王训 - 清华大学

个人简介

Education 1998 B. Sc. in Chemical Engineering, Northwest University, China 2001 M. Sc. in Chemical Engineering, Northwest University, China 2004 Ph. D. in Chemistry, Tsinghua University, China Career 2004.08-2005.11 Assistant Professor, Department of Chemistry, Tsinghua University 2005.12-2007.11 Associate Professor, Department of Chemistry, Tsinghua University 2007.12- Professor, Department of Chemistry, Tsinghua University 2011.07-2014.09 Vice-dean, Department of Chemistry, Tsinghua University 2014.10-2020.12 Dean, Department of Chemistry, Tsinghua University Awards 2019 第一届腾讯基金会科学探索奖 2018 International Solvothermal and Hydrothermal Association Conference 2018 Royi-Somiya Award 2016 第八届中国化学会-巴斯夫公司青年知识创新奖 2015 Fellow of the Royal Society of Chemistry 2014 ChangJiang Professor (Ministry of Education, China) 2014 IUMRS – MRS Singapore Young Researchers Award Nomination 2009 Science and Technology Award for Chinese Youth 2009 CCS-RSC Award for Young Chemists 2008 National Natural Science Award (2nd grade) 2007 National Science Foundation for Outstanding Young Scientists 2007 Fok Ying Tung Education Foundation 2006 Tsinghua University Young Scientist Award 2006 Program for New Century Excellent Talents of the Chinese Ministry of Education 2006 Chinese Chemical Society Prize for Young Scientists 2006 National Excellent Doctoral Dissertation of P. R. China 2005 CCS-Wiley Young Chemist Paper Award 2005 IUPAC Prize for Young Chemists

研究领域

Subnanometer As building materials, inorganic nanocrystals can be difficult to work with. Conventional nanoparticles and nanowires are often rigid and brittle, and require careful coaxing to assemble into complex structures. If only inorganic nanomaterials were more like flexible organic proteins and other macromolecules, researchers could create much more sophisticated shapes for novel devices.Now with a simple solution-based method, we have created a series of sub-nanometer materials, like GdOOH ultrathin nanowires, indium sulfide nanocoils, etc. They’re so thin and long that they bend like flexible proteins or polymers.We suggest that these ultrathin structures may help researchers to bridge the gap between organic and inorganic nanomaterials, providing insights into superstructure self-assembly and polymer crystallization.. Self-assembly Size may determine many properties in nanoscale. Here we are interested in building nanostructures from the self-assembly of ultrathin sub-units. There are many kinds of driving forces in the field of self-assembly, and each of them may take control under suitable situation. Recently we found that when the size of the inorganics decrease to the molecular scale, weak interactions would dominate the interplay between sub-units and environments. In light of this, “rigid” inorganic could achieve previously unnoticed flexibilities in proper condition, like organic molecules. Consequently, more complicated morphologies could be achieved and foreseen. Self-assembly hold great promise for constructing sophisticated nanostructures, and by utilizing the weak interactions between ultrathin sub-units, we may be able to construct nanostructures in the way like building molecules in organic chemistry..

近期论文

