舒兴中 - 兰州大学 - 化学化工学院

个人简介

2015-至今兰州大学化学化工学院、功能有机分子化学国家重点实验室，教授、博导 2012-2015 加州大学伯克利分校/劳伦斯伯克利国家实验室 (导师: F. Dean Toste教授)，博士后 2010-2012 威斯康辛大学麦迪逊分校 (导师: Weiping Tang教授)，博士后 2005-2010 兰州大学 (导师: 梁永民教授)，理学博士 2001-2005 绍兴文理学院，学士

研究领域

（1）非活性C-O键还原偶联化学；（2）氯硅（锗）烷还原偶联化学；（3）不对称还原偶联化学。

近期论文

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Enantioselective Reductive N‑Cyclization Alkylation Reaction of Alkene-Tethered Oxime Esters and Alkyl Iodides by Nickel Catalysis. Xuegong Jia, Qiwei Yao, and Xingzhong Shu*, J. Am. Chem. Soc. 2022, 144, 13461. Nickel-Catalyzed Reductive C(sp2)-Si Coupling of Chlorohydrosilanes via Si-Cl Cleavage. Zhenzhen Zhao, Xiaobo Pang, Xiaoxue Wei, Xueyuan Liu and Xingzhong Shu*, Angew. Chem. Int. Ed. 2022, 61, e202200215. Nickel-Catalyzed Cross-Electrophile 1,2-Silyl-Arylation of 1,3-Dienes with Chlorosilanes and Aryl Bromides. Qiuquan Pan, Liangliang Qi, Xiaobo Pang, and Xing-Zhong Shu*, Angew. Chem. Int. Ed. 2022, DOI:10.1002/anie.202215703, e202215703. Reductive Cross-Coupling of Unreactive Electrophiles. Xiaobo Pang, Pei-Feng Su, and Xing-Zhong Shu*, Acc. Chem. Res. 2022, 55, 2491. Ti-Catalyzed Reductive Dehydroxylative Vinylation of Tertiary Alcohols. Hao Xie, Sheng Wang, Yuquan Wang, Peng Guo and Xing-Zhong Shu*, ACS Catal. 2022, 12, 1018. Reductive Alkylation of Alkenyl Acetates with Alkyl Bromides by Nickel Catalysis. Rong-De He, Yunfei Bai, Guan-Yu Han, Zhen-Zhen Zhao, Xiaobo Pang, Xiaobo Pan, Xue-Yuan Liu, Xing-Zhong Shu*. Angew. Chem. Int. Ed. 2021, 61, DOI:10.1002/anie.202114556 Nickel-Catalyzed Reductive C−Ge Coupling of Aryl/Alkenyl Electrophiles with Chlorogermanes. Pei-Feng Su‡, Ke Wang‡, Xuejing Peng, Xiaobo Pang, Peng Guo, and Xing-Zhong Shu*. Angew. Chem. Int. Ed. 2021, 60, 26571-26576. Cobalt-Catalyzed Enantiospecific Dynamic Kinetic Cross-Electrophile Vinylation of Allylic Alcohols with Vinyl Triflates. Wei-Yuan Ma, Guan-Yu Han, Shaolin Kang, Xiaobo Pang, Xue-Yuan Liu, Xing-Zhong Shu. J. Am. Chem. Soc. 2021, 143, 15930-15935. Enantioselective Reductive Divinylation of Unactivated Alkenes by Nickel-Catalyzed Cyclization Coupling Reaction. Jin-Bao Qiao‡, Ya-Qian Zhang‡, Qi-Wei Yao, Zhen-Zhen Zhao, Xuejing Peng, and Xing-Zhong Shu. J. Am. Chem. Soc. 2021, 143, 12961-12967. Regiocontrolled Reductive Vinylation of Aliphatic 1,3-Dienes with Vinyl Triflates by Nickel Catalysis. Xiaobo Pang, Zhen-Zhen Zhao, Xiao-Xue Wei, Liangliang Qi, Guang-Li Xu, Jicheng Duan, Xue-Yuan Liu, and Xing-Zhong Shu. J. Am. Chem. Soc. 2021, 143, 4536-4542. Dynamic Kinetic Cross-Electrophile Arylation of Benzyl Alcohols by Nickel Catalysis. Peng Guo, Ke Wang, Wen-Jie Jin, Hao Xie, Liangliang Qi, Xue-Yuan Liu, and Xing-Zhong Shu. J. Am. Chem. Soc. 2021, 143, 513-523. Nickel-Catalyzed Cross-Electrophile C(sp3)-Si Coupling of Unactivated Alkyl Bromides with Vinyl Chlorosilanes. Jicheng Duan, Yuquan Wang, Liangliang Qi, Peng Guo, Xiaobo Pang, Xing-Zhong Shu*, Org. Lett. 2021, 23, 7855-7859. Nickel-Catalyzed Cross-Electrophile C(sp3)–Si Coupling of Unactivated Alkyl Bromides with Vinyl Chlorosilanes. CCS Chem.2021, 3, 1147-1154. Titanium: a Unique Metal for Radical Dehydroxylative Functionalization of Alcohols. Xiaobo Pang, Xing-Zhong