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Chen, Q. A.; Cruz, F. A.; Dong, V. M. "Alkyne Hydroacylation: Switching Regioselectivity by Tandem Ruthenium Catalysis." J. Am. Chem. Soc. ASAP.
Murphy, S. K.; Park, J.-W.; Cruz, F. A.; Dong, V. M. "Rh-catalyzed C-C bond cleavage by transfer hydroformylation." Science 2015, 2, 56.
Thanks to Clark Landis for the perspective in Science.
Read the highlight from C&E News.
Read the highlight in Korean from Dong-A Science.
Whittaker, A. M.; Dong, V. M. "Ni-Catalyzed Dehydrogenative Cross-Coupling: Direct Transformation of Aldehydes to Esters and Amides." Angew. Chem. Int. Ed. 2015, 54, 1312.
Murphy, S. K.; Bruch, A.; Dong, V. M. "Mechanistic Insights into Hydroacylation with Non-chelating Aldehydes and 2-Vinylphenols." Chem. Sci. 2015, 6, 174. Edge Article.
Oldenhuis, N. J.; Dong, V. M.; Guan, Z. "From Racemic Alcohols to Enantiopure Amines: Ru-Catalyzed Diastereoselective Amination." J. Am. Chem. Soc. 2014, 136, 12548.
Kou, K. G. M.; Le, D. N.; Dong, V. M. "Rh(I)-Catalyzed Intermolecular Hydroacylation: Enantioselective Cross-Coupling of Aldehydes and Ketoamides." J. Am. Chem. Soc. 2014, 136, 9471.
Chen, I.-H.; Kou, K. G. M.; Le, D. N.; Rathbun C. M.; Dong, V. M. "Recognition and Site-Selective Transformation of Monosaccharides Using Copper(II) Catalysis." Chem. Eur. J. 2014, 20, 5013.
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Chen, Q. A.; Kim, D. K.; Dong, V. M. "Regioselective Hydroacylation of 1,3-Dienes by Cobalt-Catalysis." J. Am. Chem. Soc. 2014, 136, 3772.
Murphy, S. K.; Bruch, A.; Dong, V. M. "Substrate-Directed Hydroacylation: Rh-Catalyzed Coupling of Vinyl Phenols and Non-Chelating Aldehydes." Angew. Chem. Int. Ed. 2014, 53, 2455.
Dornan, P. K.; Kou, K. G. M.; Houk K. N.; Dong, V. M. "Dynamic Kinetic Resolution of Allylic Sulfoxides by Rh-Catalyzed Hydrogenation: A Combined Theoretical and Experimental Mechanistic Study." J. Am. Chem. Soc. 2014, 136, 291.
Murphy, S. K.; Dong, V. M. "Enantioselective Ketone Hydroacylation using Noyori's Transfer Hydrogenation Catalyst." J. Am. Chem. Soc. 2013, 135, 5553.
von Delius, M.; Le, C. M.; Dong, V. M. "Rhodium-Phosphoramidite Catalyzed Alkene Hydroacylation: Mechanism and Octaketide Natural Product Synthesis."
J. Am. Chem. Soc. 2012, 134, 15022.
Murphy, S. K.; Coulter, M. M.; Dong, V. M. "β-Hydroxy Ketones Prepared by Regioselective Hydroacylation." Chem. Sci. 2012, 3, 355.
Murphy, S. K.; Petrone, D. A.; Coulter, M. M.; Dong, V. M. "Catalytic Hydroacylation as an Approach to Homoaldol Products." Org. Lett. 2011, 13, 6216.
Yeung, C. S.; Hsieh, T. H. H.; Dong, V. M. "Ru-catalyzed Activation of sp3 C–O Bonds: O- to N-Alkyl Migratory Rearrangement in Pyridines and Related Heterocycles."
Chem. Sci. 2011, 2, 544.
Top ten most accessed articles in December 2010.
Khan, H. A.; Kou, K. G. M.; Dong, V. M. "Nitrogen-directed Ketone Hydroacylation: Enantioselective Synthesis of Benzoxazepinones and Benzoxazecinones."