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Fenghua Zhang, Haoyang Li, Zhong Li*, Qingda Liu*, Xun Wang*, Nature Synthesis. 2024，s44160-024-00569-7 Phase engineering of polyoxometalate assembled superstructures hthttps://www.nature.com/articles/s44160-024-00569-7 Simin Zhang*, Jiangxiao Li, Wenxiong Shi, Jiatao Zhang, Xun Wang*, Advanced Functional Materials. 2024，202405243 Freestanding Scattering Polarizer Assembled with Subnanowires and Liquid Crystals https://doi.org/10.1002/adfm.202405243 Fengling Zhao, Qiang Yuan*, Siyang Nie*, Liang Wu, Xun Wang*, Journal of Energy Chemistr. 2024，92, 142-150 Modified electronic structure and enhanced hydroxyl adsorption make quaternary Pt-based nanosheets efficient anode electrocatalysts for formic acid-/alcohol-air fuel cells 10.1016/j.jechem.2023.12.042 Huaiyun Ge, Lirong Zheng, Guobao Yuan, Wenxiong Shi, Junli Liu*, Yu Zhang*, and Xun Wang, J. Am. Chem. Soc. 2024，146, 15, 10735–10744 Polyoxometallate Cluster Induced High-Entropy Oxide Sub-1 nm Nanosheets as Photoelectrocatalysts for Zn–Air Batteries 10.1021/jacs.4c00652 Qingda Liu, Zhou Sheng, Wenxiong Shi, Xijun Cheng, Xiangxing Xu, and Xun Wang*, J. Am. Chem. Soc. 2024, 146, 18, 12819–12827 Tuning the Chirality Evolution in Achiral Subnanometer Systems by Judicious Control of Molecule Interactions 10.1021/jacs.4c03378 Maria C. Dipalo, Biao Yu, Xijun Cheng, Siyang Nie, Junli Liu, Wenxiong Shi, Fenghua Zhang*, Qingda Liu* and Xun Wang*, Nanoscale 2024 Microwave-assisted synthesis of polyoxometalate-Dy2O3 monolayer nanosheets and nanotubes 10.1039/d4nr00323c Minzheng Yang, Haoyang Li, Jian Wang, Wenxiong Shi, Qinghua Zhang, Hanzheng Xing, Weibin Ren, Binzhou Sun, Mengfan Guo, Erxiang Xu, Nannan Sun, Le Zhou, Yao Xiao, Mufeng Zhang, Zhong Li, Jiayu Pan, Jianyong Jiang, Zhonghui Shen, Xiaoyan Li, Lin Gu, Ce-Wen Nan, Xun Wang* & Yang Shen*, Nature Energy 9, 143–153 (2024) Roll-to-roll fabricated polymer composites filled with subnanosheets exhibiting high energy density and cyclic stability at 200°C 10.1038/s41560-023-01416-3 Zhong Li, Yunwei Huang, Haoyang Li, Fenghua Zhang, Yazhou Ren, Wenxiong Shi*, Qingda Liu*, and Xun Wang* Journal of the American Chemical Society 2023 Single-Walled Cluster Nanotubes for Single-Atom Catalysts with Precise Structures https://doi.org/10.1021/jacs.3c09752 Tian Wang, Weichao Chen, Qingda Liu, Wei Wang, Yinming Wang, Biao Wu, Wenxiong Shi*, Yunqing Zhu*, Peilei He*, Xun Wang Angewandte Chemie 202362(51). Self-Assembly of Polyoxometalate-Based Sub-1 nm Polyhedral Building Blocks into Rhombic Dodecahedral Superstructures https://doi.org/10.1002/anie.202314045 Zhong Li, Qingda Liu*, Xun Wang* Matter 20236(11). Two-dimensional cluster-assembled materials with properties beyond their individualities and bulks https://doi.org/10.1016/j.matt.2023.09.004 Shujian Rong, Mengshi Wang & Xun Wang* Angewandte Chemie 2023202310018. Tunable Fluorescence from 2D Assemblies of LnW10 and P2W18 Polyoxometalates Clusters with Quaternary Ammonium-type AIEgens https://doi.org/10.1002/ange.202310018 Gaoyu Chen, Xiaoyu Liu, Jiakun An, Shibin Wang, Xiaokun Zhao, Zhongzheng Gu, Caojin Yuan, Xiangxing Xu*, Jianchun Bao*, Han-Shi Hu*, Jun Li* & Xun Wang*, Nature Chemistry 2023. Nucleation-mediated growth of chiral 3D organic–inorganic perovskite single crystals https://doi.org/10.1038/s41557-023-01290-2 Fengling Zhao, Siyang Nie*, Liang Wu*, Qiang Yuan*, Xun Wang*, Advanced Materials 20232303672· Porous, Ultrathin PtAgBiTe Nanosheets for Direct Hydrazine Hydrate Fuel Cell Devices https://doi.org/10.1002/adma.202303672 Zhong Li, Zihe Zhang, Hanshi Hu, Qingda Liu* & Xun Wang*, Nature Synthesis 2023. Synthesis of two-dimensional polyoxoniobate-based clusterphenes with in-plane electron