eng. Chem., 2014, 20, 2159. Ying Xu, Shuni Li, Quanguo Zhai, Yucheng Jiang, Mancheng Hu*. Thermodynamic studies on CsF/RbF in N,N-dimethylformamide/N,N-dimethylacetamide + H2O mixtures at T = 298.15 K. J. Chem. Thermodyn., 2014, 77, 71. Dandan Zhao, Shu’ni Li*, Quanguo Zhai, Yucheng Jiang, Mancheng Hu*. Solid–liquid equilibrium (SLE) of the N,N-dimethylacetamide (DMA) + MCl (M = Na, K, Rb, and Cs) + water ternary systems at multiple temperatures. J. Chem. Eng. Data, 2014, 59, 1423. Dandan Zhao, Shu’ni Li, Quanguo Zhai, Yucheng Jiang, Mancheng Hu*. Solution behavior of {(formamide/N-methylformamide/ N,N-dimethylformamide) + CsCl + water} ternary systems at multiple temperatures. J. Chem. Thermodyn., 2014, 78, 134. Huiying Zhang, Shuni Li, Quanguo Zhai, Yucheng Jiang, Mancheng Hu*. Solubilities, densities, and refractive indices for the ternary systems 1,2-propylene glycol + MNO3 + H2O (M = Na, K, Rb, Cs) at 25° and 35 °C. Chem. Eng. Commun., 2014, 201, 323. Yanjie Li, Shu’ni Li, Quanguo Zhai, A. Marcilla, Yucheng Jiang, Mancheng Hu*. Solubility, density, refractive index, and viscosity for the polyhydric alcohol + CsBr + H2O ternary systems at different temperatures. J. Chem. Eng. Data, 2013, 58, 1577. Lei Ma, Shuni Li,* Quanguo Zhai, Yucheng Jiang, Mancheng Hu*. Thermodynamic Study of RbF/CsF in amino acid aqueous solution based on the Pitzer, modified Pitzer, and extended Debye−Hückel models at 298.15 K by a potentiometric method. Ind. Eng. Chem. Res., 2013, 52, 11767. Yanping Du, Shu’ni Li, Quanguo Zhai, Yucheng Jiang, Mancheng Hu*. Activity coefficients in quaternary systems at 298.15 K: RbCl + MeOH + EtOH + H2O and CsCl + MeOH + EtOH + H2O systems. J. Chem. Eng. Data, 2013, 58, 2545. Jia Lu, Shu’ni Li*, Quanguo Zhai, Yucheng Jiang, Mancheng Hu*. Activity coefficient determination for the ternary systems CsCl in N-methylformamide or urea + water mixtures at T = 298.15 K, J. Solution Chem., 2013, 42, 1782.