郑丽敏 - 南京大学 - 配位化学国家重点实验室

研究领域

金属有机膦酸化学层状化合物是一类应用前景广阔的功能材料，在光、电、磁、催化、离子交换和传输及传感等方面都表现出优异的性能。石墨烯的发现更使传统层状化合物的研究得到了不可思议的复兴，相关研究已经拓展到其它许多无机层状化合物体系。由金属离子和有机配体构成的无机-有机杂化材料具有结构可以设计、功能易于调控等特点，探索新的无机-有机杂化低维材料并开发其功能性质及应用是目前该领域存在的关键科学问题之一。作为一类重要的无机-有机杂化材料，金属有机膦酸化合物在过去二十多年中一直受到人们广泛的关注，已报道的这类化合物大都具有层状结构，热稳定性和水相稳定性较高，因而在探索无机-有机杂化低维材料方面很有潜力。我们的研究目标是组装结构新颖的金属有机膦酸化合物晶态材料和低维材料，深入研究其光、电、磁功能性质及其构效关系，为开发基于金属有机膦酸化合物并具有实际用途的功能材料提供基础。研究兴趣: (1) 晶态和低维金属有机膦酸材料的组装; (2) 光磁双功能金属有机膦酸材料; (3) 清洁能源相关的金属有机膦酸质子导电材料; (4) 手性金属有机膦酸化合物及宏观螺旋材料; (5) 基于金属有机膦酸化合物的电催化材料。

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Zou, Q.; Wang, G.-L.; Chen, Y.-Q.; Huang, X.-D.; Wen, G. H.; Qin, M.-F.; Bao, S.-S.; Zhang, Y.-Q.; Zheng, L.-M. X-Ray Triggered Coordination-Bond Breakage in Dysprosium-Organic Framework and Its Impact on Magnetic Properties. Chemistry – A European Journal. 2023, 29 (12), e202203454. https://doi.org/10.1002/chem.202203454 Qin, M.-F.; Zheng, L.-F.; Bao, S.-S.; Xue, F.-H.; Su, J.; Ma, J.; Zheng, L.-M. Metalloporphyrinyl-Phosphonates with Serrated Chain Structures: Exfoliation and NIR Photothermal Effect. ACS Appl. Electron. Mater. 2023, 5 (2), 887–895. https://doi.org/10.1021/acsaelm.2c01438 Xu, K.; Lin, C.; Qin, M.-F.; Yuan, Z.; Tao, Y.; Bao, S.-S.; Chen, R.; Xie, X.; Zheng, L.-M. Amplifying Photoluminescence of Lanthanide-Doped Nanoparticles by Iridium Phosphonate Complex. ACS Materials Lett. 2023, 5 (3), 854–861. https://doi.org/10.1021/acsmaterialslett.2c01125 Huang, X.-D.; Ma, X.-F.; Shang, T.; Zhang, Y.-Q.; Zheng, L.-M. Photocontrollable Magnetism and Photoluminescence in a Binuclear Dysprosium Anthracene Complex. Inorg. Chem. 2023, 62 (5), 1864–1874. https://doi.org/10.1021/acs.inorgchem.2c01210 Hou, T.; Wu, L.-Q.; Xu, Y.; Bao, S.-S.; Zheng, L.-M. PH and Salt-Assisted Macroscopic Chirality Inversion of Gadolinium Coordination Polymer. Molecules. 2023, 28 (1). https://doi.org/10.3390/molecules28010163 Ma, X.-F.; Huang, X.-D.; Zheng, L.-M. Tuning the Single-Molecule Magnet and Photoluminescence Properties of Binuclear Dysprosium Complexes by Light. Crystal Growth & Design. 2023, 23 (2), 1095–1103. https://doi.org/10.1021/acs.cgd.2c01249 Huang, X.-D.; Hong, B.-K.; Wen, G.-H.; Li, S.-H.; Zheng, L.-M. Photo-Controllable Heterostructured Crystals of Metal–Organic Frameworks via Reversible Photocycloaddition. Chem. Sci. 2023, 14 (7), 1852–1860. https://doi.org/10.1039/D2SC06732C Liu, Y.; Wen, G.-H.; Liang, J.; Bao, S.-S.; Wei, J.; Wang, H.; Zhang, P.; Zhu, M.; Jia, Q.; Ma, J.; Zheng, L.-M.; Jin, Z. Aqueous Colloid Flow Batteries Based on Redox-Reversible Polyoxometalate Clusters and Size-Exclusive Membranes. ACS Energy Lett. 2023, 8 (1), 387–397. https://doi.org/10.1021/acsenergylett.2c02121 Qin, M.-F.; Wang, C.-Y.; Bao, S.-S.; Zheng, L.