燕红 - 南京大学 - 配位化学国家重点实验室

个人简介

燕红，女，1965年生，教授，博导，国家杰出青年基金获得者，俄罗斯自然科学院外籍院士。 1983-1990内蒙古大学化学系本科及硕士生；1990-1993年南京大学博士生；1993年毕业后留校任南京大学配位化学国家重点实验室讲师（1993-1995)。此后分别在瑞士Neuchatel（1996-1997）及德国Bayreuth（1997-2000）从事博士后研究；在美国Notre Dame（2000-2004）做研究助理，2005年起为美国Nanova Inc.化学家， 2005年9月应聘为南京大学教授，2006年3月评为博士生导师。2006-2007年任无机化学教研室主任，2008-2015年任无机学科副主任，2009-2015年任南京大学化学化工学院公共仪器平台主任。2015-2016年担任化学化工学院副院长。2008年被评为江苏省“青蓝工程”优秀中青年学术骨干带头人。2009年获国家杰出青年基金。2011年被聘为南京微结构国家实验室（筹）唐仲英特聘教授, 2012年入选南京大学高层次学科带头人（特聘教授）奖励计划。2012 年获教育部自然科学二等奖。2015年当选为俄罗斯自然科学院外籍院士。教学与科研涉及领域为配位化学，金属有机化学，有机化学，有机发光材料等，已在国内外刊物上发表研究论文150 余篇。2013-2015为美国化学会Organometallics 国际编委。 Education: 1983 B. Sc., Inner Mongolia University, Hohhot, China 1987 Ms. Sc., Inner Mongolia University, Hohhot, China 1990 Dr. Sc., Nanjing University, Nanjing, China 1993 Lecturer, Nanjing University, Nanjing, China 1996 Postdoc., University of Neuchâtel, Neuchâtel, Switzerland 1997 Postdoc., University of Bayreuth, Bayreuth, Germany 2000 Research Associate, University of Notre Dame, Notre Dame, USA 2005 Prof., Nanjing University, Nanjing, China Honor: 2009: The recipient of Distinguished Young Researcher by NSFC 2013-2015: International Advisory Board for Organometallics 2015: Foreign member of Russian Academy of Natural Sciences

研究领域

1.Selective cage B-H activation: Caboranes have potential applications in BNCT, function materials, and supramolecular chemistry. However, regioselective functionalization of carboranes has been great challenge for years. In view of the key roles of chelating groups in C-H activation, we will design suitable directing groups for the functionalization of carboranes via cage B-H activation. （金属协助的惰性X-H键（X=C,B）活化及功能化，以及机理的研究）； 2.Luminescent carborane-backbones: This project seeks for novel luminescent molecules, where a carborane skeleton is incorporated and investigated for tuning luminescence. （碳硼烷调控有机/金属有机分子的发光（白光，近红外及热延迟）及潜在应用）； 3.Phosphorescent bio-probes: We have developed novel phosphorescent iridium(III) complexes that bear substituted closo-carborane/nido-carboranyl units. These complexes show enhanced and tunable emission properties, long lifetime, and high phosphorescence efficiency, which have been successfully applied in cell imaging. （碳硼烷类衍生物的生物活性（包括用于生物探针）研究

