王新平 - 中国科学院上海有机化学研究所 - 金属有机化学国家重点实验室

个人简介

Biography 1993/9-1997/6, Sichuan University, Chemistry, Bachelor degree, Tutor: Professor Chen Yaoqiang 1997/9-2000/6, Lanzhou University, Chemistry, Master, Tutor: Professor Zeng Zhengzhi 2001/9-2007/6, University of New Brunswick, Canada, Chemistry, PhD, Supervisor: Professor Jack Passmore 2007/11-2010/10, University of California, Davis, Chemistry, Postdoctoral, supervisor: Professor Philip P. Power 2010/11-2012/3, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Associate Professor 2012/4-2023/2, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Professor 2022/7-present, State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Professor Awards and Honors Class A of the High-level Talent Initiative of the Chinese Academy of Sciences (2022) National Talent Program Leading Talent (2019) Young and middle-aged Leading Talents in Science and Technology Innovation of the Ministry of Science and Technology (2016) Cheung Kong Scholars Program Distinguished Professor of Ministry of Education (2015) National Science Foundation for Outstanding Young People (2015) Science Foundation for Outstanding Youth of Jiangsu Province (2014) Entrepreneurship and Innovation Plan of Jiangsu Province (2013) New Century Excellent Talents Support Program of Ministry of Education (2012) National Overseas Young Talents Program (2011) Outstanding Young Key Teachers Program of Nanjing University (2011) National Scholarship for Outstanding Self-Funded Foreign Students of Ministry of Education (2006)

研究领域

课题组根据空间位阻效应和电子性质，设计配体，合成自由基化合物，结合光(波)谱表征技术和量子化学计算, 对生成的自由基化合物的结构、化学健本质和反应机理进行深层次的研究，并挖掘自由基化合物可能具有的功能特性如催化、发光、导电和磁性等，来发现和解决基础化学领域中的重要问题。新型自由基化合物的合成基于自由基的活化与催化自由基光电功能自由基分子磁体

