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个人简介

学历教育及博士后经历 学士学位(BSc): 清华大学化学与化学工程系(1979-84) 硕士学位(MSc): 清华大学化学系(1984-87) 博士学位(PhD): 伦敦大学(英国)(King’s College London,1992-95) 博士后(Postdoc): 伊利诺伊大学(美国)(香槟分校 UIUC, 1996-98) 主要学术与社会兼职 中国化学会化学热力学与热分析专业委员会副主任 物理化学学报,编委会委员 Biomedical Spectroscopy and Imaging, Regional Editor for Asia.

研究领域

研究工作主要分为以下几个方面:(一)光谱方法学及其应用:致力于建立和完善分子间相互作用的研究方法,包括超额光谱法、二维相关光谱法、Benesi-Hildebrand法;研究内容包括氢键、卤键的性质,分子识别和分子间选择性相互作用;研究对象涉及生物大分子、离子液体等绿色溶剂和有机小分子。(二)生物物理化学:研究内容包括生物膜相变与稳定性、蛋白质变性、膜与磷脂相互作用、细胞及模型膜的显微方法;研究对象涉及磷脂、糖脂、固醇、蛋白质、核酸;在方法学方面提出了一种鉴别蛋白质变性二态性的“中止-恒温”法。(三)分子自组装:研究内容包括双亲分子自组装体和葫芦脲与小分子配体的组装,提出了双亲分子自组装体相变过程中头、尾部和界面区域可以不协同的思想,在LB膜研究中提出了超额面积的概念,近期关注同步辐射小角散射(SAXS)数据的深度解析。(四)溶液化学与热化学:研究内容包括溶液结构、超额焓、超额体积和分子的溶剂化作用等,对Flory理论进行改进,提出了双参数法。

