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研究领域

Inorganic/Bioinorganic Chemistry

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Sulfide Oxidation by O2: Synthesis, structure and reactivity of novel sulfide-incorporated Fe(II) bis(imino)pyridine complexes Widger, L. R.; Siegler, M. A.; Goldberg, D. P. Polyhedron, 2013, in press. Generation of a High-Valent Iron Imido Corrolazine Complex and NR Group Transfer Reactivity Leeladee, P.; Jameson, G. N. L.; Siegler, M. A.; Kumar, D.; de Visser, S. P.; Goldberg, D. P. Inorg. Chem., 2013, 52, 4668-4682. Mechanism of S-oxygenation by a Cysteine Dioxygenase Model Complex Kumar, D.; Sastry, G. N.; Goldberg, D. P.; de Visser, S. P. J. Phys. Chem. A, 2012, 116, 582-591. Axial and Equatorial Ligand Effects on Biomimetic Cysteine Dioxygenase Model Complexes Gonzalez-Ovalle, L. E.; Quesne M. G.; Kumar, D.; Goldberg, D. P.; de Visser, S. P. Org. Biomol. Chem. 2012, 10, 5401-5409. Sulfur Oxygenation in Biomimetic Non-heme Iron-thiolate Complexes McQuilken, A. C.; Goldberg, D. P. Dalton Transactions 2012, 41, 10883-10899.* Valence Tautomerization in a High-valent Manganese-Oxo Porphyrinoid Complex Induced by a Lewis Acid Leeladee, P.; Baglia, R. A.; Prokop, K. A.; Latifi, R.; de Visser, S. P.; Goldberg, D. P. J. Am. Chem. Soc. 2012, 134, 10397-10400. Addition of Dioxygen to an N4S(thiolate) Iron(II) Cysteine Dioxygenase Model Gives a Structurally Characterized Sulfinato-Iron(II) Complex McQuilken, A. C.; Jiang, Y.; Siegler, M. A.; Goldberg, D. P. J. Am. Chem. Soc. 2012, 134, 8758-8761. Generation of an Isolable, Monomeric Manganese(V)-Oxo Complex from O2 and Visible Light Prokop, K. A..; Goldberg, D. P. J. Am. Chem. Soc. 2012, 134, 8014-8017. A High-Valent Iron-Oxo Corrolazine Activates C-H Bonds via Hydrogen Atom Transfer Cho, K.; Leeladee, P.; McGown, A. J.; DeBeer, S.; Goldberg, D. P. J. Am. Chem. Soc 2012, 134, 7392-7399. Preparation of Aluminum(III) (bis(amido)pyridine)(thiolate) complexes: Unexpected Transmetalation Mediated by LiAlH4 Badiei, Y. M.; Jiang, Y.; Widger, L. R.; Siegler, M. A.; Goldberg, D. P. Inorg. Chim. Acta 2012, 382, 19-26. A Manganese(V)-Oxo π-Cation Radical Complex: Influence of One-Electron Oxidation on Oxygen-Atom Transfer Prokop, K. A.; Neu, H.; de Visser, S. P.; Goldberg, D. P. J. Am. Chem. Soc. 2011, 133, 15874-15877. Electron- and Hydride-Transfer Reactivity of an Isolable Manganese(V)-Oxo Complex Fukuzumi, S.; Kotani, H.; Prokop, K. A.; Goldberg, D. P. J. Am. Chem. Soc. 2011, 133, 1859-1869. O2 Activation by Bis(imino)pyridine Iron(II)-Thiolate Complexes Badiei, Y. M.; Siegler, M. A.; Goldberg, D. P. J. Am. Chem. Soc. 2011, 133, 1274-1277. Iron(II)-Thiolate S-Oxygenation by O2: Synthetic Models of Cysteine Dioxygenase Jiang, Y.; Widger, R. L.; Kasper, G. D.; Siegler, M. A.; Goldberg, D. P. J. Am. Chem. Soc. 2010, 132, 12214-12215. Unprecedented Rate Enhancements of Hydrogen-Atom-Transfer to a Manganese(V)-Oxo Corrolazine Complex Prokop, K. A.; de Visser, S. P.; Goldberg, D. P. Angew. Chem., Int. Ed. 2010, 49, 5091-5095. Preparation, Size Control, Surface Deposition, and Catalytic Reactivity of Hydrophobic Corrolazine Nanoparticles in an Aqueous Environment Cho, K.; Kerber, W. D.; Lee, S. R.; Wan, A.; Batteas, J. D.; Goldberg, D. P. Inorg. Chem. 2010, 49, 8465-8473. Epoxidation Catalyzed by Manganese(V) Oxo and Imido Complexes: Role of the Oxidant-Mn-Oxo (Imido) Intermediate Leeladee, P.; Goldberg, D. P. Inorg. Chem. 2010, 49, 3083-3085. Influence of Nitrogen Donors on Nonheme Iron Models of Superoxide Reductase: High-Spin FeIII-OOR Complexes Namuswe, F.; Hayashi, T.; Jiang, Y.; Kasper, G. D.; Sarjeant, A. A.; Moenne-Loccoz, P.; Goldberg, D. P. J. Am. Chem. Soc. 2010, 132, 157-167. X-ray Absorption Spectroscopy and Reactivity of Thiolate Ligated FeIII-OOR Complexes Stasser, J.; Namuswe, F.; Kasper, G. D.; Jiang, Y.; Krest, C. M.; Green, M. T.; Penner-Hahn, J.; Goldberg, D. P. Inorg. Chem. 2010, 49, 9178-9190. Catalytic Reactivity of a Meso-N-Substituted Corrole and Evidence for a High-Valent Iron-Oxo Species McGown, A. J.; Kerber, W. D.; Fujii, H..; Goldberg, D. P. J. Am. Chem. Soc, 2009, 131, 8040-8048.

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