Bertrand, Guy - University of California, San Diego - Department of Chemistry and Biochemistry

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University of California, San Diego Department of Chemistry and Biochemistry
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个人简介

Position and Employment 2012 - present Distinguished Professor (University of California, San Diego) Director of the UCSD/CNRS Joint Research Chemistry Laboratory (UMI 3555) 2001 - 2012 Distinguished Professor (University of California, Riverside) Director of the UCR/CNRS Joint Research Chemistry Laboratory (UMI 2957) 1999 - 2005 Director of the Laboratoire Heterochimie Fondamentale et Appliquee (Université Paul Sabatier, Toulouse, France) 1988 - 1998 Directeur de Recherche CNRS (LCC-CNRS, Toulouse, France) 1981 - 1988 Chargé de Recherche CNRS (Université Paul Sabatier, Toulouse, France) 1980 - 1981 Research Associate Sanofi-Recherche Company (Toulouse, France) 1975 - 1980 Chargé de Recherche CNRS (Université Paul Sabatier, Toulouse, France) Education 1979 PhD (Université Paul Sabatier, Toulouse, France) 1975 Ingénieur (ENSC Montpellier, France) 1972 D.U.E.S. PC (Université de Limoges, France) Honors and Awards 2024 Luigi M Venanzi Lectureship (ETH Zurich) 2023 Elected at the German National Academy of Sciences Leopoldina 2022 Silliman Lecture at Yale Fellow of the Hagler Institute for Advanced Study at Texas A&M University 2021 Neil Bartlett lectureship at UC Berkeley 2020 Grand Prize from the Fondation de la Maison de la Chimie, shared with Prof. Krzysztof Matyjaszewski 2019-2020 Strem lecturership in chemical catalysis at Boston College 2018 Vilsmeier Lecturship, University of Regensburg (Germany)Named “Distinguished Visiting Professor” at Tsinghua University (China)Named “Honorable Professor” at Wuhan University of Technology (China) 2017 Luigi Sacconi Medal of the Italian Chemical Society Luojia Lecturship, Wuhan University (China)Highly Cited Researcher (Web of Science) 2016 Sir Geoffrey Wilkinson Award of the RSC Debye Lectureship (Cornell University)Charles F. Hutchison Memorial Lectureship (University of Rochester) 2015 Senior Humboldt Research Award- Reinvitation Inaugural Anton B. Burg Memorial lecturership (USC)Gordon Stone Lectureship (Baylor University)The Swiss Chemical Society Lectureship 2014 ACS Award in Inorganic Chemistry Andrews Lectureship (Mississipi State University) 2013 Chevalier de la Legion d’Honneur Gordon Stone Lectureship (School of Chemistry at the University of Bristol, UK) 2012-2013 McRae Lectureship (Queen's University, Canada)Frontiers in Chemical Research Lectureship (Texas A&M University) 2012 Raymond Siedle Distinguished Lecture (Indiana University) 2011 PKU-Eli Lilly Lecture (Peking University, China) 2010-2011 Eli Lilly Lectureship (University of Illinois, Urbana-Champaign)Pattison Lectureship (University of Western Ontario) 2010 Grand Prix Le Bel of the French Chemical Society Bruker Lectureship (University of Toronto)Senior Humboldt Research Award- Reinvitation Anthony J. Arduengo III Lectureship of the University of Alabama 2009-2010 Sir Ronald Nyholm Lectureship and Medal of the RSC Novartis Lectureship at the Scripps Research Institute 