近期论文

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Tao Wang, Shuxuan Tang, Xue Dong, Yu Zhao, Quanchun Sun, Shanshan Kong, Yue Zhao, Xinping Wang*, Rational Design of Crystalline and Enantiomerically Pure Helicenes with Open-Shell Singlet Ground States. Angew. Chem. Int. Ed. 2024, 10.1002/anie.202415331 Yu Zhao, Yuchen Zhang, Tao Wang, Runbo Pei, Yue Zhao, Xiao-Song Xue,* Xinping Wang*, A Thermally Populated Germylene-Based Donor-Acceptor Diradical, Angew. Chem. Int. Ed. 2024, 10.1002/anie.202411180. Runbo Pei+, Wenju Chang+, Liancheng He+, Tao Wang, Yue Zhao, Yong Liang*, Xinping Wang*. Main-Group Compounds Selectively Activate Natural Gas Alkanes under Room Temperature and Atmospheric Pressure. Nat. Commun. 2024, 15, 7943. Xiaona Liu,Yuyang Dai, Qidi Bao, Qianli Li, Ning Chen, Yuanting Su and Xinping Wang. An Isolable T-shaped Planar Silyl Anion, Angew. Chem. Int. Ed. 2024, 63，e202406089. Shanshan Kong, Liming Yang, Quanchun Sun,Tao Wang, Wenqing Wang, Yu Zhao, Runbo Pei, Yue Zhao, Haiyan Cui,* Xinggui Gu,* and Xinping Wang,*Metal-free catalytic formation of a donor-acceptor-donor molecule and its Lewis acid- adduct singlet diradical with high-efficient NIR-II photothermal conversion. Angew. Chem. Int. Ed. 2024, 63, e202400913. Shuxuan Tang, Xinping Wang.* Spin frustration in organic radicals. Angew. Chem. Int. Ed.2024，63, e202310147. Quanchun Sun, Haowen Chen, Yu Zhao, Tao Wang, Runbo Pei, Yue Zhao, Shengfa Ye, Xinping Wang.* A Discrete, Boron-Containing Triangular Triradical. Chem. Eur. J. 2024, 30,e202302582. Runbo Pei, Liancheng He, Yue Zhao, Xinping Wang.* The dynamic Lewis acid-carbene hybrid: pushing the electrophilicity of carbenes to the limit. J. Am. Chem. Soc. 2023，145, 40, 21733–21737 Xue Dong, Qian-Cheng Luo, Yu Zhao, Tao Wang, Quanchun Sun, Runbo Pei, Yue Zhao, Yan-Zhen Zheng* -and Xinping Wang*. A Dynamic Triradical：Synthesis, Crystal Structure and Spin Frustration. J. Am. Chem. Soc. 2023,145, 31, 17292–17298 Min Liu,Xing Yang,Quanchun Sun, Tao Wang,Runbo Pei, Xingyu Yang,Yue Zhao,Lili Zhao*,Gernot Frenking*,and Xinping Wang*. Lewis Acid-Mediated Radical Stabilization and Dynamic Covalent Bonding: Tunable, Reversible and Photocontrollable. Angew. Chem. Int. Ed. 2023,62，e202300068. Wenqing Wang , Xiao-Hui Ma , Min Liu , Shuxuan Tang, Xuguang Ding, Yue Zhao, Yuan-Zhi Tan,* Miklos Kertesz,* and Xinping Wang*. A Triply Negatively Charged Nanographene Bilayer with Spin Frustration. Angew. Chem. Int. Ed. 2023, 62, e202217788 . Dongmin Wang, Cai Zhai, Yizhen Chen, Yuhao He, Xiao-dan Chen, Shanle Wang, Lili Zhao, Gernot Frenking, Xinping Wang & Gengwen Tan . An isolable germylyne radical with a one-coordinate germanium atom. Nature Chem ,2023，15，200–205 Shanshan Kong, Shuxuan Tang, Tao Wang, Yu Zhao, Quanchun Sun, Yue Zhao and Xinping Wang*. Stable Radical Ion Pairs Induced by Single Electron Transfer: Frustrated Versus Nonfrustrated. CCS Chem. 2023, 5, 334–340. Xiaona Liu, Yuyang Dai, Manling Bao, Wenjuan Wang, Qianli Li, Chunmeng Liu, Xinping Wang * and Yuanting Su *.A crystalline T-shaped planar group 14 anion. Chem. Sci. 2023, 14, 5722. Shuxuan Tang, Huapeng Ruan, Xue Dong, Yue Zhao, and Xinping Wang*. Ferromagnetic Exchange Coupling in Ni(II) Complexes with a Coordinated Boron-Oxamido Radical: A Result of Spin State Transition. Chin. J. Chem. 2023, 41, 1163—1169. Jie Wang, Haiyan Cui, Huapeng Ruan, Yu Zhao, Yue Zhao, Li Zhang,* and Xinping Wang*. The Lewis Acid Induced Formation of a Stable Diradical with an Intramolecular Ion Pairing State. J. Am. Chem. Soc. 2022, 144, 7978-7982. Zhongtao Feng, Shuxuan Tang,Yuanting Su and Xinping Wang *. Recent advances in stable main group element radicals: preparation and characterization. Chem. Soc. Rev., 2022, 51, 5930–5973. Shuxuan Tang, Huapeng Ruan, Zhaobo Hu, Yue Zhao, You Song and Xinping Wang *. A cationic sulfur-hydrocarbon triradical with an excited quartet state. Chem. Commun., 2022,58, 1986. Ke Li, Zhongtao Feng, Huapeng Ruan, Quanchun Sun, Yue Zhao and Xinping Wang *. The catenation of a singlet diradical