Chem. Sci. 2011, 2, 407.
Featured on the cover with artwork by Peter Dornan.
Top ten most accessed articles in December 2010.
Zhao, X.; Dong, V. M. "Carbon-Sulfur Reductive Elimination from Pd(IV) Sulfinate Complexes." Angew. Chem. Int. Ed. 2011, 50, 932.
Coulter, M. M.; Kou, K. G. M.; Galligan, B.; Dong, V. M. "Regio- and Enantioselective Intermolecular Hydroacylation: Substrate-Directed Addition of Salicylaldehydes to Homoallylic Sulfides." J. Am. Chem. Soc. 2010, 132, 16330.
Phan, D. H. T.; Kou, K. G. M.; Dong, V. M. "Enantioselective Desymmetrization of Cyclopropenes by Hydroacylation." J. Am. Chem. Soc. 2010, 132, 16354.
Coulter, M. M.; Dinglasan, J.; Goh, J. B.; Nair, S.; Anderson, D. J.; Dong, V. M. "Preparing Water-Dispersed Palladium Nanoparticles via Polyelectrolyte Nanoreactors." Chem. Sci. 2010, 1, 772.
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Yeung, C. S.; Zhao, X.; Borduas, N.; Dong, V. M. "Pd-Catalyzed ortho-Arylation of phenylacetamides, benzamides, and anilides with simple arenes using sodium persulfate." Chem. Sci. 2010, 1, 331.
Top ten most accessed articles in August 2010.
Zhao, X.; Yeung, C. S.; Dong, V. M. "Palladium-Catalyzed Ortho-Arylation of O-Phenylcarbamates with Simple Arenes and Sodium Persulfate." J. Am. Chem. Soc. 2010, 132, 5837.
Li, Y.; Jardine, K. J.; Tan, R.; Song, D.; Dong, V. M. "Palladium-Catalyzed Intramolecular Carboesterification of Olefins: A Formal [3+2] Cycloaddition." Angew. Chem. Int. Ed. 2009, 48, 9690.
Selected by the editors as a "Hot Paper".
Phan, D. H. T.; Kim, B.; Dong, V. M. "Phthalides by Rhodium-Catalyzed Ketone Hydroacylation."
J. Am. Chem. Soc. 2009, 131, 15608.
Read the highlight from SYNFACTS.
Read the highlight in Angewandte by Michael Willis.
Coulter, M. M.; Dornan, P. K.; Dong, V. M. "Rh-Catalyzed Intramolecular Olefin Hydroacylation: Enantioselective Synthesis of Seven- and Eight-Membered Heterocycles."
J. Am. Chem. Soc. 2009, 131, 6932.
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Zhao, X.; Dimitrijević, E.; Dong, V. M. "Palladium-Catalyzed C–H Bond Functionalization with Arylsulfonyl Chlorides." J. Am. Chem. Soc. 2009, 131, 3466.
Shen, Z.; Dornan, P. K.; Khan, H. A.; Woo, T. K.; Dong, V. M. "Mechanistic Insights into the Rhodium-Catalyzed Intramolecular Ketone Hydroacylation." J. Am. Chem. Soc. 2009, 131, 1077.
Shen, Z.; Dong, V. M. "Benzofurans Prepared by C-H Bond Functionalization with Acylsilanes." Angew. Chem. Int. Ed. 2009, 48, 784.
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Yeung, C. S.; Dong, V. M. "Beyond Aresta’s Complex: Ni- and Pd-Catalyzed Organozinc Coupling to CO2." J. Am. Chem. Soc. 2008, 130, 7826.
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Read the highlight in Angewandte by Martin and Correa.
Li, Y.; Song, D.; Dong, V. M. "Palladium-Catalyzed Olefin Dioxygenation."
J. Am. Chem. Soc. 2008, 130, 2962.
Read the highlight from SYNFACTS.
Shen, Z.; Khan, H. A.; Dong, V. M. "Rh-Catalyzed Carbonyl Hydroacylation: An Enantioselective Approach to Lactones." J. Am. Chem. Soc. 2008, 130, 2916.
