Borovik, A. S. - University of California, Irvine

研究领域

Inorganic and Organometallic/Organic and Synthetic

近期论文

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Cook, S. A.; Hill, E. A.; Borovik, A.S. "Synthetic Chemistry as a Window into Biology." Biochemistry, submitted. Gupta, R.; Taguchi, T.; Kaiser-Lassalle, B.; Yano, J.; Hendrich, M. P.; Borovik, A. S. "High Spin Mn–Oxo Complexes and their Relevance to the Oxygen Complex within Photosystem II," Proc. Natl. Acad. Sci USA 2015, 112, 0000. Lau, N.; Ziller, J. W.; Borovik, A. S. "Sulfonamido Tripods: Tuning Redox Potentials via Ligand Modifications," Polyhedron 2015, 84, 777–782. Cook, S. A.; Ziller, J. W.; Borovik, A. S. "Iron(II) Complexes Supported by Sulfonamido Tripodal Ligands: Endogenous versus Exogenous Substrate Oxidation," Inorg. Chem. 2014, 53, 11029-11035. Taguchi, T.; Stone, K.; Gupta, R.; Kaiser-Lassalle, B.; Yano, J.; Hendrich, M. P.; Borovik, A. S. "Preparation and Properties of an MnIV–hydroxide Complex: Proton and Electron Transfer at a Mononuclear Manganese Site and its Relationship to the Oxygen Evolving Complex Within Photosystem II," Chem. Sci., 2014, 5, 3064-3071. Sickerman, N. S.; Peterson, S. M.; Ziller, J. W.; Borovik, A. S. "Synthesis, structure, and reactivity of FeII/III –NH3 complexes bearing a tripodal sulfonamido ligand," Chem. Commun. 2014, 50, 2515–2517. [invited Communication for thematic issue on Small Molecule Activation] Rolf Mitzner, Jens Rehanek, Jan Kern, Sheraz Gul, Johan Hattne, Taketo Taguchi, Roberto Alonso-Mori, Rosalie Tran, Christian Weniger, Henning Schröder, Wilson Quevedo, Hartawan Laksmono, Raymond G. Sierra, Guangye Han, Benedikt Lassalle-Kaiser, Sergey Koroidov, Katharina Kubicek, Simon Schreck, Kristjan Kunnus, Maria Brzhezinskaya, Alexander Firsov, Michael P. Minitti, Joshua J. Turner, Stefan Moeller, Nicholas K. Sauter, Michael J. Bogan, Dennis Nordlund, William F. Schlotter, Johannes Messinger, A. S. Borovik, Simone Techert, Frank M. F. de Groot, Alexander Föhlisch, Alexei Erko, Uwe Bergmann, Vittal K. Yachandra, Philippe Wernet, Junko Yano "Mn L-edge X-ray Absorption Spectroscopy of Dilute Systems Relevant to Photosystem II Using a X-ray Free Electron Laser," J. Phys. Chem. Let. 2013, 4, 3641-3647. Marsh, D. A.; Yan, W.; Liu, Y.; Hemminger, J. C.; Penner, R. M.; Borovik, A. S. "Water Oxidation using a Cobalt Monolayer Prepared by Underpotential Deposition," Langmuir 2013, 29, 14728–14732. Gupta, R.; Taguchi, T.; Borovik, A.S.; Hendrich, M. P. "Characterization of Monomeric MnII/III/IV Complexes from X- and Q-band Dual Mode EPR Spectroscopy," Inorg. Chem. 2013, 52, 12568-12575. Usharani, D.; Lacy, D. C; Borovik, A. S; Shaik, S. "Dichotomous Hydrogen Atom Transfer vs. Proton Coupled Electron Transfer During Activation of X–H Bonds (X = N, O, C) by Non-Heme Iron-Oxo Complexes of Variable Basicity," J. Am. Chem. Soc. 2013, 135, 17090–17104. Sano, Y.; Weitz, A. C.; Ziller, J. W.; Hendrich, M. P.; Borovik, A. S. "Unsymmetrical Bimetallic Complexes with MII–(μ-OH)–MIII Cores (MIIMIII = FeIIFeIII, MnIIFeIII, MnIIMnIII): Structural, Magnetic, and Redox Properties," Inorg. Chem. 2013, 52, 10229-10231. Cook, S.; Borovik, A. S. "Inorganic chemistry: Deconstructing water oxidation," Nature Chem. 2013, 5, 259–260. [Invited Contribution] Park, Y. J.; Cook, S.; Sickerman, N. S.; Sano, Y.; Ziller, J. W.; Borovik, A. S. "Heterobimetallic Complexes with MIII–(μ-OH)–MII Cores (MIII = Fe, Ga, Mn; MII = Ca, Sr and Ba): Structural, Kinetic, and Redox Properties," Chem. Sci. 2013, 4, 717–726. Lacy, D. C.; Mukherjee, J.; Lucas, R. L.; Powell, D. R.; Day, V. W.; Borovik, A. S. "Complexes with Varying Intramolecular Hydrogen Bonding Networks," Polyhedron 2013, 44, 261–267. [Invited Article in Honor of the 100 Year Anniversary Alfred Werner’s Noble Prize] Sickerman, N. S.; Henry, R. M.; Ziller, J. W.; Borovik, A. S. "Preparation and Structural Properties of InIII–OH Complexes," Polyhedron 2013, 58, 65–70. [Invited Article in Honor of Michelle Millar]