2007 East Cost Lecturer (Scotland) 2006 Fellow of the American Association for Advancement of Science 2003 Member of the European Academy of Sciences Taiwan National Science Foundation Distinguished Lectureship 2002 Member of the Academia Europea 2000 Member of the Académie des Technologies 1999 Japanese Society for Promotion of Science Award 1998 Médaille d'Argent du CNRS Kharasch Lecturer (University of Chicago) Visiting Professor at ETH Zürich (June-September) 1996 Membre Correspondant de l’Institut (French Academy of Sciences) 1994 French-German Humboldt Award Membre Correspondant de l’Institut (French Academy of Sciences) 1993 International Council on Main Group Chemistry Award 1988-1989 Humboldt junior award at T. U. München, Germany 1983 Visiting Associate Professor at Utah University, Salt Lake City, USA

研究领域

Ambiphilic Carbene Mimicks Transition-Metal Catalysts in the Activation of Carbon Monoxide The activation and catalytic transformation of carbon monoxide by transition metals is well known. However, within the realm of organocatalysis the former behavior is rare while the latter is entirely unknown - until now. As published in JACS and highlighted in Synfacts, we have succesfully demonstrated a metal-free, carbene-catalyzed carbonylation with CO. Insights from this discovery will pave the way for further developments in metal-free catalysis. Eliminating nonradiativedecay in Cu(I) emitters: > 99%quantum efficiency and microsecond lifetime OLED 2.0: Organic Light Emitting Diodes (OLED) are traditionally made using luminescent complexes of heavy metals such as iridium, platinum, and ruthenium. Achieving comparable performance from copper, an earth-abundant metal, requires overcoming weak spin-orbit coupling, as well as limiting high reorganization energies. In a recent report in Science, however, Jesse Peltier (left) from the Bertrand group at UCSD and Rasha Hamze (right) from the Thompson group at USC, thoroughly explored two-coordinate copper complexes that sandwich the metal between an amide ligand and a cyclic (alkyl)(amino)carbene ligand (CAAC) and measured a nearly perfect luminescence efficiency. They used this property to produce a prototype blue organic light-emitting diode.

近期论文

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A crystalline doubly oxidized carbene Ying Kai Loh, Mohand Melaimi, Milan Gembicky, Domink Munz, and Guy Bertrand Nature 2023, 1.DOI: 10.1038/s41586-023-06539-x Enhancing Substrate–Metal Catalyst Affinity via Hydrogen Bonding: Pd(II)-Catalyzed β-C(sp3)–H Bromination of Free Carboxylic Acids Liang Hu, Guangrong Meng, Xiangyang Chen, Joseph S. Yoon, Jing-Ran Shan, Nikita Chekshin, Daniel A. Strassfeld, Tao Sheng, Zhe Zhuang, Rodolphe Jazzar, Guy Bertrand, K. N. Houk, and Jin-Quan Yu J. Am. Chem. Soc. 2023, 145, 16297-16304.DOI: 10.1021/jacs.3c04223 Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino) Carbene Derived Propellers Jan Lorkowski, Dylan Bouetard, Patrick Yorkgitis, Thierry Roisnel, Nicolas Vanthuyne, Dominik Munz, Ludovic Favereau, Guy Bertrand, Marc Mauduit, and Rodolphe Jazzar Angew. Chem. Int. Ed. 2023, e202305404. DOI: 10.1002/anie.202305404 Highly Robust and Efficient Blechert-Type Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Olefin Metathesis Antonio Del Vecchio, Jakub Talcik, Sophie Colombel-Rouen, Jan Lorkowski, Melinda R. Serrato, Thierry Roisnel, Nicolas Vanthuyne, Guy Bertrand*, Rodolphe Jazzar*, and Marc Mauduit ACS Catal. 