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过渡金属催化下的有机合成方法学研究

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Copper-Catalyzed One-Pot Trifluoromethylation/Aryl Migration/ Carbonyl Formation with Homopropargylic Alcohols. Pin Gao, Shen, Yong-Wen Shen, Ran Fang, Xin-Hua Hao, Zi-Hang Qiu, Fan Yang, Xiao-Biao Yan, Qiang Wang, Xiang-Jun Gong, Xue-Yuan Liu,* Yong-Min Liang,* Angew. Chem. Int. Ed. 2014, 53, 7629 –7633. Palladium-catalyzed C2-acylation of indoles with aryl and alkyl aldehydes. Xiao-Biao Yan, Yong-Wen Shen, Dao-Qian Chen, Pin Gao, Ying-Xiu Li, Xian-Rong Song, Xue-Yuan Liu,* Yong-Min Liang. Tetrahedron, 2014, 70, 7490-7495. Copper(II)-catalyzed direct thiolation of C-H bonds in aromatic amides with aryl and aliphatic thiols. Xiao-Biao Yan, Pin Gao, Hong-Bin Yang, Ying-Xiu Li, Xue-Yuan Liu*, Yong-Min Liang. Tetrahedron, 2014, 70, 8730-8736. Copper-Catalyzed Trifluoromethylation–Cyclization of Enynes: Highly Regioselective Construction of Trifluoromethylated Carbocycles and Heterocycles. Pin Gao, Xiao-Biao Yan; Tao Tao, Fan Yang, Ting He, Xian-Rong Song, Xue-Yuan Liu*, Yong-Min Liang* Chem. Eur. J. 2013, 19, 14420 – 14424. Palladium-/Copper-Catalyzed Regioselective Amination and Chloroamination of Indoles. Xue-Yuan Liu,* Pin Gao, Yong-Wen Shen, and Yong-Min Liang. Org. Lett. 2011, 13, 4196-4199. Copper-Catalyzed Chloroamination of Alkynes: Highly Regioand Stereoselective Synthesis of (E)-β-Chloro- Enesulfonamides. Xue-Yuan Liu,* Pin Gao, Yong-Wen Shen, and Yong-Min Liang. Adv. Synth. Catal. 2011, 353, 3157 – 3160. Copper- catalyzed direct thiolation of azoles with aliphatic thiols. An-Xi Zhou, Xue-Yuan Liu,* Ke Yang, Shu-Chun Zhao and Yong-Min Liang. Org. Biomol. Chem. 2011, 9, 5456-5462.

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