个人简介

2012 ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry 2011 Elected Fellow of the American Chemical Society 2002 Chair, ACS Division of Inorganic Chemistry 1992 Elected Fellow of American Association for the Advancement of Science

研究领域

Inorganic Chemistry

Recent advances in the instrumentation for small molecule X-ray crystallography have made it possible to complete a full structural characterization of a new material in less time, at less expense and with far less ambiguity than any other characterizational method currently available. Prof. Rheingold's research explores ways of using X-ray crystallography to provide very rapid and accurate structural characterizations of new compounds in collaboration with members of this department and with several hundred chemists from about fifty other departments worldwide. He welcomes inquiries regarding the establishment of new collaborations, particularly in the areas of inorganic and organometallic chemistry. His interest in crystallography arose from his research in the synthesis and properties of large cluster structures containing hybrid p-block and transition-metal atoms. These are often paramagnetic solids necessitating crystallographic characterization. A recent example is the di-cubane structure, {[(Cp*CrSe)3Se]2(µ6-As)}, shown below. It contains Cr in a non-integral oxidation state and it behaves ferromagnetically at low temperatures. Such hybrid clusters are of interest as precursors to new materials displaying thermoelectric and thermomagnetic properties. Simple tetrahedrane analogues such as [(CO)3CoAs3] are found to be excellent volatile precursors to skudderudite phases useful in high-temperature Seebach-effect applications. Both of these metal/p-block hybrid clusters was formed from p-block hetero- and homo-cyclic precursors; in the cases above: (CH3AsSe)3 and (CH3As)5.

近期论文

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CD Martin, CM Weinstein, CE Moore, AL Rheingold and G Bertrand "Exploring the Reactivity of White Phosphorus with Electrophilic P4 and P8 Clusters", Chemical Communications, 2013, Vol. 49, 4486-4488 D Martin, CE Moore, AL Rheingold and G. Bertrand "An Air-Stable Oxyallyl Radical Cation", Angew. Chem., Int. Ed., 2013, Vol. 52, 2014-2017 SF Hannigan, JS Lum, JW Bacon, CE Moore, J Golen, AL Rheingold and LH Doerrer "Room Temperature Stable Organocuprate Cu(III) Complex", Organometallics, 2013, Vol. 32, 3429-36 AE Carpenter, GW Margulieux, MD Millard, CE Moore, N. Weidemann, AL Rheingold and JS Figueroa "Zwitterion Stabilization of Reactive Cobalt Tris-isocyanide Monoanion by Cation Coordination", Angew. Chem., I.E., 2012, Vol. 51, 9412-9416 CL Perrin, P Karri, CE Moore and AL Rheingold "Hydrogen-Bond Symmetry in Difluoromaleate Monoanion", J. Am. Chem. Soc., 2012, Vol. 134, 7766-7772 E Shurda, SH Lapidus, PW Stevens, CE Moore, AL Rheingold and JS Miller "Extended Network Thiocyanate- and Tetracyanoethanide-Based First Row Transition-Metal Complexes", Inorganic Chemistry, 2012, Vol. 51, 9655-9665 DB Grotjahn, DB Brown, JK Martin, DC Marelius, MC Abadjian, NH Tran, G. Kalyuzhny, KS Vecchio, ZG Specht, SA Cortes-Llamas, V Miranda-Soto, C van Niekerk, CE Moore, AL Rheingold "Evolution of Iridium-Based Molecular Catalysts during Water Oxidation with Cerium Ammonium Nitrate", J. Am. Chem. Soc., 2011, Vol. 133, 19024-19027