2023, 13, 6195-6202. DOI: 10.1021/acscatal.3c01208 Mesoionic Carbene-Catalyzed Formyl Alkylation of Aldehydes Chang Liu, Zengyu Zhang, Liang-Liang Zhao, Guy Bertrand, Xiaoyu Yan Angew. Chem. Int. Ed. 2023, e202303478. DOI: 10.1002/anie.202303478 and 10.1002/ange.202303478 Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino)Carbenes (CAACs) Maria Haimerl, Christoph Schwarzmaier, Christoph Riesinger, Alexey Timoshkin, Mohand Melaimi, Guy Bertrand, Manfred Scheer Chem-Eur. J. 2023, e202300280. DOI: 10.1002/chem.202300280 A Straightforward Access to Cyclic (Alkyl)(amino)carbene Copper (I) Complexes Dr. Jan Lorkowski [+], Melinda R. Serrato [+], Dr. Milan Gembicki, Dr. Marc Mauduit, Prof. Dr. Guy Bertrand, Dr. Rodolphe Jazzar Eur. J. Inorg. Chem. 2023, e202300074.[+] These authors contributed equally to this work DOI: 10.1002/ejic.202300074 Ambivalent Role of Rotamers in Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Enantioselective Ring-Opening Cross-Metathesis Jennifer Morvan, François Vermersch, Ziyun Zhang, Thomas Vives, Thierry Roisnel, Christophe Crévisy, Laura Falivene, Luigi Cavallo, Nicolas Vanthuyne, Guy Bertrand, Rodolphe Jazzar, and Marc Mauduit Organometallics 2023, 42, 495-504. DOI: 10.1021/acs.organomet.3c00054 How To Enhance the Efficiency of Breslow Intermediates for SET Catalysis Florian F. Mulks, Mohand Melaimi, Xiaoyu Yan, Mu-Hyun Baik, and Guy Bertrand J. Org. Chem. 2023, 88, 2535-2542. DOI: 10.1021/acs.joc.2c02978 Cyclic(alkyl)(amino)carbene ruthenium complexes for Z-stereoselective (asymmetric) olefin metathesis Jennifer Morvan, François Vermersch, Jan Lorkowski, Jakub Talcik, Thomas Vives, Thierry Roisnel, Christophe Crévisy, Nicolas Vanthuyne, Guy Bertrand, Rodolphe Jazzar, Marc Mauduit Catal. Sci. Technol. 2023, 13, 381-288. DOI: 10.1039/D2CY01795D An Air-Stable “Masked” Bis(imino)carbene: A Carbon-Based Dual Ambiphile Ying Kai Loh, Mohand Melaimi, Dominik Munz, Guy Bertrand J. Am. Chem. Soc. 2023, 145, 2064-2069. DOI: 10.1021/jacs.2c12847 An air-stable radical with a redox-chameleonic amide Jesse L. Peltier, Melinda R. Serrato, Valentin Thery, Jacques Pecaut, Eder Tomas-Mendivil, Guy Bertrand, Rodolphe Jazzar, David Martin Chem. Comm. 2023, 59, 595. DOI: 10.1039/d2cc05404c The triplet state of deprotonated mesoionic carbene Breslow intermediates is thermally accessible: Distal difunctionalization of aldehydes Zengyu Zhang, Shiqing Huang, Chen-Yuan Li, Liang-Liang Zhao, Wei Liu, Mohand Melaimi, Guy Bertrand, and Xiaoyu Yan Chem Catalysis 2022, 2, 3517-3527. DOI: 10.1016/j.checat.2022.09.047 Six-coordinate ruthenium water oxidation catalysts bearing equatorial polypyridinedicarboxylato and axial phosphine ligands Sima Yazdani, Colton J. Breyer, Pratibha Kumari, Arnold L.Rheingold, Rodolphe Jazzar, Guy Bertrand, Douglas B. Grotjahn Polyhedron 2022, 228, 116163. DOI: 10.1016/j.poly.2022.116163 A Career in Catalysis: Jean-Marie M. Basset Didier Astruc, Guy Bertrand, Mohamed