研究领域
1. 烯烃聚合、开环移位聚合导向的金属有机化学
2. 金属有机导向的有机合成方法学
近期论文
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Hao Zhang, Yunjie Luo, Zhaomin Hou*“Scandium-Catalyzed Syndiospecific Copolymerization of Styrene with Isoprene” Macromolecules 2008, 41, 1064-1066.
Hao Zhang, Shohei Katao, Kotohiro Nomura*, Jiling Huang*“Synthesis of Nonbridged hlaf-titanocenes containing phenoxy-imine ligands and their use in catalysis for olefin polymerization”.Organometallics 2007, 26, 5967-5977.
Hao Zhang, Doo-Jin Byun, and Kotohiro Nomura*“Tuning the active species from syndiospecific styrene polymerisation to ethylene/styrene copolymerisation by (aryloxo)(cyclopentadienyl)titanium complexes - MAO catalysts”Dalton Trans. 2007, 18. 1802-1806.(cover article).
Hao Zhang, Kotohiro Nomura*“Ligand effect in syndiospecific styrene polymerization and ethylene/styrene copolymerization by some nonbridged half-titanocenes containing anionic donor ligands”Studies in Surface Science and Catalysis, 2006,161, 145-152.
Hao Zhang, Kotohiro Nomura*Living Copolymerization of Ethylene with Styrene Catalyzed by (Cyclopentadienyl)(ketimide) titanium(IV) Complex - MAO Catalyst System: Effect of Anionic Ancillary Donor Ligand”Macromolecules 2006, 39, 5266-5274.
Hao Zhang, Kotohiro Nomura*“Living Copolymerization of Ethylene with Styrene Catalyzed by (Cyclopentadienyl)(ketimide) titanium(IV) Complex - MAO Catalyst System”J. Am. Chem. Soc. 2005, 127, 9364-9365.SCI,
Kotohiro Nomura,* Hao Zhang, and Doo-Jin Byun“Factors Affecting Product Distributions in Ethylene/Styrene Copolymerization by (Aryloxo)(cyclopentadienyl)titanium Complexes - MAO Catalyst Systems”J. Polym. Sci. PartA: Polym. Chem., , 2008, 46, 4162-4174.
Hao Zhang, Jun Ma, Yanlong Qian, Jiling Huang*“Synthesis and Characterization of Cyclopentadienylchromium Complex Bearing Pendant Pyridine Group as Catalyst for Ethylene Polymerization”Organometallics. 2004, 23, 5681-5688.
Xueqin Sun, Jun Xie, Hao Zhang, Jiling Huang*“Various silyl-substituted cyclopentadienyl titanium complexes [CpSi(CH3)2X]TiCl3 as catalysts for syndiotactic polystyrene”Eur. Polym. J. 2004, 40, 1903-1908.
Yanlong Qian*, Hao Zhang, Junxia Zhou, Wei Zhao, Xueqin Sun, Jiling Huang*“Synthesis and polymerization behavior of various substituted half-sandwich titanium complexes Cp´TiCl2(OR*) as catalysts for syndiotactic polystyrene”J. Mol. Catal. A: Chem. 2004, 208(1-2), 45-54.
Yanlong Qian*, Jiling Huang, Muhammad D.Bala, BingLian, Hao Zhang, Hao Zhang“Synthesis, Structures, and Catalytic Reactions of Ring-Substituted Titanium(IV) Complexes”, Chem. Rev. 2003, 103 (7), 2633-2690.
Quanling Suo*, Hao Zhang, Yibing Wang, Li Wang, Linhong Wen, Xuebing Leng“Synthesis and structural characterization of {μ3-H(Ph)C=C}FeCo2(CO)7dppm(dppm=Ph2PCH2PPh2) and {μ3-H(Ph)C=C}FeCo2(CO)9-nLn [L=PPh3(n=1,2),AsPh3(n=1)]”J. Organomet. Chem. 2001, 63, 87-93.
Yanlong Qian*, Hao Zhang, Jiling Huang,“Synthesis and Characterization of Cyclopentadienylchromium Complexes Bearing Pendant o-Me2N-C6H4-C(CH3)(CH3)- Group as Catalysts for Ethylene Polymerization”Chinese Journal of Catalysis 2003, 21(7), 487-488.
Quanling Suo*, Hao Zhang, Yibing Wang, Jiehui Yan, Liming Han, Linghong Weng, Xuebing Leng“Synthesis and Molecular Structure of Substituted Derivatives of the Mixed-metal Carbonyl Clusters Bearing µ3-vinylidene Moiety”Chinese Journal of Inorganic Chemistry 2003, 19(5), 506-508.
Hao Zhang, Jiling Huang, Yanlong Qian*, “Progress in Synthesis of Chromium Catalysts and Their Application in Olefin Polymerization”Chinese Journal of Organic Chemistry 2003, 22(12), 981-989.
Hao Zhang, Quanling Suo*, Yibing Wang, LiWang, Linghong Weng,, Xuebing Leng “Synthesis and Crystal Structure of (μ3-S)FeCo2(CO)7dppfe”Acta Phys.-Chim. Sin. 2002, 18(8), 746-749.Manuscripts in preparation (tentative title)
Hao Zhang, Jun Ma, Yanlong Qian, Jiling Huang,“Synthesis and Characterization of Cyclopentadienylchromium Complex Bearing Pendant Furan Group as Catalyst for Olefin Polymerization”(To be submitted J. Organomet. Chem.)"
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