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配位化学、金属有机化学、络合催化

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Bao-Hua Zhu, Guo-Hua Xu, Zhi-Wei Xia, Ruthenium and Iron Carbonyl Clusters Catalyzed Reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl)benzamide, Advanced Materials Research, 2011, (in press) Bao-Hua Zhu, Chapter 15:PREPARATION, STRUCTURE AND PROPERTIES OF LINKED TRANSITION-METAL MULTINUCLEAR CARBONYL CLUSTERS in Organometallic Compounds: Preparation, Structure and Properties (ISBN: 978-1-60741-917-4) Editors: H.F. Chin, Nova Science Publishers, Inc. New York, Pub. 2010. Bao-Hua Zhu, Yusuke Shibata, Satoshi Muratsugu, Yoshinori Yamanoi, and Hiroshi Nishihara. A Cyclic Hexanuclear Heterometalladithiolene Cluster[{(Cp*Rh)2Mo(m-CO)2 (CO)}2(S2C6H2S2)2] with Two p-Conjugated S2C6S2 Bridges,: Synthesis, Crystal Structure, and Properties, Angew. Chem. Int. Ed., 2009, 48, 3858-3861. Bao-Hua Zhu, Yan-Hong Bai, Hong Hong and Shuang-Yu Gao, Synthesis and characterization of linked alkyne-bridging Co2C2 tetrahedral clusters and expansion reactions of (Co2(CO)6(μ-HCCCH2OOC))2R with Fe3(CO)12, Journal of Coordination Chemistry, 2009, 7, 1086-1090. Bao-Hua Zhu, Shuang-Yu Gao and Yan-Hong Bai, Synthesis and Characterization of the (μ3-CR)Co3 Tetrahedral Carbonyl Clusters Containing (μ3,η3-(PPh2CH2)3CCH3) Ligand and the Crystal Structure of Cluster (μ3-CPh)CCo3(CO)3(μ-CO)3(μ3,η3-(PPh2CH2)3CCH3), Journal of Cluster Science, 2008, 19,171­-179. Bao-Hua Zhu, Bin Hu, Hong Hong, Yuan-Qi Yin, Jie Sun. Reactions of linked tetrahedron clusters [Co2(CO)6(μ-HC2CH2CO)-]2R with Rh2(CO)4Cl2 to give mixed-metal linked alkyne-bridged butterfly clusters containing C2Co2Rh2 unit,J. Organomet. Chem., 2006, 691(3), 485-490. Bao-Hua Zhu, Yuan-Qi Yin. Synthesis and Characterization of New Mixed- metal Tetrahedral Carbonyl Clusters Containing (µ3-E)RuCoM (M=Co, Mo) Core and (-)-DIOP Diphosphine Ligand, Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2006, 36(4), 331-334. Bao-Hua Zhu, Hong Hong, Se Jing , Peng-Hui Lü, Jie Sun. Synthesis and crystal structure of the new binuclear iron carbonyl cluster containing the triphos and µ,η2-OCC6H5 ligands,J. Chem. Res.-S, 2006,1,43-44. Bao-Hua Zhu, Bin Hu, Yuan-Qi Yin, Jie Sun. Synthesis and characterization of new RuCoM (M=Co, Mo) mixed-metal linked tetrahedral clusters containing (-)-DIOP and reaction of [(µ3-Se)RuCo2(CO)8]2(DIOP) with Na[Mo(CO)3(η5-C5H4COCH3)], Polyhedron, 2005, 24(15), 2055-2061. Bao-Hua Zhu, Lei Zhang, Nu Xiao, Jia-Bi Chen, Yuan-Qi Yin and Jie Sun. Novel Rh-Mn mixed-metal carbonyl cluster containing µ3 and µ- bridging carbyne ligands, [(µ3-CC6H5)(µ-CC6H5)Rh2Mn2Cp2(µ-CO)3(CO)3]: structure, electro- chemistry and catalytic properties, Inorg. Chim. Acta, 2004, 357(3), 864-868. Bao-Hua Zhu, Hong Hong, Yuan-Qi Yin, Jie Sun,Synthesis and crystal structure of the chiral linked tetrahedral cluster [(µ3-Se)RuCo2(CO)8]2(DIOP), J. Chem. Res.-S, 2004, 11, 756-757. BAO-HUA ZHU, WEI-QIANG ZHANG, BIN HU, QUAN-YI ZHAO, YUAN- QI YIN and JIE SUN. REACTIONS OF trans-CARBONYL(CHLOROBIS (TRIPHENYLPHOSPHINE))RHODIUM(I) WITH SUBSTITUTED CYCLO- PENTADIENYL TRICARBONYL MOLYBDENUM ANION, J. Coord. Chem., 2003, 56(9), 817-823. Bao-Hua Zhu, Bin Hu, Wei-Qiang Zhang, Yu-Hua Zhang, Yuan-Qi Yin, Jie Sun. Synthesis and characterization of new rhodium and cobalt mixed-metal octahedral linked clusters containing η2-diyne ligands, J. Organomet. Chem., 2003, 681, 275-279. Zhu Bao-Hua, Hu Bin, Zhang Wei-Qiang, Bian Zhi-Guo, Zhao