delocalization https://www.nature.com/articles/s44160-023-00305-7 Yuang Shi, Wenxiong Shi, Simin Zhang and Xun Wang*, CCS Chemistry 2023,202302729. Revealing the Flexibility of Inorganic Sub-Nanowires by Single-Molecule Force Spectroscopy https://doi.org/10.31635/ccschem.023.202302729 Qingda Liu and Xun Wang*, Angew. Chem. Int. Ed. 2022,e202217764. Precise Assembly of Polyoxometalates at Single-cluster Levels https://doi.org/10.1002/anie.202217764 Qingda Liu and Xun Wang*, Angew. Chem. Int. Ed. 2022,e202217764.Precise Assembly of Polyoxometalates at Single-cluster Levels Simin Zhang and Xun Wang*, ACS Nano 2022,20–26.Inorganic Subnanometer Nanowire-Based Organogels: Trends, Challenges, and Opportunities Wanyue Ouyang, Simin Zhang and Xun Wang*, Small 2022,2206018.Freestanding Block Copolymer Membranes with Tunable Pore Sizes Promoted by Subnanometer Nanowires Junli Liu, Yuqi Li, Zhao Chen, Nan Liu, Lirong Zheng, Wenxiong Shi* and Xun Wang*, J. Am. Chem. Soc. 2022,23191–23197.Polyoxometalate Cluster-Incorporated High Entropy Oxide Sub-1 nm Nanowires Feng Yuan, Dr. Chen Ouyang, Minzheng Yang, Prof. Wenxiong Shi, Dr. Weibin Ren, Prof. Yang Shen, Prof. Yan Wei, Prof. Xuliang Deng and Xun Wang*, Angew. Chem. Int. Ed. 2022,e202214571.Regulating the Mechanical and Optical Properties of Polymer-based Nanocomposites by Sub-Nanowires Simin Zhang and Xun Wang*, Acc. Mater. Res. 2022,1285–1298.Sub-1 nm: A Critical Feature Size in Materials Science Qingda Liu and Xun Wang*, Chem. Sci. 2022,12280–12289.Fabricating sub-nanometer materials through cluster assembly Shujian Rong and Xun Wang*, Chem. Commun. 2022,11475-11487.Recent progress of sub-1 nm nanomaterials: synthesis, polymer-analogue properties and applications in redox catalysis Simin Zhang, Wenxiong Shi, Biao YuCheng, Wenxiong Shi and Xun Wang*, J. Am. Chem. Soc. 2022,16389–16394.Versatile Inorganic Subnanometer Nanowire Adhesive Qingda Liu, Shiqing He, Biao Yu, Xijun Cheng, Wenxiong Shi and Xun Wang*, Advanced Materials. 2022,2206178.Visible Light Induced Ag–Polyoxometalate Coassembly into Single-Cluster Nanowires Chen Ouyang, Lirong Zheng, Qinghua Zhang and Xun Wang*, Advanced Materials. 2022,2205372.A Simple Preheating-Pyrolysis Strategy Leading to Superior Oxygen Reduction Reaction Activity in Fe-N/Carbon Black Shujian Rong, Mengshi Wang & Xun Wang* Angewandte Chemie 2023202310018.Tunable Fluorescence from 2D Assemblies of LnW10 and P2W18 Polyoxometalates Clusters with Quaternary Ammonium-type AIEgens Gaoyu Chen, Xiaoyu Liu, Jiakun An, Shibin Wang, Xiaokun Zhao, Zhongzheng Gu, Caojin Yuan, Xiangxing Xu*, Jianchun Bao*, Han-Shi Hu*, Jun Li* & Xun Wang*, Nature Chemistry 2023.Nucleation-mediated growth of chiral 3D organic–inorganic perovskite single crystals Fengling Zhao, Siyang Nie*, Liang Wu*, Qiang Yuan*, Xun Wang*, Advanced Materials 20232303672·Porous, Ultrathin PtAgBiTe Nanosheets for Direct Hydrazine Hydrate Fuel Cell Devices Zhong Li, Zihe Zhang, Hanshi Hu, Qingda Liu* & Xun Wang*, Nature Synthesis 2023.Synthesis of two-dimensional polyoxoniobate-based clusterphenes with in-plane electron delocalization Yuang Shi, Wenxiong Shi, Simin Zhang and Xun Wang*, CCS Chemistry 2023,202302729.Revealing the Flexibility of Inorganic Sub-Nanowires by Single-Molecule Force Spectroscopy Zhang, Simin, Wenxiong Shi, and Xun Wang*, Science. 2022,7574. Locking volatile organic molecules by subnanometer inorganic nanowire-based organogels Liu, Junli, Wenxiong Shi*, Siyang Nie*, and Xun Wang*, Small Struct. 