-M. Photoresponsive Proton Conduction in Zr-Based Metal–Organic Frameworks Using the Photothermal Effect. Chem. Commun. 2022, 58 (60), 8372–8375. https://doi.org/10.1039/D2CC02470E Wen, G.-H.; Zou, Q.; Xu, K.; Huang, X.-D.; Bao, S.-S.; Chen, X.-T.; Ouyang, Z.; Wang, Z.; Zheng, L.-M. Layered Uranyl Phosphonates Encapsulating Co(II)/Mn(II)/Zn(II) Ions: Exfoliation into Nanosheets and Its Impact on Magnetic and Luminescent Properties. Chemistry – A European Journal. 2022, 28 (42), e202200721. https://doi.org/10.1002/chem.202200721 Guo, Q.; Li, N.; Zou, Q.; Jia, J.; Wei, Y.; Bao, S.; Zheng, L. In Situ Thermal-Induced Generation of {Ag0AgI} Dimer within Co-Ag Phosphonates. Chinese Chemical Letters. 2022, 33 (6), 3259–3262. https://doi.org/10.1016/j.cclet.2021.10.091 Fan, K.; Bao, S.-S.; Yu, Z.-W.; Huang, X.-D.; Liu, Y.-J.; Kurmoo, M.; Zheng, L.-M. Engineering Heteronuclear Arrays from IrIII-Metalloligand and CoII Showing Coexistence of Slow Magnetization Relaxation and Photoluminescence. Chinese Journal of Chemistry. 2022, 40 (8), 931–938. https://doi.org/10.1002/cjoc.202100783 Ma, Z.; Fan, K.; Li, Q.; Xu, F.; Zou, L.; Wang, N.; Zheng, L.-M.; Xue, F. Dynamic Cantilever Magnetometry of Paramagnetism with Slow Relaxation. Chinese Physics Letters. 2022, 39 (3), 037501. https://doi.org/10.1088/0256-307X/39/3/037501 Huang, X.-L.; Chen, Y.-Q.; Wen, G.-H.; Bao, S.-S.; Zheng, L.-M. Hydrated Metal Ions as Weak Brønsted Acids Show Promoting Effects on Proton Conduction. CrystEngComm. 2022, 24 (21), 3886–3893. https://doi.org/10.1039/D2CE00430E Ma, X.-F.; Guo, Y.; Huang, X.-D.; Wen, G.-H.; Bao, S.-S.; Zhang, Y.-Q.; Zheng, L.-M. Polymorphism Modulates Photoluminescence and Magnetic Dynamics of Mononuclear Dysprosium–Anthracene Complexes. Dalton Trans. 2022, 51 (32), 12026–12030. https://doi.org/10.1039/D2DT01710E Wei, Y.-F.; Ma, X.-F.; Huang, X.-D.; Wen, G.-H.; Jia, J.-G.; Zheng, L.-M. Mixed-Ligated Cobalt Phosphonates Showing Slow Magnetic Relaxation and Spin-Flop Behavior. Journal of Solid State Chemistry. 2022, 312, 123227. https://doi.org/10.1016/j.jssc.2022.123227 Jia-Ge Jia,† Chen-Chen Zhao,† Song-Song Bao, Lan-Qing Wu, Ge-Hua Wen, Allan J. Jacobson, Jing Ma,* and Li-Min Zheng,* Layer or Tube? Uncovering Key Factors Determining the Rolling-up of Layered Coordination Polymers, J. Am. Chem. Soc. 2021, 143, 17587-17598. https://doi.org/10.1021/jacs.1c07517 Xin-Da Huang, Ge-Hua Wen, Song-Song Bao, Jia-Ge Jia and Li-Min Zheng,* Thermo- and light-triggered reversible interconversion of dysprosium-anthracene complexes and their responsive optical, magnetic and dielectric properties, Chem. Sci. 2021, 12, 929-937. https://doi.org/10.1039/d0sc04851h Guo-Guo Weng, Ben-Kun Hong, Song-Song Bao, Yujie Wen, Lan-Qing Wu, Xin-Da