Shu*, Synlett 2021, 32, 1269-1274. Synthesis of Dibenzyls Synthesis by Nickel-Catalyzed Homocoupling of Benzyl Alcohols. Feng-Feng Pan, Peng Guo, Xiaochuang huang, Xing-Zhong Shu*, Synthesis-Stuttgart 2021, 53, 3094-3100. Cross-Electrophile Csp2-Si Coupling of Vinyl Chlorosilanes. Jicheng Duan, Ke Wang, Guangli Xu, Shaolin Kang, Liangliang Qi, Xueyuan Liu, and Xingzhong Shu*. Angew. Chem. Int. Ed. 2020, 59, 23083-23088. Radical Dehydroxylative Alkylation of Tertiary Alcohols by Ti Catalysis. Hao Xie, Jiandong Guo, Yuquan Wang, Ke Wang, Peng Guo, Peifeng Su, Xiaotai Wang*, and Xingzhong Shu*. J. Am. Chem. Soc. 2020, 142, 16787-16794. Allylboronates from Vinyl Triflates and α-Chloroboronates by Reductive Nickel Catalysis. Jinbao Qiao, Zhenzhen Zhao, Yaqian Zhang, Kai Yin, Zhixiong Tian, and Xingzhong Shu*. Org. Lett. 2020, 22, 5085-5089. Reductive Coupling between C-N and C-O Electrophiles. Rongde He, Chunling Li, Qiuquan Pan, Peng Guo, Xueyuan Liu, and Xingzhong Shu*. J. Am. Chem. Soc. 2019, 141, 12481-12486. Highly Enantioselective Cross-Electrophile Aryl-Alkenylation of Unactivated Alkenes. Zhixiong Tian, Jinbao Qiao, Guangli Xu, Xiaobo Pang, Liangliang Qi, Weiyuan Ma, Zhenzhen Zhao, Jicheng Duan, Yunfei Du, Peifeng Su, Xueyuan Liu, and Xingzhong Shu*. J. Am. Chem. Soc. 2019, 141, 7637-7643. Ni-catalyzed cross-electrophile coupling between vinyl/aryl and alkyl sulfonates: synthesis of cycloalkenes and modification of peptides. Jicheng Duan, Yunfei Du, Xiaobo Pang, and Xingzhong Shu*. Chem. Sci. 2019, 10, 8706-8712. Enones from Acid Fluorides and Vinyl Triflates by Reductive Nickel Catalysis. Fengfeng Pan, Peng Guo, Chunling Li, Peifeng Su, and Xingzhong Shu*. Org. Lett. 2019, 21, 3701-3705. Dual nickel and Lewis acid catalysis for cross-electrophile coupling: the allylation of aryl halides with allylic alcohols. Xuegong Jia, Peng Guo, Jicheng Duan, and Xingzhong Shu*. Chem. Sci. 2018, 9, 640-645. Reductive coupling of benzyl oxalates with highly functionalized alkyl bromides by nickel catalysis. Xiaobiao Yan, Chunling Li, Wenjie Jin, Peng Guo, and Xingzhong Shu*. Chem. Sci. 2018, 9, 4529-4534. Silica-Supported Cationic Gold(I) Complexes as Heterogeneous Catalysts for Regio- and Enantioselective Lactonization Reactions. Xingzhong Shu, Son C. Nguyen, Ying He, Fadekemi Oba, Qiao Zhang, Christian Canlas, Gabor A. Somorjai*, A. Paul Alivisatos*, and F. Dean Toste*. J. Am. Chem. Soc. 2015, 137, 7083. Dual Visible Light Photoredox and Gold-catalyzed Arylative Ring Expansion. Xingzhong Shu, Miao Zhang, Ying He, Heinz, Frei*, and F. Dean Toste*. J. Am. Chem. Soc. 2014, 136, 5844. Transfer of Chirality in Rhodium-Catalyzed Intramolecular (5+2) Cycloaddition of 3-Acyloxy-1, 4-enyne (ACE) and Alkyne: Enantioselective Synthesis of Bicyclo[5.3.0]decatrienes. Xingzhong Shu, Casi M. Schienebeck, Wangze Song, Ilia A. Guzei, and Weiping Tang*. Angew. Chem. Int. Ed. 2013, 52, 13601. Rhodium-Catalyzed Intra- and Intermolecular 5+2 Cycloaddition of 3-Acyloxy-1, 4-enyne and Alkyne with Concomitant 1, 2-Acyloxy Migration, Xingzhong Shu, Xiaoxun Li, Dongxu Shu, Suyu Huang, Casi Mae Schienebeck, Xin Zhou, Patrick J. Robichaux, and Weiping Tang. J. Am. Chem. Soc. 2012, 134, 5211.