2022,2200039. Functionally Guided Precise Synthesis of Manganous Oxide-Polyoxometalate 2D Hybrid Sub-1 nm Nanosheet Superstructures Yang, Deren, and Xun Wang*, SmartMat 2022,54-67. 2D π-conjugated metal–organic frameworks for CO2 electroreduction Liu, Qingda, and Xun Wang*, Chem. Catal. 2022,03.008. Sub-nanometric materials: Electron transfer, delocalization, and beyond Qingda Liu, Qinghua Zhang, Wenxiong Shi, Hanshi Hu, Jing Zhuang and Xun Wang*, Nat. Chem. 2022,14, 433-440. Self-assembly of polyoxometalate clusters into two-dimensional clusterphene structures featuring hexagonal pores Rong, Shujian, Wenxiong Shi, Simin Zhang*, and Xun Wang*, Angew. Chem. Int. Ed.. 2022,202208349. Circularly and Linearly Polarized Luminescence from AIE Luminogens Induced by Super-Aligned Assemblies of Sub-1 nm Nanowires Simin Zhang, Qichen Lu, Biao Yu, Xijun Cheng, Jing Zhuang, Xun Wang*, Adv. Func. Mater. 2021,31, 2100703. Polyoxometalates facilitating synthesis of subnanometer nanowires Simin Zhang, Nan Liu, Hongwei Wang, Qichen Lu, Wenxiong Shi*, Xun Wang*, Adv.Mater. 2021,2100576. Subnanometer Nanobelts Based on Titanium dioxide/Zirconium dioxide-Polyoxometalate Heterostructures Yongkai Wang, Xiaoyu Liu, Qiqian He, Gaoyu Chen, Dongdong Xu, Xudong Chen, Wenbo Zhao, Jianchun Bao, Xiangxing Xu*, Junli Liu, Xun Wang*, Adv. Func. Mater. 2021,2011251. Yue Zhou, Lirong Zheng, Deren Yang, Haozhou Yang, Xun Wang*, Adv. Mater. 2021,33, 2101886. Boosting CO2 electroreduction via the synergistic effect of tuning cationic cluster and visible-light irradiation Qiqian He, Gaoyu Chen, Yongkai Wang, Xiaoyu Liu, Danting Xu, Xiangxing Xu*, Ying Liu*, Small. 2021,2101403. CsPbX3-ITO (X = Cl, Br, I) nano-heterojunctions: Voltage Tuned Positive to Negative Photoresponse Qingda Liu, Hongde Yu, Qinghua Zhang, Dong Wang,* Xun Wang*, Adv. Func. Mater. 2021,31, 2103561. Temperature-responsive self-assembly of single polyoxometalates clusters driven by Hydrogen bonds Biao Yu, Simin Zhang*, Xun Wang*, Angew. Chem. Int. Ed. 2021,60, 17404-17409. Helical Microporous Nanorods assembled by Polyoxometalate Clusters for the Photocatalytic Oxidation of Toluene Qingda Liu, Xun Wang*, InfoMat. 2021,3, 854-868. Cluster-assembled materials: Ordered structures with advanced properties Simin Zhang, Haodong Shi, Junwang Tang, Wenxiong Shi*, Zhong-Shuai Wu*, Xun Wang*, Sci. China. Mater. 2021,64, 2949-2957. Super-aligned films of sub-1 nm Bi2O3-polyoxometalate nanowires as interlayers in lithium-sulfur batteries Qichen Lu, Bolong Huang, Qinghua Zhang, Shuangming Chen, Lin Gu, Li Song, Yong Yang,* Xun Wang*, J. Am. Chem. Soc. 2021,143, 9858-9865. Single-Crystal Inorganic Helical Architectures Induced by Asymmetrical Defects in Sub-Nanometric Wires Fengling Zhao, Lirong Zheng, Qiang Yuana, Xiaotong Yang, Qinghua Zhang, Han Xu, Yuanlong Guo, Lin Gu, Song Yang*, Zhiyou Zhou*, Xun Wang*, Adv. Mater. 2021,202103383. Hassan Ali, Haifeng Lin*, Qichen Lu, Xun Wang*, J. Phys. Chem. C. 2021,125, 14646-14655. A General Strategy to Synthesize Ultrathin Palladium/Transition Metal Alloy Nanowires: Anti-Poisoned Electrocatalytic Performance for ORR in Acidic and Alkaline Media Junli Liu, Mingxin Wang, Maria C. Dipalo, Jing Zhuang, Wenxiong Shi,* Xun Wang*, Chem. Sci. 2021,12, 11490-11494. Ternary hybrid CuO-PMA-Ag sub-1 nm nanosheet heterostructures Junli Liu, Jing Zhuang, Wenxiong Shi*, Xun Wang*, Chem. Mater. 2021,33, 7100-7105. Ni(OH)2- Polyoxometalate Cluster Hybrid Superstructures