Huang, Jia-Ge Jia, Ge-Hua Wen, Shu-Hua Li, Luming Peng and Li-Min Zheng,* From helices to superhelices: hierarchical assembly of homochiral van der Waals 1D coordination polymers, Chem. Sci. 2021, 12, 12619-12630. https://doi.org/10.1039/d1sc01913a Kun Zhang, Ge-Hua Wen, Xiao-Jing Yang, Dae-Woon Lim, Song-Song Bao, Masaki Donoshita, Lan-Qing Wu, Hiroshi Kitagawa,* and Li-Min Zheng,* Anhydrous Superprotonic Conductivity of a Uranyl-Based MOF from Ambient Temperature to 110 °C, ACS Mater. Lett. 2021, 3, 744-751. https://doi.org/10.1021/acsmaterialslett.1c00176 Qian Zou, Tao Shang, Xin-Da Huang, Qing-Qing Guo, Jia-Ge Jia, Song-Song Bao,* Yi-Quan Zhang* and Li-Min Zheng,* Dysprosium-dianthracene framework showing thermo-responsive magnetic and luminescence properties, J. Mater. Chem. 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J. 2021, 27, 16722-16734. https://doi.org/10.1002/chem.202102954 Guo-Guo Weng,† Xin-Da Huang,† Rui Hu, Song-Song Bao, Qian Zou, Ge-Hua Wen, Yi-Quan Zhang,* and Li-Min Zheng,* Homochiral Dysprosium Phosphonate Nanowires: Morphology Control and Magnetic Dynamics, Chem. Asian J. 2021, 16, 2648-2658. https://doi.org/10.1002/asia.202100670 Qian Zou, Song-Song Bao, Xin-Da Huang, Ge-Hua Wen, Jia-Ge Jia, Lan-Qing Wu, and Li-Min Zheng,* Cobalt(II)-dianthracene Frameworks: Assembly, Exfoliation and Properties, Chem. Asian J. 2021, 16, 1456-1465. https://doi.org/10.1002/asia.202100283 Ge-Hua Wen, Xiu-Mei Chen, Kui Xu, Xiaoji Xie, Song-Song Bao* and Li-Min Zheng,* Uranyl phosphonates: crystalline materials and nanosheets for temperature sensing, Dalton Trans. 2021, 50, 17129-17139. https://doi.org/10.1039/d1dt02977k Ge-Hua Wen, Qian Zou, Xin-Da Huang, Kun Zhang, Song-Song Bao, Li-Min Zheng,* Heterometallic uranyl-organic frameworks incorporating manganese and copper: Structures, ammonia sorption and magnetic properties, Polyhedron 2021, 205, 115327. https://doi.org/10.1016/j.poly.2021.115327 Jing-Cui Liu, Qian Zou, Xin-Da Huang, Song-Song Bao, and Li-Min Zheng,* Dysprosium Coordination Polymer Incorporating Dianthracene: Thermo-induced Phase Transition Accompanied with Magnetic and Optical Changes, Eur. J. Inorg. Chem. 2021, 2021, 1565-1570. https://doi.org/10.1002/ejic.202100138 Guo-Bin Sun, Xin-Da Huang, Tao Shang, Shuo Yan, Song-Song Bao, Xiao-Mei Lu, Yi-Quan Zhang,* and Li-Min Zheng,* Polar Lanthanide Anthracene Complexes Exhibiting Magnetic, Luminescent and Dielectric Properties, Eur. J. Inorg. Chem. 2021, 2021, 4207-4215. https://doi.org/10.1002/ejic.202100538 Wen Yan, Kun Fan, Li-Min Zheng,* and Zhong Jin,* Cluster-Bridging-Coordinated Bimetallic Metal-Organic Framework as High-Performance Anode Material for Lithium-Ion Storage, Small Struct. 2021, 2100122. https://doi.org/10.1002/sstr.202100122