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个人简介

学习经历 1998.9-2002.7 北京大学化学与分子工程学院,获理学学士学位 2003.8-2007.8 香港中文大学化学系,获博士学位 工作经历 2002.8-2003.7 北京大学物理化学研究所 研究助理 2007.9-2009.9 美国犹他大学化学系 博士后 2009.11-2022.6 清华大学化学系 历任副研究员,准聘、长聘副教授 2022.7至今 清华大学化学系 长聘教授

研究领域

有机金属簇合物的可控合成与反应性质研究; 手性金属簇合成及其应用研究; 金属簇超分子组装与簇基功能材料合成。

近期论文

查看导师新发文章 (温馨提示:请注意重名现象,建议点开原文通过作者单位确认)

“Mechanistic Insights into Multisilver-Mediated Synergistic Activation of Terminal Alkynes” Wan Wang, Xiao-Yi Zhai, and Liang Zhao*, Inorg. Chem. 2023, 62, 1414–1422. DOI: 10.1021/acs.inorgchem.2c03464. “Metal-ligand cooperative effect on intramolecular electron transfer in macrocycle-encircled copper-oxygen species” Siqi Zhang, Liang Zhao*, CCS Chem. 2022, DOI: 10.31635/ccschem.022.202202356. “Stepwise Polymetalation around A sp3 Benzyl Carbon Atom” Kui Xiao, Cong Jin, Keting Zhou, Wan Wang*, Liang Zhao*, Organometallics, 2022, 41, 3493-3498. DOI: 10.1021/acs.organomet.2c00467. "Pro-oxidant response and accelerated ferroptosis caused by synergetic Au(I) release in hypercarbon-centered gold(I) cluster prodrugs" Kui Xiao, Niyuan Zhang, Feifei Li, Dayong Hou, Xiaoyi Zhai, Wanhai Xu*, Gelin Wang*, Hao Wang*, Liang Zhao*, Nat. Commun. 2022, 13, 4669. DOI: 10.1038/s41467-022-32474-y “Pyridine dicarbanion-bonded Ag13 organometallic nanoclusters: synthesis and on-surface oxidative coupling reaction” Cui-Cui Li, Siqi Zhang, Jian Tang, Ruijun Jian, Yu Xiaa, Liang Zhao*, Chem. Sci. 2022, 13, 8095-8103 DOI:10.1039/d2sc00989g “Unraveling the Structural Development of Peptide-Coordinated Iron-Sulfur Clusters: Prebiotic Evolution and Biosynthetic Strategies” Yijun Dong, Siqi Zhang*, Liang Zhao*, Chin. J. Chem. 2022, 40, 1478-1491. DOI: 10.1002/cjoc.202100892. “Structural Control and Chiroptical Response in Intrinsically Tetra- and Pentanuclear Chiral Gold Clusters” Jian Tang, Liang Zhao*, Inorg. Chem. 2022, 61, 11, 4541-4549. DOI:10.1021/acs.inorgchem.2c00256. “Multiresponsive Luminescent Behaviorsof Assembled Spirocyclic Nonanuclear Silver(I) Clusters” Han Wu, Siqi Zhang, Liang Zhao*, CCS Chem, 2022, 4, 3364-3377. DOI: 10.31635/ccschem.021.202101229 “Photoluminescence enhancement by controllable aggregation and polymerization of octanuclear gold clusters” Biao Yang, Han Wu, Liang Zhao*, Chem. Commun. 2021, 57, 5770-5773. DOI:10.1039/D1CC01162F “Assembly-Induced Strong Circularly Polarized Luminescence of Spirocyclic Chiral Silver(I) Clusters” Han Wu, Xin He, Biao Yang, Cui-Cui Li, Liang Zhao*, Angew. Chem. Int. Ed. 2021, 60, 1535-1539. DOI:10.1002/anie.202008765 2016-2020 “Low Valent Palladium Clusters: Synthesis, Structures and Catalytic Applications” Qian Liu, Liang Zhao*,Chin. J. Chem. 2020, 38, 1897-1908. DOI: 10.1002/cjoc.202000378 “Ion-Pairing Chirality Transfer in Atropisomeric Biaryl-Centered Gold Clusters” Kui Xiao, Yang Xue, Biao Yang, Liang Zhao*, CCS Chem. 2020, 2, 555-565. DOI: 10.31635/ccschem.020.202000225 “Polynuclear organometallic clusters: synthesis, structure, and reactivity studies” Jian Tang, Liang Zhao*,Chem. Commun. 