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金属有机发光化合物的合成、结构与光物理性能 本课题立足于合成具有较强的室温磷光性能的金属有机化合物,寻找有效的室温磷光材料以及有效的敏化镧系稀土发光的金属有机发色团;研究物质结构与发光机理之间的关系;定量研究天线发色团和镧系稀土离子能级的匹配情况;通过激发过渡金属天线发色团的低能量吸收,实现镧系稀土的高效敏化发光。本课题将为寻找新型、有效、低能量的过渡金属天线发色团、增强镧系稀土发光提供了一种有效途径,同时又可能为开发高效的金属有机发光二极管和镧系稀土发光器件奠定一定的理论基础。

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Xiu-Ling Li, Ming Tan, Ke-Juan Zhang, Bo Yang, Jie Chen, Yu-Bo Ai, Dual Luminescent Tetranuclear Organogold(I) Macrocycles of 5,5′-Diethynyl-2,2′-bipyridine and Their Efficient Sensitization of Yb(III) Luminescence, Inorg. Chem., 2012, 51(1), 109-118. Xiu-Ling Li, Lin-Xi Shi, Li-Yi Zhang, Hui-Min Wen, En Ma, and Zhong-Ning Chen, Syntheses, Structures and Sensitized Lanthanide Luminescence by Pt®Ln (Ln = Eu, Nd, Yb) Energy Transfer for Heteronuclear PtLn2 and Pt2Ln4 Complexes with a Terpyridyl-functionalized Alkynyl Ligand, Inorg. Chem., 2007, 46(25), 10892-10900. Xiu-Ling Li, Feng-Rong Dai, Li-Yi Zhang, Yue-Mei Zhu, Qi Peng, and Zhong-Ning Chen, Sensitization of Lanthanide Luminescence in Heterotrinuclear PtLn2 (Ln = Eu, Nd, Yb) Complexes with Terpyridyl-functionalized Alkynyl by Energy Transfer from a Platinum(II) Alkynyl Chromophore, Organometallics, 2007, 26(18), 4483-4490. Xiu-Ling Li, Ke-Juan Zhang, Juan-Juan Li, Xin-Xin Cheng, Zhong-Ning Chen, Dual Luminescent Dinuclear Gold(I) Complexes of Terpyridyl-Functionalized Alkyne Ligands and Their Efficient Sensitization of EuIII and YbIII Luminescence, Eur. J. Inorg. Chem., 2010, (22), 3449-3457. Xiu-Ling Li, Yu-Bo Ai, Bo Yang, Jie Chen, Ming Tan, Xue-Lian Xin and Yan-Hui Shi, Syntheses, Structures and Photophysical Properties of a Series of Luminescent Copper(I) Mixed-Ligand Complexes, Polyhedron, 2012, 35(1), 47-54.

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