近期论文

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Direct B–H Functionalization of Icosahedral Carboranes via Hydrogen Atom Transfer, Hongyuan Ren, Ping Zhang, Jingkai Xu, Wenli Ma, Deshuang Tu,* Chang-sheng Lu,* Hong Yan*, J. Am. Chem. Soc. 2023, 145, 7638-7647. Photoinduced Selective B−H Activation of nido-Carboranes, Shengwen Xu, Hongjian Zhang, Jingkai Xu, Weiqun Suo, Chang-Sheng Lu, Deshuang Tu,* Xingwei Guo,* Jordi Poater,* Miquel Solà,* and Hong Yan*，J. Am. Chem. Soc. 2024, 146,7791−7802 Molecular engineering of AIE-active boron clustoluminogens for enhanced boron neutron capture therapy, Wenli Ma Yanyang Wang, Yilin Xue, Mengmeng Wang, Changsheng Lu, Wanhua Guo, Yuan-Hao Liu, Diyun Shu, Guoqiang Shao, Qinfeng Xu,* Deshuang Tu,* and Hong Yan*, Chem. Sci., 2024,15, 4019-4030 A Hot Exciton Luminogen Constructed by an o-Carborane Scaffold Xiao Yu, Jingkai Xu, Mengmeng Wang, Xiaofei Miao, Quli Fan, Deshuang Tu, Zhaojin Wang,* Chunbo Duan,* Changsheng Lu,* Hui Xu,* and Hong Yan*，Adv. Optical Mater. 2024, 2302218 Meng Chen,+ Jingkai Xu,+ Deshi Zhao, Fangxiang Sun, Songlin Tian, Deshuang Tu,* Changsheng Lu*and Hong Yan*. Site-Selective Functionalization of Carboranes at Electron-Rich Boron Vertex: Photocatalytic B-C Coupling via a Carboranyl Cage Radical. Angew. Chem. Int. Ed.2022, e202205672. Fangxiang Sun, Shuaimin Tan, Hou-Ji Cao, Jingkai Xu, Vladimir I. Bregadze,Deshuang Tu,* Changsheng Lu,* and Hong Yan*. Palladium-Catalyzed Hydroboration of Alkynes with Carboranes:Facile Construction of a Library of Boron Cluster-Based AIE-Active Luminogens. Angew. Chem. Int. Ed. 2022, e202207125. Lihao Guo, Xiao Yu, Jiahui Du, Wei Li, Vladimir Bregadze, Deshuang Tu,* Changsheng Lu,* and Hong Yan*. Remote Effect from Boron Cluster: Tunable Photophysical Properties of o-Carborane-Based Luminogens. Chem. Eur. J., 2022, 28, e202200303. Hou-ji Cao, Meng Chen, Fangxiang Sun, Yue Zhao, Changsheng Lu, Xiaolei Zhang,* Zhuangzhi Shi,*and Hong Yan* . Variable Metal Chelation Modes and Activation Sequence in PdCatalyzed B-H Poly-arylation of Carboranes. ACS Catal. 2021, 11, 14047-14057. Hou-Ji Cao, Xing Wei, Fangxiang Sun, Xiaolei Zhang,* Changsheng Lu *and Hong Yan*. Metal-catalyzed B–H acylmethylation of pyridylcarboranes: access to carborane-fused indoliziniums and quinoliziniums. Chem. Sci., 2021, 12, 15563. Ronghui Huang, Weijia Zhao, Shengwen Xu, Jingkai Xu, Chunxiao Li, Changsheng Lu * and Hong Yan *. Photoredox B–H functionalization to selective B–N(sp3) coupling of nido-carborane with primary and secondary amines. Chem. Commun., 2021, 57, 8580–8583. Jiaxin Li, Jinkai Xu, Linbo Yan, Changsheng Lu and Hong Yan. A “flexible” carborane-cored luminogen: variable emission behaviours in aggregates. Dalton Trans., 2021, 50, 8029–8035. Chen, M.; Zhao, D.; Xu, J.; Li, C.-X.; Lu, C.-S.; Yan, H., Electrooxidative B-H Functionalization of nido-Carboranes. Angew. Chem. Int. Ed. 2020, 60, 7838-7844. Li, C.-X.; Ning, Q.; Zhao, W.; Cao, H.-J.; Wang, Y.-P.; Yan, H.; Lu, C.