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课题组的研究主要是通过开发新的合成方法和策略,并辅以计算化学方法,制备在气体吸附、分离、催化、光电以及能源存储和转化等领域有应用前景的新型多孔材料和能源材料。 当前研究课题: 1.分子筛催化剂:着重研究具有超大孔道、交叉孔道等特殊孔道结构的新型硅铝酸盐沸石分子筛材料的设计合成,开发其在石油和精细化工中催化裂解、催化加氢等领域的应用性能。 2.能源储存材料:针对锂离子电池、超级电容器等储能体系,研究开发新型高性能电极材料、电解质材料和新技术,以期获得具有应用价值的能源储存系统和技术。 当前,我课题组开发出了具有应用价值的超大孔硅铝酸盐分子筛、用作锂离子电池负极材料的多孔硅、纳米硅、多孔碳球等材料,欢迎联系洽谈应用推广!

近期论文

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Yun-Shan Xue, Feng-Yan Jin, Lian Zhou, Mei-Pin Liu, Yan Xu, Hong-Bin Du,* Min Fang,* Xiao-Zeng You, ""Structural diversity and properties of coordination polymers built from a rigid octadentenate carboxylic acid"", Cryst. Growth Des., 2012, 12, 6158−6164. Jun Zhang, Yun-Shan Xue, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""Four cluster-based coordination polymers built on a semirigid tripod tricarboxylate ligand"", CrystEngComm, 2012, 14, 8215–8221. Jun Zhang, Yun-Shan Xue, Hong-Mei Wang, Min Fang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""Three open-framework coordination polymers with new topological structures built on two tripod ligands"", Inorg. Chim. Acta 2012, 392, 148-152. Gen-Wu Ge, Zhi-Yuan Qi, Zhi-Gang Ni, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""Solvothermal synthesis, structure and characterization of 1D chain and 2D layered rare earth sulfates in the presence of cyclic diamines"", Inorg. Chem. Commun. 2012, 20, 228-233. Mei-Pin Liu, Cheng-Hui Li, Hong-Bin Du,* Xiao-Zeng You, ""Facile preparation of silicon hollow spheres and their use in electrochemical capacitive energy storage"", Chem. Commun. 2012, 48, 4950-4952. (Back cover) Gen-Wu Ge, Yu-Xiang Hu, Mei-Pin Liu, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""The crystal structure and characterization of 2-D and 3-D indium phosphates synthesized from a water/ethylene glycol mixed-solvent system"", Inorg. Chem. Acta 2012, 385, 39-44. Yun-Shan Xue, Yanfeng Yue, Shi-Bin Ren, Le Zhou, Jun Zhang, Yi-Zhi Li, Hong-Bin Du,* Xiao-Zeng You, Banglin Chen*, ""Flexible octadentate ligand based robust microporous metal-organic frameworks with high gas storage and selective adsorption properties"", J. Mater. Chem. 2012, 22, 10195-10199. Ling-Ling Qu, You-Long Zhu, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""Structural diversity and properties of coordination polymers built from a semirigid tetradentenate carboxylic acid"", CrystEngComm 2012, 14, 824-831. (Top 10 Most Accessed Articles in November 2011). Hong-Bin Du, Xiao-Zeng You, ""Design and synthesis of functional coordination compounds with optoelectronic properties (Review)"", Huaxue Tongbao, 2011, 74(11), 989-994 (Invited, in Chinese)(""国际化学年在中国""专栏). Jun Zhang, Yun-Shan Xue, Jing Bai, Min Fang, Yi-Zhi Li, Hong-Bin Du,* Xiao-Zeng You, ""An unprecedented (3,7)-connected microporous solvatochromic coordination polymer built on a semirigid tripod pyridinium-4-olate ligand"", CrystEngComm, 2011, 13, 6010-6012. You-Long Zhu, Ling-Ling Qu, Jun Zhang, Gen-Wu Ge, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""In situ formation of an unprecedented 3D microporous CuCN coordination polymer based on a semirigid tetrahedral linker"", Inorg. Chem. Commun., 2011, 14, 1644-1647. Ling-Ling Qu, You-Long Zhu, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""Solvent-controlled synthesis of zinc(II) and manganese(II) coordination polymers with a semirigid tetracarboxylic acid"", Crystal Growth & Design, 2011, 11(6), 2444-2452. ( Top 10 Most Read Articles for Q2 2011) Gen-Wu Ge, Mei-Pin Liu, Zhi-Gang Ni, Hong-Bin Du*, ""Synthesis, characterization and fluorescent study of two 3-D open-framework rare-earth sulfates [Ln4(H2O)4(SO4)10] (C4N2H12)4(H2O)4 (Ln = Gd, Eu)"", Chemical Journal of Chinese Universities, 2011, 32(3), 644-649 (Invited, in Chinese) (""庆祝徐如人教授和庞文琴教授执教六十年暨八十华诞""专刊). Jun Zhang, Yun-Shan Xue, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""Cuprous iodide coordination polymers (CuI)x(L)y.z(solvent) built on linear thioether linkers"", CrystEngComm, 2011, 13, 2578-2585. Shi-Bin Ren, Le Zhou, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""A Cu4(SCN)4 Cubane Cluster-Based Microporous Coordination Polymer with a Diamond Net"", Inorg. Chem. Commun., 2011, 14, 558-561. Li-Li Liang, Shi-Bin Ren, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""Two Thermostable Three-Dimensional Homochiral Metal-Organic Polymers with Quartz Topology"", Crystal Growth & Design, 2010, 10(3), 1307-1311. Shi-Bin Ren, Le Zhou, Jun Zhang, You-Long Zhu, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, ""A 4-connected 3D porous coordination polymer with a binodal 6^2.8^4 net built on tetrahedral quadridentate and bidentate linkers"", CrystEngComm, 2010, 12(5), 1635 - 1638. Xiao-Li Yang, Jun Zhang, Yi-Zhi Li, Hong-Bin Du,* Xiao-Zeng You*, ""Synthesis and characterization of two 2D layered new coordination polymers of Co/Ni with the ligand of 1,4-bis(imidazol-1-ylmethyl)benzene"", Chinese Journal of Inorganic Chemistry, 2010, 26(3), 374-378 (in Chinese). Xiao-Li Yang, Jun Zhang, Shi-Bin Ren, Yi-Zhi Li, Hong-Bin Du,* Xiao-Zeng You*, ""A three-dimensional semiconducting superlattice built up of neutral [Zn10(μ3-S)4(SPhMe-4)12(DMF)4] supertetrahedral clusters"", Inorg. Chem. Commun. 2010, 13(4), 546–549.

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