See the highlight in Chemistry World featuring this work: James Mitchell Crow, "Rhodium fast tracks route to lactones."
Oldenhuis, N. J.; Dong, V. M.; Guan, Z. "Catalytic acceptorless dehydrogenations: Ru-Macho catalyzed construction of amides and imines." Tetrahedron 2014, 70, 4213.
[Sarah Reisman]
Invited contribution in honor of Sarah Reisman.
Phan, D. H. T.; Dong, V. M. "Silver-catalyzed ring-opening of cyclopropenes: preparation of tertiary α-branched allylic amines." Tetrahedron 2013, 69, 5726.
[Melanie Sanford]
Invited contribution in honor of Melanie Sanford.
Dornan, P. K.; Leung, P. L.; Dong, V. M. "Synthesis of C3- and C2-symmetric tris- and bis-sulfoxide ligands by asymmetric oxidation." Tetrahedron 2011, 67, 4378.
[Dean Toste]
Invited contribution in honor of Dean Toste.
Borduas, N.; Lough, A. J.; Dong, V. M. "Cyclopalladation of N-Phenylbenzamides: Synthesis and Structure of Bimetallic Palladium(II)-Complexes." Inorg. Chem. Acta. 2011, 369, 247.
[Robert Bergman]
Invited contribution in honor of Robert Bergman.
Yeung, C. S.; Dong, V. M. "Pd-catalyzed ortho-Arylation of N-Aryloxazolidinones with Simple Arenes Using Sodium Persulfate." Synlett. 2011, 7, 974.
[Xiyan Lu]
Invited contribution in honor of Xiyan Lu and Li-Xin Dai.
Hsieh, T. H. H.; Dong, V. M. "Indole Synthesis: Palladium-Catalyzed C–H Bond Amination via Reduction of Nitroalkenes with Carbon Monoxide." Tetrahedron 2009, 65, 3062.
[Justin Du Bois]
Invited contribution in honor of Justin Du Bois's Young Investigator Award.
Highlights and Reviews
Murphy, S. K.; Dong, V. M. "Catalytic Enantioselective hydroacylation of olefins with rhodium catalysts." Chem. Commun. 2014, 50, 13645.
Yeung, C. S.; Dong, V. M. "Catalytic Making C-C Bonds from Carbon Dioxide via Transition-Metal Catalysis." Topics in Catalysis. 2014, 57, 1342.
Coulter, M. M.; Dong, V. M. "Transition Enantioselective Synthesis of Lactones via Rh-Catalyzed Ketone Hydroacylation" in Asymmetric Synthesis II: More Methods and Applications, M. Christmann; S. Brase; Wiley-VCH: New York, 2012; Chapter 35.
Gladysz, J.; Ball, Z. T.; Bertrand, G.; Blum, S. A.; Dong, V. M.; Dorta, R.; Hahn, F. E.; Humphrey, M. G.; Jones, W. D.; Klosin, J.; Manners, I.; Marks, T. J.; Mayer, J. M.; Rieger, B.; Ritter, J. C.; Sattelberger, A. P.; Schomaker, J. M.; Yam V. W. "Organometallics Roundtable 2011." Organometallics 2012, 31, 1.
Yeung, C. S.; Dong, V. M. "Catalytic Dehydrogenative Cross-Coupling: Forming Carbon-Carbon Bonds by Oxidizing Two Carbon-Hydrogen Bonds." Chem. Rev. 2011, 111, 1215.
Yeung, C. S.; Dong, V. M. "New Direction in Enantioselective Catalysis: Scaffolding Ligands in Olefin Hydroformylation", Highlight article, Angew. Chem. Int. Ed. 2011, 50, 809.
Yeung, C. S.; Dornan, P. K.; Dong, V. M. "Transition Metal Catalyzed Approaches to Lactones Involving C-O Bond Formation" in Catalyzed Carbon-Heteroatom Bond Formation, A. K. Yudin; Wiley-VCH: New York, 2010; Chapter 2.