-S.; Liang, Y., Rh-Catalyzed Decarbonylative Cross-Coupling between o-Carboranes and Twisted Amides: A Regioselective, Additive-Free, and Concise Late-Stage Carboranylation. Chem. - Eur. J. 2021, 27, 2699-2706. Description of an Unusual Hydrogen Bond between Carborane and a Phenyl Group, Wenli Zou, Xiaolei Zhang, Humin Dai, Hong Yan,* Dieter Cremer and Elfi Kraka *, J. Organomet. Chem. .V. Timofeev, O.B. Zhidkova, I.B. Sivaev, Z.A. Starikova, K.Yu. Suponitsky, H. Yan*, V.I. Bregadze*, Synthesis of rhodacarboranes containing σ- and π-carboranyl ligands in one molecule, J. Organomet. Chem., doi: 10.1016/j.jorganchem.2017.11.014 Transition Metal-induced B–H Functionalization of o-Carborane, Xiaolei Zhang, Hong Yan*, Coord. Chem. Rev. 2017, online. yridyl Directed Cp*Rh(III) Catalyzed B(3)–H Acyloxylation of o-Carborane, Chun-Xiao Li, Hao-Yun Zhang, Tsz-Yung Wong, Hou-Ji Cao, Hong Yan*, Chang-Sheng Lu*, Org. Lett. 2017, 19, 5178-5181. A novel phosphorescent iridium(III) complex bearing donor-acceptor-type o-carboranylated ligand for endocellular hypoxia imaging，Xiang Li, Yongheng Yin, Hong Yan,* Changsheng Lu,* and Qiang Zhao*，Dalton Trans.2017, 46, 13802 – 13810. Reactivity of Half-Sandwich 16 Electron Compound CpCo(S2C2B10H10) with Ethyl Diazoacetate and Allenes, Gui-Feng Liu, Hong Yan, Chinese J. of Inorg. Chem. 2017, 33, 487-492. Highly-Emissive Organic Single-Molecule White Emitters by Engineering o-Carborane-based Luminophores, Deshuang Tu, Pakkin Leong, Song Guo, Hong Yan,* Changsheng Lu* and Qiang Zhao*, Angew. Chem. Int. Ed. 2017, 56(38), 11370-11374. Pd(II)-Catalyzed Synthese of Benzyl Benzoates via Benzyl C(sp3)−H Activation, Dan-dan Duanmu, Pak-kin Leong, Qi-bai Jiang, * and Hong Yan,* Chinese J. of Org. Chem.2017, 37, 2669-2677. Progress in Selective B-H Bond Functionalization of Carborane, Huanhuan Li, Hong Yan*, Changsheng Lu*, Chinese J. Inorg. Chem.2017, 33, 1313-1329. Base–Promoted Decarboxylative Azo–Coupling: Construction of Unsymmetrical Azocarboranes Huan–huan Li, Fan Bai, Hong Yan* and Chang–sheng Lu*, Org. Lett.2017, 19, 862-865. Iridium(III)–Catalyzed Selective Sulfonamidation of o–Carborane with Sulfonyl Azides via Carboxylic Acid–Assisted B (4)–H Bond Activation, Huanhuan Li, Fan Bai, Hong Yan* and Changsheng Lu*, Vladimir, I, Bregadze*, Eur. J. Org. Chem. 2017, 1343–1352. Selective Catalytic B−H Arylation of o‑Carboanyl Aldehydes by a Transient Directing Strategy, Xiaolei Zhang,* Hongning Zheng, Jie Li, Fei Xu, Jing Zhao, and Hong Yan*,J. Am. Chem. Soc. 2017,139, 14511-14517. Novel phosphorescent cationic iridium(III) complexes with o- carboranylation on the ancillary N^N ligand, Xiang Li, Yongheng Yin, Hong Yan,* Changsheng Lu,* and Qiang Zhao*, Dalton Trans. 2017, 46, 10082–10089. Aggregation–induced emission characteristics of o-carborane-functionalized tetraphenylethylene luminogens: the influence of carborane cages on photoluminescence, Xiang Li, Yongheng Yin, Hong Yan*, and Changsheng Lu*, Chem.Asian J. 2017, 12, 2207–2210. Using highly emissive and environmentally sensitive o-carborane-functionalized metallophosphors to monitor mitochondrial polarity , Xiang Li, Xiao Tong, Yongheng Yin, Hong Yan,* Changsheng Lu,* Wei Huang, and Qiang Zhao*, Chem. Sci.2017, 8, 5930 –5940. Carborane derivative conjugated with gold nanoclusters for target cancer cell imaging, Jianling Wang, Leifeng Chen, Jing Ye, Zhiyong Li, Hui Jiang, Hong Yan*, Marina Y. Stogniy, Igor Sivaev, Vladimir I. Bregadze and Xuemei Wang*, Biomacromolecules 2017, 18,1466-1472. A Highly Potent Antibacterial Agent Targeting Methicillin-Resistant Staphylococcus aureus Based on Cobalt Bis(1,2-Dicarbollide) Alkoxy Derivative, Youkun Zheng, Weiwei Liu, Yun Chen, Hui Jiang, Hong Yan, Irina Kosenko, Lubov Chekulaeva, Igor Sivaev, Vladimir Bregadze, and Xuemei Wang*, Organometallics2017, 36, 3484-3490. Copper(II) Catalyzed Domino Synthesis of Quinoline Derivatives from Arylamines and Alkynes,Huimin Dai, Zihao Wang, Chao Yu and Hong Yan*, Changsheng Lu*, Org. Chem. Front.2017, 4, 2008 – 2011.