Quan-Yi,Yin Yuan-Qi, Sun Jie. Synthesis and Characterization of Rh-Co Butterfly Clusters Capped By Functionally Substituted 1-Alkynes, Chin. J. Stru. Chem., 2003, 22(1), 60-64. Bao-Hua Zhu, Wei-Qiang Zhang, Quan-Yi Zhao, Zhi-Guo Bian, Bin Hu, Yu-Hua Zhang, Yuan-Qi Yin, Jie Sun. Synthesis, characterization of new Rh-Co mixed-metal clusters and reactions of clusters containing [Rh2Co2C2] core with 1-alkynes and/or carbon monoxide, J. Organomet. Chem., 2002, 650, 181-187. Bao-Hua Zhu, Bin Hu, Yu-Hua Zhang, Wei-Qiang Zhang, Yuan-Qi Yin, Jie Sun. Syntheses and characterization of the new Rh-Co mixed-metal octahedral linked clusters, J. Chem. Res.-S, 2002, 622-623. Bao-Hua Zhu, Bin Hu, Wei-Qiang Zhang, Yuan-Qi Yin, Jie Sun. Synthesis and crystal structure of a novel butterfly cluster [Rh2Co2(CO)6(µ-CO)4(µ4,η2-HC≡CFeCp2)], J. Chem. Res.-S, 2002, 328-329. Yusuke Shibata, Baohua Zhu, Shoko Kume and Hiroshi Nishihara. Development of a versatile synthesis method for trinuclear Co(III), Rh(III), and Ir(III) dithiolene complexes, and their crystal structures and multi-step redox properties, Dalton Trans., 2009,1939-1943. Wei-Qiang Zhang, Bao-Hua Zhu, Bin Hu, Yu-Hua Zhang, Quan-Yi Zhao,Yuan-Qi Yin, Jie Sun. Studies of metal exchange reactions: the synthesis and structures of heteronuclear metal clusters containing the indenyl ligand, J. Organomet. Chem., 2004, 689, 714-721. ZHI-GUO BIAN, BAO-HUA ZHU, QING-SHAN LI, BIN HU, YUAN-QI YIN. PREPARATION AND CHARACTERIZATION OF CLUSTERS CONTAINING THE MNiRuS(M=Mo OR W) CORE, J. Coord. Chem., 2004, 57(4), 295-301. Bin Hu, Bao-Hua Zhu, Wei-Qiang Zhang, Quan-Yi Zhao, Yuan-Qi Yin, Jie Sun. The synthesis of tetrahedral clusters SOsCo2(CO)9, relevant to chiral tetrahedral clusters containing the SOsCoW core. J. Chem. Res.-S, 2004, 8, 517-518. Lei Zhang, Baohua Zhu, Nu Xiao, Qiang Xu, Nobuko Tsumori, Jie Sun, Yuanqi Yin, and Jiabi Chen, Remarkable Reactions of Cationic Carbyne Complexes of Manganese and Rhenium with the Carbonylrhodium Anion [Rh(CO)4]-. A Novel Route to Heteropolymetallic Bridging Carbyne Complexes with μ- and μ3-Carbyne Ligands,Organometallics,2003,22, 4369 -4371. Wei-Qiang Zhang, Bao-Hua Zhu, Bin Hu, Yu-Hua Zhang, Quan-Yi Zhao,Yuan-Qi Yin, Jie Sun. Synthesis of the chiral indenyl tetrahedral clusters [(µ3-S)FeCoM(η5-Ind)(CO)8](M=Mo,W) and the crystal structure of [(µ3-S) FeCoW(η5-Ind) (CO)8], J. Chem. Res.-S, 2003, 11, 730-731. Zhi-Guo Bian, Yu-Hua Zhang, Wei-Qiang Zhang, Bao-Hua Zhu, Yuan-Qi Yin and Jie Sun. Synthesis and Characterization of the Chiral Skeleton Cluster [NiRuMo(CO)5(µ3-S)(η5-C5H5)(η5-C5H4COCH3)], Chin. J. Stru. Chem., 2002, 21(5), 489-492. Zhao Quan-Yi, Zhang Yu-Hua, Hu Bin, Zhang Wei-Qiang, Zhu Bao-Hua, Yin Yuan-Qi, Xia Chun-Gu. Asymmetric inducing synthesis of optically active tetrahedral cluster containing SMCoW core, Chinese Journal of Chemistry, 2004, 22(7), 757-760. Zhi-Guo Bian, Yu-Hua Zhang, Bin Hu, Wei-Qiang Zhang, Bao-Hua Zhu, Yuan-Qi Yin and Jie Sun. Synthesis of Cluster Derivatives Containing the NiRuMoS Core. J. Chem. Res.-S, 2002, 1, 194-195. 朱保华,胡斌,张伟强,殷元骐,孙杰,铑钴四核簇合物的合成表征及其对苯乙烯的氢甲酰化反应性能的研究,分子催化,2005,19(1),61-64。 朱保华,刘树堂,配合物Co[S2P(O-i-C3H7)2]3的合成和晶体结构,化学研究与应用, 2002, 14(6), 671-674。 朱保华,刘树堂,簇合物Co4(μ3-S)[P(S)(OCH3)2]2(CO)9, Co4(μ,η2-S2)[P (O-i-C3H7)2]2(CO)10和 Co6(μ3-S)2(μ-PC(CH)3S)(μ6,η2- PC(CH)3S)(μ-CO)(CO)10的合成和谱学表征,内蒙古大学学报(自然科学版) 2001,32(4), 415-418。 胡 斌, 张玉华, 张伟强, 边治国, 朱保华, 殷元骐, 钌催化剂催化C=O加氢反应研究, 分子催化, 2001, 15(6), 404-406."

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