2020, 56, 1915-1925. DOI:10.1039/C9CC09354K “Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums” Kui Xiao, Yu Zhao, Jun Zhu*, Liang Zhao*, Nat. Commun. 2019, 10, 5639, DOI: 10.1038/s41467-019-13663-8 “A merged copper(I/II) cluster isolated from Glaser coupling” Siqi Zhang, Liang Zhao*, Nat. Commun. 2019, 10,4848, DOI: 10.1038/s41467-019-12889-w “Pentanuclear Gold(I) Cluster with an Axially Chiral Biaryl Center: Synthesis and Chiral Transformation” Yang Xue, Liang Zhao*, Chin. J. Chem. 2019, 37, 667-671. DOI: 10.1002/cjoc.201900138 “Bonded to Carbon or Nitrogen? This is a Question on the Regioselectivity in Hyperconjugative Aromaticity” Tingting Sun, Ping Guo, Qiong Xie, Liang Zhao*, Jun Zhu*, J. Org. Chem. 2019, 84, 3881-3886. DOI:10.1021/acs.joc.8b02996 “Synthesis, Structure and Properties of C(sp2)-Centered Homo- and Hetero-nuclear Gold Complexes” Cui-Cui Li, Liang Zhao*, Chin. J. Chem. 2019, 37, 276-291. DOI: 10.1002/cjoc.201800548 “Probing the Most Aromatic and Antiaromatic Pyrrolium Rings by Maximizing Hyperconjugation and Push–Pull Effect” Tingting Sun, Qiong Xie, Liang Zhao, Jun Zhu*, Chem. Asian J. 2018, 13, 1419-1423. DOI: 10.1002/asia.201800179 “Macrocycle-encircled polynuclear metal clusters: Controllable synthesis, reactivity studies, and applications” Siqi Zhang, Liang Zhao*, Acc. Chem. Res. 2018, 51, 2535-2545. DOI: 10.1021/acs.accounts.8b00283 “Temperature dependent chiroptical response of sigmoidal gold clusters: probing the stability of chiral metal clusters” Ping Guo, Biao Yang, Li Zhang, Liang Zhao*, Chem. Sci. 2018, 9, 5614-5622. DOI: 10.1039/C8SC00344K “Synthesis of stable polymetalated aromatic complexes through metal–macrocycle capsuletriggered cyclization” Xin He, Yang Xue, Cui-Cui Li, Yuechao Wang, Hong Jiang, Liang Zhao*, Chem. Sci. 2018, 9, 1481-1487. DOI:10.1039/C7SC04503D “Molecular cage-bridged plasmonic structures with well-defined nanogaps as well as the capability of reversible and selective guest trapping” Chen Wang, Li Tian, Wei Zhu, Shiqiang Wang, Ning Gao, Kang Zhou, Xianpeng Yin, Wanlin Zhang, Liang Zhao, Guangtao Li*, Chem. Sci. 2018, 9, 889-895. DOI:10.1039/C7SC03536E “Chiral metal cluster and nanocluster complexes and their application in asymmetric catalysis” Qiong-You Zhang, Liang Zhao*,Tetrahedron Lett. 2018, 59, 310-316. DOI:10.1016/j.tetlet.2017.12.006 “Macrocyclic-ligand Induced Synthesis of Aryl Ethynides with Divergent Silver(I) Clusters” Guangmian Ji, Siqi Zhang, Sam C. W. Hau, Liang Zhao*, Chin. J. Chem. 2017, 35, 1824-1828. DOI: 10.1002/cjoc.201700481

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