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个人简介

Basells Visiting Scholar, 2012 Thieme Synlett-Synthesis Journal Award, 2009 (international) NSF CAREER Award, 2008 UC-Berkeley Teaching Effectiveness Award, 2005 (campus-wide) UC-Berkeley Outstanding Graduate Instructor, 2004 NSF Graduate Fellow, 2000-2003 Hertz Foundation Grant, 2000

研究领域

Inorganic and Organometallic/Organic and Synthetic/Physical Chemistry and Chemical Physics/Polymer/Materials/Nanoscience

近期论文

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(23) Hirner, J. J.; Roth, K. E.; Shi, Y.; Blum, S. A. "Mechanistic Studies of Azaphilic versus Carbophilic Activation by Gold(I) in the Gold/Palladium Dual-Catalyzed Rearrangement of Alkenyl Vinyl Aziridines." Organometallics 2012, 31, 6943. Cornell, T. P.; Shi, Y.; Blum, S. A. "Synthesis of Alkenylgold(I) Compounds via Sequential Hydrozirconation and Zirconium to Gold Transmetalation." Organometallics 2012, 31, 5990. Esfandiari, N. M.; Wang, Y.; Bass, J. Y.; Blum, S. A. "Deconvoluting Subensemble Chemical Reaction Kinetics of Platinum–Sulfur Ligand Exchange Detected with Single-Molecule Fluorescence Microscopy." Inorg. Chem. 2011, 50, 9201. Esfandiari, N. M.; Blum, S. A. "Homogeneous vs Heterogeneous Polymerization Catalysis Revealed by Single-Particle Fluorescence Microscopy." J. Am. Chem. Soc. 2011, 133, 18145. Roth, K. E.; Blum, S. A. "Direct Observation of Gold/Palladium Transmetalation in an Organogold Heck Reaction," Organometallics 2011, 30, 4811. Esfandiari, N. M.; Wang, Y.; Bass, J. Y.; Blum, S. A. "Deconvoluting Subensemble Chemical Reaction Kinetics of Platinum–Sulfur Ligand Exchange Detected with Single-Molecule Fluorescence Microscopy," Inorg. Chem. 2011, asap. Hirner, J. J.; Shi, Y.; Blum, S. A. "Organogold Reactivity with Palladium, Nickel, and Rhodium: Transmetalation, Cross-Coupling, and Dual Catalysis," Acc. Chem. Res. 2011, 44, 603. Shi, Y.; Blum, S. A. "Gold and Rhodium Transmetalation: Mechanistic Insights and Dual-Metal Reactivity," Organometallics 2011, 30, 1776. Hirner, J. J.; Blum, S. A. "Nickel-Catalyzed Cross-Coupling of Organogold Reagents," Organometallics 2011, 30, 1299. Esfandiari, N. M.; Wang, Y.; McIntire, T. M.; Blum, S. A. "Real-Time Imaging of Platinum-Sulfur Ligand Exchange Reactions at the Single-Molecule Level via a General Chemical Technique," Organometallics 2011, 30, 2901. Esfandiari, N. M.; Wang, Y.; Bass, J. Y.; Cornell, T. P.; Otte, D. A. L.; Cheng, M. H.; Hemminger, J. C.; Mcintire, T. M.; Mandelshtam, V. A.; Blum, S. A. "Single-Molecule Imaging of Platinum Ligand Exchange Reaction Reveals Reactivity Distribution." J. Am. Chem. Soc. 2010, 132, 15167-15169. Roth, K. E.; Blum, S. A. "Relative Kinetic Basicities of Organogold Compounds." Organometallics 2010, 29, 1712. Shi, Y.; Roth, K. E.; Ramgren, S. D.; Blum, S. A. "Catalyzed Catalysis Using Carbophilic Lewis-Acidic Gold and Lewis-Basic Palladium: Synthesis of Substituted Butenolides and Isocoumarins." J. Am. Chem. Soc. 2009, 131, 18022. Lim, S. G.; Blum, S. A. "A General Fluorescence Resonance Energy Transfer (FRET) Method for Observation and Quantification of Organometallic Complexes under Reaction Conditions." Organometallics 2009, 28, 4643. Shi, Y.; Ramgren, S. D.; Blum, S. A. "Palladium-Catalyzed Carboauration of Alkynes and Palladium/Gold Cross-Coupling." Organometallics 2009, 28, 1275. Canham, S. M.; Bass, J. Y.; Navarro, O.; Lim, S.-G.; Das, N.; Blum, S. A. "Toward the Single-Molecule Investigation of Organometallic Reaction Mechanisms: Single-Molecule Imaging of Fluorophore-Tagged Palladium(II) Complexes." Organometallics 2008, 27, 2172. Shi, Y.; Peterson, S. M.; Haberaecker, W. W., III; Blum, S. A. "Alkynes as Stille Reaction Pseudohalides: Synthesis of Tri- and Tetra-Substituted Olefins." J. Am. Chem. Soc. 2008, 130, 2168. Lalic, G.; Blum, S. A.; Bergman, R. G. "Zirconium-Mediated SN2' Substitution of Allylic Ethers: Regio- and Stereospecific Formation of Protected Allylic Amines." J. Am. Chem. Soc. 2005, 127, 16790-16791. Blum, S. A.; Rivera, V. A.; Ruck, R. T.; Michael, F. E.; Bergman, R. G. "Synthetic and Mechanistic Studies of Strained Heterocycle Opening Reactions Mediated by Zirconium(IV) Imido Complexes." Organometallics 2005, 24, 1647-1659. Blum, S. A.; Bergman, R. G. "Nitro and Nitroso Metathesis Reactions with Monomeric Zirconium Imido Complexes." Organometallics 2004, 23, 4003-4005. Blum, S. A.; Tan, K. L.; Bergman, R. G. "The Application of Physical Organic Methods to the Investigation of Organometallic Reaction Mechanisms." J. Org. Chem. 2003, 68, 4127-4137. Blum, S. A.; Walsh, P. J.; Bergman, R. G. "Epoxide-Opening and Group-Transfer Reactions Mediated by Monomeric Zirconium Imido Complexes." J. Am. Chem. Soc. 2003, 125, 14276-14277. Blum, S. A.; Bergman, R. G.; Ellman, J. A. "Enantioselective Oxidation of Di-tert-Butyl Disulfide with a Vanadium Catalyst: Progress Toward Mechanism Elucidation." J. Org. Chem. 2003, 68, 150-155.

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