韩丙 - 兰州大学 - 功能有机分子化学国家重点实验室

个人简介

2008-至今兰州大学化学化工学院、功能有机分子化学国家重点实验室，讲师、副教授、教授 2006-2007 休斯顿大学 (导师: Jay K. Kochi)，博士后 2001-2006 兰州大学 (导师: 刘中立)，理学博士 1996-2000 西北师范大学，理学学士荣誉奖励 2014 国家自然科学基金委 “优秀青年科学基金” 2013 入选教育部“新世纪优秀人才支持计划

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Regioselective Fluoroalkylphosphorylation of Unactivated Alkenes by Radical-Mediated Alkoxyphosphine Rearrangement. Dongtai Xie, Honglei Chen, Dian Wei, Bangyi Wei, Zhenghu Li, Jianwu Zhang, Wei Yu, and Bing Han*, Angew. Chem. Int. Ed. 2022, 61, e202203398. Sequential Catalytic Annulations: Divergent Synthesis of Heterocycles through a Radical [1,4]-Oxygen Shift. Wen-Jun Han, Jian-Wu Zhang, Chao-Xian Yan, Jia-Wei Wang, Pan-Pan Zhou, and Bing Han*, Org. Lett. 2022, 24, 542. Photocatalytic Anti-Markovnikov Radical Hydro- and Aminooxygenation of Unactivated Alkenes Tuned by Ketoxime Carbonates. Sheng-Qiang Lai‡, Bang-Yi Wei‡, Jia-Wei Wang, Wei Yu, and Bing Han*. Angew. Chem. Int. Ed. 2021, 60, 21997– 22003. Radical 1,4/5-Amino Shift Enables Access to Fluoroalkyl-Containing Primary β(γ)-Aminoketones under Metal-Free Conditions, Dian Wei‡, Tuming Liu‡, Yiheng He, Bangyi Wei, Jiahao Pan, Jianwu Zhang, Ning Jiao, and Bing Han*. Angew. Chem. Int. Ed. 2021, 60, 26308–26313. Electrochemically Tuned Oxidative [4+2] Annulation and Dioxygenation of Olefins with Hydroxamic Acids. Bangyi Wei‡, Dongtai Xie‡, Shengqiang Lai, Yu Jiang, Hong Fu, Dian Wei, and Bing Han*. Angew. Chem. Int. Ed. 2021, 60, 3182-3188. Deconstructive Oxygenation of Unstrained Cycloalkanamines. Jianwu Zhang, Yuanrui Wang, Jiahao Pan, Yiheng He, Wei Yu, and Bing Han*. Angew. Chem. Int. Ed. 2020, 59, 3900-3904. Decarboxylative Borylation of mCPBA-Activated Aliphatic Acids.Wei Dian, Liu Tuming, Zhou Bo, Han Bing*. Org. Lett. 2020, 22, 234-238. 4-HO-TEMPO-Catalyzed Redox Annulation of Cyclopropanols with Oxime Acetates toward Pyridine Derivatives. Junlong Zhan, Mengwei Wu, Dian Wei, Bangyi Wei, Yu Jiang, Wei Yu, and Bing Han*. ACS Catal. 2019, 9, 4179-4188. Silver-Catalyzed Site-Selective Ring-Opening and C–C Bond Functionalization of Cyclic Amines: Access to Distal Amino-Alkyl Side-Chain-Containing Quinones. Ruihua Liu, Yiheng He, Wei Yu, Bo Zhou, and Bing Han*. Org. Lett. 2019, 21, 4590−4594. Theoretical study on the mechanism and chemoselectivity in gold(I)-catalyzed cycloisomerization of β,β-disubstituted ortho-(alkynyl)styrenes. Lin Zhou, Li Yang, Yanwen Zhang, Alexander M. Kirillov, Ran Fan*, and Bing Han*. Org. Chem. Front. 2019, 6, 2701-2712. Cu-Catalyzed Radical Cascade Annulations of Alkyne-Tethered N-Alkoxyamides with Air: Facile Access to Isoxazolidine/1,2-Oxazinane-Fused Isoquinolin-1(2H)‑ones. Fei Chen, Shengqiang Lai, Feifei Zhu, Qiang Meng, Yu Jiang, Wei Yu, and Bing Han*. ACS Catal. 2018, 8, 8925-8931. Cu-Catalyzed Aminoacyloxylation of Unactivated Alkenes of Unsaturated Hydrazones with Manifold Carboxylic Acids toward Ester-Functionalized Pyrazolines. Ruihua Liu, Ziqing Wang, Bangyi Wei, Jianwu Zhang, Bo Zhou, and Bing Han*. Org. Lett. 2018, 20, 4183-4186. Cu-Catalyzed Oxyalkynylation and Aminoalkynylation of Unactivated Alkenes: Synthesis of Alkynyl-Featured Isoxazolines and Cyclic Nitrones. Wenjun Han, Yuanrui Wang, Jianwu Zhang, Fei Chen, Bo Zhou, and Bing Han*. Org. Lett. 2018, 20, 2960-2963. Synthesis of Halomethyl Isoxazoles/Cyclic Nitrones via Cascade Sequence: 1,2-Halogen Radical Shift as a Key Link, Honglei Chen, Dian Wei, Jianwu Zhang, Chenglin Li, Wei Yu, and Bing Han*. Org. Lett. 2018, 20, 2906-2910. Dioxygen Activation via Cu-Catalyzed Cascade Radical Reaction: An Approach to Isoxazoline/Cyclic Nitrone-Featured α-Ketols. Peng X.