个人简介
Education
1989-1994 Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, China. Received Ph.D. degree in June, 1994 (with Prof. Zheng-Ming Li).
2005-2009 Department of Chemistry, Central China Normal University, Wuhan, China. Received B. Sc. Degree in June, 1989.
Academic Career
2004- Professor, Department of Chemistry, Nankai University, Tianjin, CHINA.
2003-2004 Postdoctoral associate, Department of Industrial and Physical Pharmacy, Pharmacy School, Purdue University, USA (with Prof. Shuang Liu).
1999-2003 Postdoctoral associate, Department of Chemistry, Marquette University, USA (with Prof. William A. Donaldson and Prof. Chae S. Yi).
1998-1999 Postdoctoral associate, Department of Chemistry, University of Pretoria, South Africa (with Prof. Tomasz A. Modro).
1994-1998 Lecturer (1994-1996) and Associate Professor (1996-1998), Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, China.
研究领域
(1) Organic synthetic chemistry mainly focused on phosphorus reagents-mediated new reactions and synthetic methods.
(2) Asymmetric catalysis.
(3) Processing chemistry focused on fine chemicals used in the UV curing and electronic materials such as photoresists.
近期论文
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Shixuan Cao, Jiatian Li, Taishan Yan, Jie Han*, Zhengjie He*, UV Light-driven Asymmetric Vinylogous Aldol Reaction of Isatins with 2-Alkylbenzophenones and Enantioselective Synthesis of 3-Hydroxyoxindoles, Org. Chem. Front. 2022, 9, 643–648.
Jiayong Zhang, Yuhe Qiu, Biao Zhang, Zhiqiang Huang, Zhengjie He*, P(NMe2)3-Mediated Reductive Intramolecular Annulation of Benzoylformates Tethered with a Trisubstituted Alkene Unit and Synthesis of 2,2-Disubstituted 2H-Chromenes, Org. Lett. 2021, 23, 1880-1885.
Jiayong Zhang, Jiahang Hao, Zhiqiang Huang, Jie Han, Zhengjie He*, PIII-Mediated Intramolecular Cyclopropanation and Metal-free Synthesis of Cyclopropane-fused Heterocycles, Chem. Commun. 2020, 56, 10251-10254.
Hanyuan Li, Bojuan Li, Jianwei Zeng, Changzun Jiang, Zhengjie He*, Enantiopure Chiral Phosphines Bearing a Sulfinyl Group and their Application in Catalytic Enantiodivergent Synthesis of Polysubstituted Pyrrolines, Adv. Synth. Catal. 2020, 362, 2760-2766.
Rongfang Liu, Zifeng Qin, Binbin Fan, Ruifeng Li, Rong Zhou*, Zhengjie He*, Phosphine-Catalyzed Chemo- and Diastereoselective [2 + 2 + 2] and [3 + 2] Annulations of γ-Methyl Allenoates with Doubly Activated Olefins: Syntheses of Highly Substituted Cyclohexanes and Cyclopentenes, J. Org. Chem. 2019, 84, 12490-12498.
Jinghua Luo, Rongshun Chen, Xia Fan, Junyu Gong, Jie Han*, Zhengjie He*, Catalytic Asymmetric (4 + 1) Annulation of Nitroalkenes with Allylic Acetates: Stereoselective Synthesis of Isoxazoline N-oxides, Org. Biomol. Chem. 2019, 17, 6989-6993.
Yiyi Liu, Hengyu Li, Xun Zhou, Zhengjie He*, P(NMe2)3-Mediated Reductive (1 + 4) Annulation Reaction of Isatins with Nitroalkenes: An Access to Spirooxindolyl Isoxazoline N-Oxides and Their Corresponding Isoxazolines, J. Org. Chem. 2017, 82, 10997–11007.
Hanyuan Li, Jiesi Luo, Bojuan Li, Xizhen Yi, Zhengjie He*, Enantioselective [4 + 1]-Annulation of α,β-Unsaturated Imines with Allylic Carbonates Catalyzed by a Hybrid P-Chiral Phosphine Oxide–Phosphine, Org. Lett. 2017, 19, 5637-5640.
Changjiang Yang, Wei Liu, Zijian He, Zhengjie He*, Divergent Reactivity of Nitrocyclopropanes with Huisgen Zwitterions and Facile Syntheses of 3-Alkoxy Pyrazolines and Pyrazoles, Org. Lett. 2016, 18, 4936-4939.
Zifeng Qin, Wei Liu, Danyang Wang, and Zhengjie He*, Phosphine-Catalyzed (4 + 1) Annulation of o‑Hydroxyphenyl and o‑Aminophenyl Ketones with Allylic Carbonates: Syntheses and Transformations of 3‑Hydroxy-2,3-Disubstituted Dihydrobenzofurans and Indolines, J. Org. Chem. 2016, 81, 4690-4700.
Changjiang Yang, Wei Liu, Zijian He, Zhengjie He*, Divergent reactivity of nitrocyclopropanes with Huisgen zwitterions and facile syntheses of 3-alkoxy pyrazolines and pyrazoles, Org. Lett. 2016, 18, 4936-4939.
Changjiang Yang, Xiangyu Chen, Tong Tang, Zhengjie He*, Annulation reaction of 3-acylmethylidene oxindoles with Huisgen zwitterions and its applications in the syntheses of pyrrolo[4,3,2-de]quinolinones and marine alkaloids Ammosamides, Org. Lett. 2016, 18, 1486-1489.
Rong Zhou*, Kai Zhang, Yusong Chen, QiangMeng, Yiyi Liu, Ruifeng Li, Zhengjie He*, P(NMe2)3-mediated reductive [1+4] annulation of isatins with enones: facile synthesis of spirooxindole-dihydrofurans, Chem. Commun. 2015, 51, 14663-14666.
Mei Yang, Tianyi Wang, Shixuan Cao, Zhengjie He*, Phosphine-catalyzed [4+1] annulation of 1,3-(aza)dienes with maleimides: highly efficient construction of azaspiro[4.4]nonenes, Chem. Commun. 2014, 50, 13506-13509.
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