个人简介
Professional
Full Professor, Nanjing University, ChinaMar 1998 – present
Deputy Vice-Chancellor, Nanjing University, ChinaJan 2006 – Jun 2017
Dean, School of Chemistry&Chemical Engineering,
Nanjing University, ChinaJan 2001 – Jan 2006
Associate Professor, Nanjing University, ChinaSep 1992 – Mar 1998
Research Fellow, Imperial College London, UKAug 1989 – Jul 1992
Education
PhD in Organic Chemistry, Nanjing University, ChinaSep 1985 – May 1988
Research Supervisor: Prof Hongwen Hu
MSc in Chemistry, Nanjing University, ChinaSep 1982 – Jun 1985
BSc in Chemistry, Nanjing University, ChinaFeb 1978 – Jun 1982
研究领域
OLED
Organic light emitting diodes (OLEDs) are becoming the major solution of next generation lighting technologydue to their successful applications in solid-state lighting and full-color flat-panel displays. To the present, cyclometalated iridium (III) complexes are the most promising phosphorescent guest materials for highly efficient OLEDs because of their short excited lifetime (microsecond time-scale), color tuning flexibility, high quantum yields and thermal stability.The research is mainly aimed at the synthesis of phosphorescent moleculesand the understanding ofthe light-emitting mechanisms. The projects include:
1. Phosphorescent metal complexes: Ir, Pt, Re, Ru, Os, Au phosphorescent complexes with excellent photoluminescence and charge transporting properties
2. Thermally-activated delayed fluorescent materials: to design new TADF structureto improve triplet electron to singlet effective back-propagation for higher device efficiency;
3. Chiral materials: designed and synthesized chiral fluorescent, phosphorescent and thermally-activated delayed fluorescent materials with high asymmetric factor (g factor), for circularly polarized (CPL) emissionto manufacture3D display devices;
4. Supporting materials for OLEDs devices: the design and synthesis of electron transport materials, hole transport materials and host materials.
Fluorine
Fluorine is the most electron-negative element. Fluorinated organic compounds are of high significance inareas such as materials science, catalysis, medicine, andbiochemistry.This is because the reactivity and properties ofmolecules and ions can change dramatically in the presence offluorinated moieties. There is a growing demandfor the development of unprecedented routes to accessfluorinated molecules and building blocks, and even to designnew scaffolds.Our research mainly focused on the synthesisof novel fluorinating reagents for asymmetric catalysis and radical processes.
近期论文
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Photoexcited Direct Amination/Amidation of Inert Csp3–H Bonds via Tungsten–Nickel Catalytic Relay. Qing Wang, Shengyang Ni, Lei Yu, Yi Pan, and Yi Wang*. DOI:10.1021/acscatal.2c03456.
A practical fluorosulfonylating platform via photocatalytic imidazolium-based SO2F radical reagent. Weigang Zhang, Heyin Li, Xiaojuan Li, Zhenlei Zou, Mengjun Huang, Jiyang Liu, Xiaochen Wang, Shengyang Ni, Yi Pan & Yi Wang*, Nature Communications, 13, 3515 (2022).
Electrochemical-Promoted Nickel-Catalyzed Reductive Allylation of Aryl Halides. Wangzhe Chen , Shengyang Ni*, Yi Wang*, and Yi Pan. Org. Lett. 2022, 24, 20, 3647–3651.
Radical boron migration of allylboronic esters. Xiangzhang Tao, Shengyang Ni, Lingyu Kong, Yi Wang* and Yi Pan. Chem. Sci., 2022,13, 1946-1950.
Visible-light-mediated tungsten catalyzed C−H amination of unactivated alkanes with nitroarenes. Qing Wang , Shengyang Ni , Xiaochen Wang , Yi Wang* and Yi Pan. Science China Chemistry, 65, 678-685 (2022).
Uranyl-catalysed C–H alkynylation and olefination. Yu Mao, Yeqing Liu, Lei Yu, Shengyang Ni, Yi Wang* and Yi Pan. Org. Chem. Front., 2021, 8, 5968-5974.
Electrochemical C–N bond activation for deaminative reductive coupling of Katritzky salts. Yeqing Liu, Xiangzhang Tao, Yu Mao, Xin Yuan, Jiangkai Qiu, Linyu Kong, Shengyang Ni*, Kai Guo*, Yi Wang* & Yi Pan. DOI: 10.1038/s41467-021-27060-7.
Electrochemical-Promoted Nickel-Catalyzed Oxidative Fluoroalkylation of Aryl Iodides. Zhenlei Zou , Heyin Li, Mengjun Huang, Weigang Zhang*, Sanjun Zhi, Yi Wang*, and Yi Pan. Org. Lett. 2021, 23, 21, 8252–8256
Feng Zhang, Yang Wang,* Yi Wang,* and Yi Pan. Electrochemical Deoxygenative Thiolation of Preactivated Alcohols and Ketones. Org. Lett. 2021, 23, 19, 7524–7528
Qiang Zhang , Xiaojuan Li, Weigang Zhang*, Yi Wang*, and Yi Pan. Photocatalyzed Radical Relayed Regio and Stereoselective Trifluoromethylthiolation–Boration. Org. Lett. 2021, 23, 14, 5410–5414.
Zhenlei Zou, Weigang Zhang, Yi Wang* and Yi Pan. Recent advances in radical fluorination under electrochemical conditions. Org. Chem. Front., 2021,8, 2786-2798. (Invited Review)
Yi Zhu, Yifan Ni, Chenxi Lu, Xiaochen Wang, Yi Wang*, Xiao-Song Xue*, and Yi Pan. Ligand-Dependent Regiodivergent Enantioselective Allylic Alkylations of α‑Trifluoromethylated Ketones. Org. Lett. 2021, 23, 7, 2443–2448.
Xiaojuan Li, Qiang Zhang, Weigang Zhang,* JinZhu Ma,* Yi Wang* and Yi Pan. Metal-free visible-light-enabled vicinal trifluoromethyl dithiolation of unactivated alkenes. Beilstein J. Org. Chem. 2021, 17, 551–557. (Invited Article)
Weigang Zhang, Mengjun Huang, Zhenlei Zou, Zhengguang Wu, Shengyang Ni, Lingyu Kong, Youxuan Zheng, Yi Wang,* and Yi Pan. Redox-active benzimidazolium sulfonamides as cationic thiolating reagents for reductive cross-coupling of organic halides. Chem. Sci., 2021,12, 2509-2514.
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