近期论文

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Free-Standing Two-Dimensional Crystals Formed from Self-Assembled Ionic Liquids, J. Phys. Chem. Lett. 14: 2744?2749 (2023) (Dai D, Cao B, Hao XL, Li ZH, and Yu ZW*) Cholesterol Protects the Liquid-ordered Phase of Raft Model Membranes from the Destructive Effect of Ionic Liquids, J. Phys. Chem. Lett. 13: 7386?7391 (2022) (Hao XL, Cao B, Dai D, Wu FG, and Yu ZW*) Abnormalities of the Halogen Bonds in the Complexes between Y2CTe (Y = H, F, CH3) and XF (X = F, Cl, Br, I), Molecules 27(23): 8523 (2022) (Wang YQ, Wang RJ, Li QZ*, and Yu ZW*) Structural microheterogeneity and hydrogen bonding properties in the mixtures of two ionic liquids with a common imidazolium cation, J. Mol. Liquids, 368: 120594 (2022) (Zhao R, Xu XZ, Wang ZH, Zheng Y, Zhou Y*, Yu ZW*) Generalized excess spectroscopy, J. Phys. Chem. A 126: 1775? 1781 (2022) (Wang YQ and Yu ZW*) The distinct effects of two imidazolium-based ionic liquids, [C4mim][OAc] and [C6mim][OAc], on the phase behaviour of DPPC, Phys. Chem. Chem. Phys. 23(33):17888 – 17893 (2021) (Hao XL, Guo HY, Cao BB, Mo G, Li ZH, and Yu ZW*) Tracking the Micro-heterogeneity and Hydrogen-bonding Interactions in Hydroxyl-functionalized Ionic liquid solutions: A Combined Experimental and Computational Study, ChemPhysChem. 22(18): 1891-1899 (2021) (Zhang YQ Tan X, Ding WL, Wang YL, He HY*, and Yu ZW*) The structural properties of ZnCl2-ethylene glycol binary system and the peculiarities at the eutectic composition, Phys. Chem. Chem. Phys. 23(23):13136 – 13147 (2021) (Kalhor P, Ghandi K, Ashraf H, and Yu ZW*) Transition Mechanism from Nonlamellar to Well-Ordered Lamellar Phases: Is the Lamellar Liquid-Crystal Phase a Must? J. Phys. Chem. Lett. 12: 4484?4489 (2021) (Cao BB, Guo HY, Hao XL, Wu ZH, Wu FG, and Yu ZW*) The Structures of ZnCl2-Ethanol Mixtures, a Spectroscopic and Quantum Chemical Calculation Study, Molecules 26(9): 2498 (2021) (Kalhor P, Wang YQ, and Yu ZW*) Comparative Study of the Hydrogen Bonding Properties between Bis(fluorosulfonyl)imide/Bis(trifluoromethyl)sulfonylimide-based Ether-Functionalized Ionic Liquids and Methanol, J. Mol. Liquids, 322: 115333 (2021) (Chen H, Wang ZH, Xu XZ, Gong SD, Yu ZW, Zhou Y*). The Microscopic Structure of 1-Methoxyethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EOMIMTFSI) during Dilution with Polar Solvents, J. Mol. Liquids, 322: 114901. (2021) (Chen H, Wang ZH, Xu XZ, Gong SD, Yu ZW, Zhou Y*) Identification and Properties of Ion-Pairs in the Aqueous Solutions of LiI and NaI by FTIR and Quantum Chemical Calculations, J. Mol. Liquids, 322: 114891 (2021). (Ashraf H, Cao BB, Kalhor P, and Yu ZW*) Excess Spectroscopy and Its Applications in the Study of Solution Chemistry, Pure Appl. Chem. 92(10): 1611-1626 (2020) (Zhang YQ, Wu ZW, Wang YQ, He HY*, and Yu ZW*) Local Acid Strength of Solutions and Its Quantitative Evaluation Using Excess Infrared Nitrile Probes, J. Phys. Chem. Lett. 11: 1007?1012 (2020) (Xu J, Deng G, Wang YT, Guo HY, Kalhor P, and Yu ZW*) Fabrication of Asymmetric Phosphatidylserine-Containing Lipid Vesicles, A Study on the Effects of Size, Temperature, and Lipid Composition, Langmuir, 36(42): 12684-12691(2020). (Guo HY, Sun HY, Deng G, Xu J, Wu FG, and Yu ZW*) Enzyme-Mediated Tumor Starvation and Phototherapy Enhance Mild-Temperature Photothermal Therapy, Adv. Funct. Mater. 1909391 (2020) (Gao G, Jiang YW, Guo YX, Jia HR, Cheng XT, Deng Y, Yu XW, Zhu YX, Guo HY, Sun W, Liu XY, Zhao J, Yang SH, Yu ZW, Raya, FMS, Liang GL*, and Wu FG*) Is the FTIR Free-OH Band of t-Butanol only from Free OHs? Case Studies on the Binary Systems of the Alcohol with CCl4 and CHCl3, J. Phys. Chem. A 124(30): 6177? 6185 (2020) (Kalhor P, Li QZ, Zheng YZ, and Yu ZW*) Influence of Hydration on the Structure and Interactions of (Choline Chloride + Ethylene Glycol) Deep-Eutectic Solvent: A Spectroscopic and Computational study, ChemPhysChem. 21(10): 995-1005 (2020). (Kalhor P, Zheng YZ, Ashraf, H, Cao BB, and Yu ZW*) The Effect of Introducing an Ether Group into an Imidazolium-based Ionic Liquid in Binary Mixtures with DMSO, Phys. Chem. Chem. Phys. 22: 15734-15742 (2020). (Zhou Y, Xu XZ, Wang ZH, Gong SD, Chen H, Yu ZW, Kiefer, J*) Structural and Hydrogen-bonding Properties of Neat t-BuNH2 and Its Binary Mixtures with CCl4, CHCl3 and DMSO, J. Mol. Struct. 1215: 128257 (2020). (Kalhor P and Yu ZW*) Structural Properties and Hydrogen Bonding Interactions in Binary Mixtures Containing a Deep-Eutectic-Solvent and Acetonitrile, J. Phys. Chem. B 124: 1229?1239 (2020) (Kalhor P, Xu J, Ashraf H, Cao BB, and Yu ZW*) The Interactions between Polar Solvents (Methanol, Acetonitrile, Dimethylsulfoxide) and the Ionic Liquid 1-Ethyl-3-methylimidazolium Bis(fluorosulfonyl)Imide, J. Mol. Liquids. 299: 112159 (2020) (Zhou Y, Gong SD, Xu XZ, Yu ZW, Kiefer J*, and Wang ZH*) Effect of Imidazolium-Based Ionic Liquids on the Structure and Phase Behavior of Palmitoyloleoylphosphatidylethanolamine, J. Phys. Chem. B, 123(26): 5474-5482 (2019) (Guo HY, Cao BB, Deng G, Hao XL, Wu FG, and Yu ZW*) Insights into the Hydrogen Bond Interactions in Deep Eutectic Solvents Composed of Choline Chloride and Polyols, ACS Sustainable Chem. Eng. 7: 7760-7767 (2019) (Wang HY, Liu SY, Zhao YL, Wang JJ*, and Yu ZW*) The Velocity Dependence of Viscosity of Flowing Water, J. Mol. Liquids. 278: 234-238 (2019) (Ni K, Fang HW*, Yu ZW, and Fan ZS) Comparative Study of Hydrogen Bonding Interactions between N-methylacetamide and Methyl Acetate/Ethyl Formate, J. Mol. Struct. 1173: 321-327 (2018) (Zhou Y, Wang ZH*, Gong SD, Yu ZW, and Xu XZ) Hydroxyl Group as IR Probe to Detect the Structure of Ionic Liquid-Acetonitrile Mixtures, J. Mol. Struct. 1161: 424-432 (2018) (Xu J, Deng G, Zhou Y, Ashraf H, and Yu ZW*) Identifying Different Halogen/Hydrogen Bonding Interaction Modes in the Binary Systems Containing an Acetate Ionic Liquid and Various Halobenzenes, ChemPhysChem. 19(9): 1030-1040 (2018) (Xu J, Zhou Y, Deng G, Ashraf H, and Yu ZW*) Plasma Membrane Activatable Polymeric Nanotheranostics with Self-Enhanced Light-Triggered Photosensitizer Cellular Influx for Photodynamic Cancer Therapy, Journal of Controlled Release, 255(15): 231-241 (2017) (Jia, HR, Jiang YW, Zhu YX, Li YH, Wang HY, Han XF, Yu ZW, Gu N, Liu PD, Chen Z, and Wu FG)

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