王新益 - 南京大学 - 配位化学国家重点实验室

个人简介

2015年全国优青，江苏省杰青；化学化工学院院长助理，配位化学国家重点实验室副主任经历（英） 2016-present Professor, Nanjing University 2010-2016 Associate Professor, Nanjing University 2008-2010Postdoctoral Associate in Texas A&M University 2006-2007Postdoctoral Associate in University of Notre Dame 2001-2006PhD in Inorganic Chemistry, Peking University 1997-2001B. Sc. In Material Chemistry, Peking University 1979 年出生，南京大学化学化工学院教授，博士生导师。2001年和2006年分获北京大学化学与分子工程学院学士、博士学位（高松院士），博士研究课题为三原子桥连分子磁性材料的研究。2006年至2007年，美国圣母大学化学系从事博士后研究（Slavi C Sevov教授课题组），进行多功能金属有机骨架及由静电辅助的氢键构筑的柔性分子网络的研究。2008年至2010年，美国德州农工大学化学系从事博士后研究工作（Kim R Dunbar教授课题组），主要进行基于4d、5d金属的分子磁性材料的研究，主要研究内容为基于Mo(III)的分子磁体研究。2010年9月，南京大学化学化工学院副教授，主要研究方向为光电功能配位聚合物及分子磁性材料的研究。2011年入选南京大学青年骨干教师培养计划，2014年入选南京大学登峰人才支持计划（B层次），2015年获得自然科学基金“优秀青年基金”及江苏省“杰出青年基金”。2016年晋升为教授。

研究领域

Single Molecule Magnets (SMMs) SMMs are paramagnetic molecules that possess easy-axis anisotropy and a barrier to their magnetization reversal. Their quantum nature, manifested by quantum tunneling of the magnetization and quantum phase interference, has led to much excitement regarding their applications in future generations of information storage and quantum computing. To obtain SMMs with high energy barrier and blocking temperature, lanthanide centers with large magnetic anisotropy and the 4d/5d metal ions with strong anisotropic magnetic exchange coupling were used in our group. For the SMMs constructed from lanthanide centers, we used the 3d-4f compartmental compounds as the starting materials and employed the azide ligand to bridge the lanthanide centers. In this way, we were able to obtain a whole series of end-on azide bridged 3d-4f compounds. Most of these compounds containing the Tb3+ and Dy3+ centers were indeed SMMs. Detailed magnetic measurements on one single crystal of some of these systems revealed the Ising anisotropy of the system and the magneto-structural relationship of the magnetic anisotropy. Using the [MoIII(CN)7]4- building blocks, we intended to use the anisotropic magnetic coupling to construct better SMMs. We obtained the first molecule cluster made of [MoIII(CN)7]4- (Angew. Chem. Int. Ed.2010, 49, 5081-5084. cover). This compound has the most paramagnetic metal centers and the highest ground spin state (S = 31) for the cyano-bridged compounds. Furthermore, we obtained a series of trinuclear Mn2Mo compounds, one of which is really the first SMM based on the[MoIII(CN)7]4- unit. It has the highest energy barrier for all the cyano-bridged SMMs (J.Am. Chem. Soc.2013, 135, 13302). Bistable Materials Molecular bistability has invoked intense interest in themolecular materials community because of its great potential for application in sensors, displays, and switching devices. We are interested in two main systems of magnetic bistability. The first one is the well-known spin-crossover compounds. We hope to develop anionic spin-crossover compounds and multifunctional spin crossover compounds, such as the cation dependent and porous spin crossover compounds. The other system is the phase transition induced magnetic bistability.In this area, we were able to prepare a whole series of azido-bridged perovskite-type compounds where the magnetic bistability can be obtained near room temperatures and the critical temperatures can be tuned using different cations(J. Am. Chem. Soc.2013,135, 16006). Sequential phase transitions were observed in these metal-organic framework perovskite structures, just as observed in the pure inorganic ABO3 perovskite compounds. These systems might be of great importance for the further development of functional materials.

近期论文

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1. Reversible On-Off Switching of a Single-Molecule Magnet via a Crystal-to-Crystal Chemical Transformation，Dong-Qing Wu, Dong Shao, Xiao-Qin Wei, Fu-Xing Shen, Le Shi, David Kempe, Yuan-Zhu Zhang,* Kim R Dunbar,* Xin-Yi Wang*, J. Am. Chem. Soc.,2017, 139, 11714. 2. Cation-dependent magnetic ordering and room temperature bistability in azido-bridged perovskite-type compounds, Xin-Hua Zhao, Xing-Cai Huang, Shao-Liang Zhang, Dong Shao, Hai-Yan Wei,* and Xin-Yi Wang*, J. Am. Chem. Soc.2013,135, 16006. 3. A single-molecule magnet based on heptacyanomolybdate with the highest energy barrier for a cyanide compound, Kun Qian, Xing-Cai Huang, Chun Zhou, Xiao-Zeng You, Xin-Yi Wang,* and Kim R. Dunbar*, J. Am. Chem. Soc.2013, 135, 13302. 4. Syntheses and magnetic properties of a pyrimidylsubstituted nitronyl nitroxide radical and its cobalt(II) complexes”, Jian Wang, Jia-Nan Li, Shao-Liang Zhang, Xin-Hua Zhao, Dong Shao, Xin-Yi Wang*,Chemical Communications, 2016, 52, 5033. 5. End-on azido-bridged 3d−4f complexes showing single-molecule-magnet property, Xing-Cai Huang, Chun Zhou, Hai-Yan Wei,* Xin-Yi Wang,* Inorg. Chem.2013, 52, 7414. 6. Molecular magnetic materials based on 4d and 5d transition metals, Xin-Yi Wang,* Carolina Avendano and Kim R Dunbar, Chem. Soc. Rev.2011, 40, 3213-3238. 7. A docosanuclear Mo8Mn14 cluster based on [Mo(CN)7]4−, Xin-Yi Wang,; Andew V Prosvirin and K. R. Dunbar*, Angew. Chem. Int. Ed.2010, 49, 5081-5084. (封面) 8. Trigonal bipyramidal magnetic molecules based on [MoIII(CN)6]3-, Xin-Yi Wang, Matthew G. Hilfiger, Andrew V Prosvirin, Kim R Dunbar,* Chem. Commun. 2010, 4484. 9. Solvent templated azido-bridged Co2+ layers: square, honeycomb, and Kagomé, Xin-Yi Wang, Lu Wang, Zhe-Ming Wang, Song Gao,* J. Am. Chem. Soc.2006, 128, 674.