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研究领域

主要从事加、脱氢反应及催化剂的设计与制备等方面研究工作。根据具体反应的机理,有目的的设计、制备和优化适合特定反应的优良催化剂。通过改进制备方法和选用最新的材料为载体来提高催化剂的性能。重点研究催化剂的组成,结构,酸碱性质等物理化学性质对催化反应的影响。特别是活性中心与催化载体之间的相互作用,载体的酸碱性质对反应选择性的影响,活性中心金属形态对反应活性和选择性的影响等问题。经过长期的研究和探索我们对铜、镍基催化剂在有关醇脱氢和醛、酮、脂肪醇以及芳香族类加氢有了较为深入的认识。

近期论文

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吉定豪,朱万春,王振旅,王国甲,石油化工(Petrochemical Technology),36(1),59 – 62(2007)。对二甲苯液相氨氧化制对甲基苯甲腈。 Dinghao Ji, Wanchun Zhu, Zhenlu Wang*, Guojia Wang*, Dehydrogenation of cyclohexanol on Cu-ZnO/SiO2 catalysts: the role of copper species. Catalysis Communication. 8(12), 1891-1895 (2007). 吉定豪,刘钢,贾明君,张文祥,王国甲,吴通好,王振旅*,高等学校化学学报,28(8)1543-1546(2007)。溶胶-凝胶和浸渍法制备的铜催化剂在仲丁醇脱氢反应中的研究。 Xiangzhou Liao, Zhou Zhou, Zhenlu Wang, Xiujing Zou, Gang Liu, Mingjun Jia, Wenxiang Zhang, Preformed precursor of microporous aluminophosphate coating on mesoporous SBA-15: Synthesis, characterization, and catalytic property for selective O-methylation of catechol, Journal of Colloid and Interface Science,308(2007)176-181. 吉定豪,朱万春,吴通好,王振旅*,王国甲, 石油化工(Petrochemical Technology),36(6),570 – 574(2007)。Cu/ZSM-5催化剂的表征及其环己醇脱氢性能。 Anna Kubacka, Zhenlu Wang, Bogdan Sulikowski, Vicente Cortes Corberan. Hydroxylation/oxidation of benzene over Cu-ZSM-5 systems: Optimization of the one-step route to phenol. J. Catalysis. 250(2007) 184-189. 朱万春,贾明君,王振旅,吴通好,王国甲,高等学校化学学报,28(2),334-337(2007)。水热法合成的MoVTeNbOx多组份氧化物催化剂上异丁烷的选择氧化。 Jingqi Guan, Shujie Wu, Mingjun Jia, Jiahui Huang, Shubo Jing, Haiyan Xu, Zhenlv Wang, Wanchun Zhu, Haijun Xing, Hongsu Wang, Qiubin Kan. Catalysis Communications 8, 1219-1223 (2007). Effect of antimony doping on the catalytic behavior of Mo–V–Te–P mixed oxide catalysts in oxidation of isobutane Guoming Zhao, Xiaomei Zhu, Zhenlu Wang, Gang Liu, Yan Liu, Mingjun Jia and Wenxiang Zhang. React.Kinet.Catal.Lett. 91(1), 77-83 (2007). Transesterification Dimethyl Oxalate with Phenol over Ti-Containing Phosphate Catalysts Wanchun Zhu, Lixia Wang, Shiyan Liu and Zhenlu Wang*. React. Kinet. Catal. Lett., 93 (1), 93-99(2008). CHARACTERIZATION AND CATALYTIC BEHAVIOR OF SILICA-SUPPORTED COPPER CATALYSTS PREPARED BY IMPREGNATION AND ION-EXCHANGE METHODS D.H. Ji1, X.J. Zou1, D.F. Zheng2, L.X. Wang1, S.Y. Liu1, W.C. Zhu1, G.J. Wang1, Z.L. Wang1*. Polish J. Chem. 82,1097-1104 (2008). Surface structure and catalytic properties of Cu/SiO2 catalysts prepared by different methods. 井淑波,管景奇,王振旅,朱万春,王国甲,吉林大学学报(理学版)46(2)336-340 (2008)Dawson 结构磷钼钒酸在环己烷催化氧化中的应用 张祚望, 张钰, 王振旅, 邢海军, 贾明君, 吴通好, 张文祥,催化学报,29(10)1015-1020 (2008). H-MCM-22和H-MCM-36分子筛上苯与异丙醇烷基化反应的研究. J. Zheng, W.C. Zhu, C.X. Ma, M.J. Jia, Z.L. Wang*,Y.H. Hou and W.X. Zhang﹡, Polish J. Chem., 83, 1379–1387 (2009). Hydrogenolysis of Glycerol to 1,2-Propanediol over Cu/SiO2 Catalysts Prepared by Ion-Exchange Method. L.X. Wang1, D.F. Zheng2, C.X. Ma1, W.C. Zhu1, S.Y. Liu1, J. Cui1, Z.L. Wang1* W.X. Zhang1*, Polish J. Chem.,83,1993-2000,(2009). Direct Transformation of Ethanol to Ethyl acetate over MoSx/C Catalyst. Jing Zheng, Wanchun Zhu, Chunxiang Ma, Yazhuo Hou, Wenxiang Zhang, Zhenlu Wang*,React. Kinet. Mech. Lett., 99,455-462 (2010). HYDROGENOLYSIS OF GLYCEROL TO 1, 2-PROPANEDIOL ON THE HIGH DISPERSED SBA-15 SUPPORTED COPPER CATALYST PREPARED BY ION-EXCHANGED METHOD. 曲渊立,刘士艳,王振旅*,徐家宁*,高等学校化学学报,31(2),325-329(2010)钼基复合氧化物催化剂在异丁烯选择氧化制甲基丙烯醛反应中的研究. Lixia Wang, Jing Cui, Shiwen Li, Wanchun Zhu, Xue Yu, Zhenlu Wang*and Wenxiang Zhang*,Reaction Kinetics, Mechanisms and Catalysis: Volume 101, Issue 2 (2010), Page 365. Direct Transformation of Ethanol to Ethyl acetate on Cu/ZrO2 Catalyst. Zongwen Guoa, b, Weitao Huoa, Mingjun Jiaa, Kaige Lia, Zhenlu Wang a*, Wenxiang Zhanga*.Journal of Molecular Catalysis A, 326(2010)82-87. Hydrodealkylation of 1,2,4-trimethylbenzene over reduced Ni-Al mixed oxide catalysts prepared by co-precipitation method. Yanhong Zu, Gang Liu,* Zhenlv Wang, Jinghui Shi, Min Zhang, Wenxiang Zhang, and Mingjun Jia* Energy fuels,24,3810-3816,2010.CaO Supportedon Porous Carbon as Highly Efficient Heterogeneous Catalysts for Transesterification of Triacetin with Methanol.

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