-X.†, Wei D.†, Han W.-J.†, Chen F., Yu W., Han B.* ACS Catal. 2017, 7, 7830-7834. Copper-Catalyzed Cascade Cyclization of 1,7-Enynes toward Trifluoromethyl- Substituted 1’H‑Spiro[azirine-2,4-quinolin]-2’(3H)-ones. Qiang Meng, Fei Chen, Wei Yu*, and Bing Han*. Org. Lett. 2017, 19, 5186-5186. Iminoxyl Radical-Promoted Oxycyanation and Aminocyanation of Unactivated Alkenes: Synthesis of Cyano-Featured Isoxazolines and Cyclic Nitrones. Fei Chen, Feifei Zhu, Man Zhang, Ruihua Liu, Wei Yu, and Bing Han*. Org. Lett. 2017, 19, 3255-3258. Cu-catalyzed [3+3] annulation for the synthesis of pyrimidines via β-C(sp3)−H functionalization of saturated ketones. Junlong Zhan, Mengwei Wu, Fei Chen, and Bing Han*. J. Org. Chem. 2016, 81,11994-12000. Copper-Catalyzed Oxidative Oxyamination/Diamination of Internal Alkenes of Unsaturated Oximes with Simple Amines. Ruihua Liu, Dian Wei, Bing Han*, and Wei Yu*. ACS Catal. 2016, 6, 6525-6530. Tert-Butyl Hydroperoxide (TBHP)-Initiated Vicinal Sulfonamination of Alkynes: A Radical Annulation toward 3-Sulfonylindoles. Fei Chen, Qiang Meng, ShangQing Han, and Bing Han*. Org. Lett. 2016, 18, 3330-3333. TEMPO-Mediated Aza-Diels–Alder Reaction: Synthesis of Tetrahydropyridazines Using Ketohydrazones and Olefins. XiuLong Yang, XieXue Peng, Fei Chen, and Bing Han*. Org. Lett. 2016, 18, 2070-2073. Synthesis of Isoxazoline/Cyclic Nitrone-Featured Methylenes Using Unsaturated Ketoximes: A Dual Role of TEMPO. Fei Chen, XiuLong Yang, ZhiWei Wu, and Bing Han*. J. Org. Chem. 2016, 81, 3042-3050. Hydrazonyl Radical-Participated Tandem Reaction: A Strategy for the Synthesis of Pyrazoline-Functionalized Oxindoles. XiaoYong Duan, XiuLong Yang, PanPan Jia, Man Zhang, and Bing Han*. Org. Lett. 2015, 17, 6022-6025. Transition from π Radicals to σ Radicals: Substituent-Tuned Cyclization of Hydrazonyl Radicals. Xiaoyong Duan, Nengneng Zhou, Ran Fang, Xiulong Yang, Wei Yu, and Bing Han*. Angew. Chem. Int. Ed. 2014, 53, 3158-3162. Iminoxyl Radical-Promoted Dichotomous Cyclizations: Efficient Oxyoximation and Aminooximation of Alkenes. Xiexue Peng, Yunjing Deng, Xiulong Yang, Lin Zhang, Wei Yu, and Bing Han*. Org. Lett. 2014, 16, 4650-4653. Synthesis of Isoxazoline-Functionalized Phenanthridines via Iminoxyl Radical- Participated Cascade Sequence. Xiulong Yang, Fei Chen, Nengneng Zhou, Wei Yu, and Bing Han*. Org. Lett. 2014, 16, 6476-6479. Hydrazone Radical Promoted Vicinal Difunctionalization of Alkenes and Trifunctionalization of Allyls: Synthesis of Pyrazolines and Tetrahydropyridazines. Xiaoyong Duan, Xiulong Yang, Ran Fang, Xiexue Peng, Wei Yu, and Bing Han*. J. Org. Chem. 2013, 78, 10692-10704. Oxime Radical Promoted Dioxygenation, Oxyamination and Diamination of Alkenes: Synthesis of Isoxazolines and Cyclic Nitrones. Bing Han, Xiulong Yang, Ran Fang, Wei Yu, Chao Wang, Xiaoyong Duan, and Shuai Liu. Angew. Chem. Int. Ed. 2012, 51, 8816-8820.

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