dication and modulation of diradical character by metal coordination. Chem. Commun., 2022, 58, 6457. Qiang Sun, Min Liu, Huapeng Ruan,Chao Chen, Yue Zhao, Gengwen Tan * and Xinping Wang *. The cis/trans conformation approach for tuning the magnetic coupling in a diradical: isolation of pure pyridine-based diradical dianions. Chem. Commun., 2022, 58, 1708. Xue Dong, Quanchun Sun, Zhongtao Feng, Huapeng Ruan, Shuxuan Tang, Min Liu, Yue Zhao, Yuanting Su,* and Xinping Wang*. Room-Temperature Reversible σ-Dimerization of a Phenalenyl Radical. Chin. J. Chem. 2022, 40, 1655—1661. Zhongtao Feng,Yuanyuan Chong, Shuxuan Tang, Yong Fang, Yue Zhao, Jun Jiang* and Xinping Wang*. A stable triplet diradical emitter. Chem. Sci., 2021, 12, 15151. Zhongtao Feng, Yuanyuan Chong, Shuxuan Tang, Huapeng Ruan, Yong Fang, Yue Zhao, Jun Jiang,* and Xinping Wang*, Stable Boron-Containing Blue-Photoluminescent Radicals. Chin. J. Chem. 2021, 39, 1297—1302. Haiyan Cui, Zhao-Bo Hu, Chao Chen, Huapeng Ruan,a Yong Fang,a Li Zhang,d Yue Zhao,a Gengwen Tan,*c You Song *a and Xinping Wang*a. A high-spin diradical dianion and its bridged chemically switchable single-molecule magnet. Chem. Sci., 2021, 12, 9998-10004. Haiyan Cui,* Liting Wang, Huapeng Ruan, Min Liu, Zhongtao Feng, Jie Wang, Yue Zhao and Xinping Wang*. Controlling the unpaired electron by electrostatic attraction in the solid state. Chem. Commun., 2021, 57, 13345. Wenbang Yang, Wenqing Wang,* Leran Zhang, Li Zhang, Huapeng Ruan,Zhongtao Feng, Yong Fang and Xinping Wang*. Persistent 2c–3e r-bonded heteronuclear radical cations centered on S/Se and P/As atoms. Chem. Commun., 2021,57, 5067. Jie Wang, Huapeng Ruan, Zhaobo Hu, Wenqing Wang, Yue Zhao, and Xinping Wang*. Indeno[2,1-a]fluorene-11,12-dione radical anions：synthesis，characterization and property. Chem. Eur. J. 2021, e202103897(1 of 8). Yong Fang, Qiang Sun, Xiaoyu Chen, Yunfan Qiu, Chao Chen, Lei Wang,Yue Zhao, Yuanting Su,* Tao Li,* Li Zhang* and Xinping Wang. Rational design and syntheses of aniline-based diradical dications: isolable congeners of quinodimethane diradicals. Org. Chem. Front., 2021, 8,891-900. Wenbang Yang, Li Zhang, Dengmengfei Xiao, Rui Feng, Wenqing Wang, Yue Zhao, Lili Zhao,* Gernot Frenking,* Xinping Wang,* A Diradical Based on Odd-Electron σ-Bonds.Nat Commun，2020.11,3441. De-Hui Tuo, Chao Chen, Huapeng Ruan, Qi-Qiang Wang, Yu-Fei Ao, Xinping Wang,* De-Xian Wang,* Magnetic Multistability in an Anion Radical Pimer.Angew. Chem. Int. Ed. 2020, 59, 14040–14043. Shuxuan Tang, Li Zhang, Huapeng Ruan, Yue Zhao and Xinping Wang,* A Magnetically Robust Triplet Ground State Sulfur-Hydrocarbon Diradical Dication.J. Am. Chem. Soc.2020, 142, 16, 7340–7344. Chao Chen, Huapeng Ruan, Zhongtao Feng, Yong Fang, Yue Zhao, Yuanting Su,* and Xinping Wang,* Crystalline Diradical Dianions of Azaacenes.Angew. Chem. Int. Ed. 2020, 59, 11794–11799. Zhongtao Feng,Yong Fang,Huapeng Ruan, Yue Zhao, Gengwen Tan,* Xinping Wang,* Stable Radical Cation and Dication of an N-Heterocyclic Carbene Stabilized Digallene: Synthesis, Characterization and Reactivity.Angew. Chem. Int. Ed. 2020, 59, 6769 –6774. aiyan Cui, Dengmengfei Xiao, Li Zhang, Huapeng Ruan, Yong Fang, Yue Zhao, Gengwen Tan,* Lili Zhao,* Gernot Frenking,* Matthias Driess and Xinping Wang.* Isolable cyclic radical cations of heavy main-group elements.Chem. Commun. 2020, 56, 2167. Wenqing Wang, Gengwen Tan, Rui Feng, Yong Fang, Chao Chen, Huapeng Ruan, Yue Zhao and Xinping Wang.* Stable, yet “Naked”, Azo Radical Anion ArNNAr·– and Dianion ArNNAr2- (Ar = 4-CN-2,6-iPr2-C6H2) with Selective CO2 Activation.Chem. Commun.2020, 56, 3285--3288. Chao Chen, Zhaobo Hu, Huapeng Ruan, Yue Zhao, Yi-Quan Zhang, Gengwen Tan,* You Song,* Xinping Wang,* Tuning the Single-Molecule Magnetism of Dysprosium Complexes by a Redox-Noninnocent Diborane Ligand, Organometallics 2020,39, 23, 4143–4148. Xiaobo Pan, Li Zhang, Yue Zhao, Gengwen Tan,* Huapeng Ruan* and Xinping Wang,* Zig-zag diphosphene oligomers linked by silver(I) cation. Chinese Journal of Chemistry, 2020, 38, 351.