Eddaoudi, Yu Han, Kuo-Wei Huang, Johannes Lercher, Catherine Santini, Kazuhiro Takanabe, Mostafa Taoufik, Luigi Cavallo ACS Catalysis 2022, 12, 4961. DOI: 10.1021/acscatal.2c00588 Cyclic (amino)(barrelene)carbenes: an original family of CAACs through a novel synthetic pathway Melinda R. Serrato, Mohand Melaimi, Guy Bertrand Chem Comm 2022, 58, 7519-7521. DOI: 10.1039/D2CC02565E (CAAC)Copper Catalysis Enables Regioselective Three-Component Carboboration of Terminal Alkynes Yang Gao, Nana Kim, Skyler D. Mendoza, Sima Yazdani, Andre Faria Vieira, Mingyu Liu, Aaron Kendrick IV, Douglas B. Grotjahn, Guy Bertrand, Rodolphe Jazzar, Keary M. Engle ACS Catal. 2022, 12, 7243–7247. DOI: 10.1021/acscatal.2c00614 Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties François Vermersch, Luana Oliveira, Joseph Hunter, Michele Soleilhavoup, Rodolphe Jazzar, Guy Bertrand J. Org. Chem. 2022, 87, 3511-3518. DOI: 10.1021/acs.joc.1c03075 Cyclic (Alkyl)(amino)carbenes (CAACs) in Ruthenium Olefin Metathesis Jennifer Morvan, Marc Mauduit, Guy Bertrand, and Rodolphe Jazzar ACS Catal. 2021, 11, 1714-1748. DOI: 10.1021/acscatal.0c05508. Stable Singlet Carbenes as Organic Superbases François Vermersch, Sima Yazdani, Glen P. Junor, Douglas B. Grotjahn, Rodolphe Jazzar, Guy Bertrand Angew. Chem. 2021, 60, 27253–27257. DOI: 10.1002/anie.202111588. Cyclic(Alkyl)(Amino)Carbene Ligands Enable Cu-Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes Yang Gao, Sima Yazdani, Aaron Kendrick, Glen P. Junor, Taeho Kang, Douglas B. Grotjahn, Guy Bertrand, Rodolphe Jazzar, Keary Mark Engle Angew. Chem. 2021, 60, 19871–19878. DOI: 10.1002/anie.202106107. Cyclic (Alkyl)(Amino)Carbene (CAAC) Gold(I) Complexes as Chemotherapeutic Agents Maria T. Proetto, Kelsey Alexander, Mohand Melaimi, Guy Bertrand, Nathan C. Gianneschi Chem. Eur. J. 2021, 27, 3772-3778. DOI: 10.1002/chem.202004317. Mesoionic carbene-Breslow intermediates as super electron donors: Application to the metal-free arylacylation of alkenes Wei Liu, Adam Vianna, Zengyu Zhang, Shiqing Huang, Linwei Huang, Mohand Melaimi, Guy Bertrand, Xiaoyu Yan Chem. Catalysis 2021, 1, 196-206. DOI: 10.1016/j.checat.2021.03.004. Cyclic (Alkyl)(amino)carbenes (CAACs) in Ruthenium Olefin Metathesis Jennifer Morvan, Marc Mauduit, Guy Bertrand, and Rodolphe Jazzar ACS Catal. 2021, 11, 1714-1748. DOI: 10.1021/acscatal.0c05508. Optically Pure C1– Symmetric Cyclic(Alkyl)(Amino)Carbenes for Asymmetric Olefin Metathesis Jennifer Morvan, François Vermersch, Ziyun Zhang, Laura Falivene, Thomas Vives, Vincent Dorcet, Thierry Roisnel, Christophe Crévisy, Luigi Cavallo, Nicolas Vanthuyne, Guy Bertrand, Rodolphe Jazzar, Marc Mauduit J. Am. Chem. Soc. 2020, 142, 19895-19901. DOI: 10.1021/jacs.0c10705. Realizing Metal-Free Carbene-Catalyzed Carbonylation Reactions with CO Jesse L. Peltier, Eder Tomás-Mendivil, Daniel R. Tolentino, Max M. Hansmann, Rodolphe Jazzar, Guy Bertrand J. Am. Chem. Soc. 2020, 142. 18336-18340. DOI: 10.1021/jacs.0c09938. Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange Jesse L. Peltier, Michele Soleilhavoup, David Martin, Rodolphe Jazzar, Guy Bertrand J. Am. Chem. Soc. 2020, 142, 16479-16485. DOI: 10.1021/jacs.0c07990. The influence of C(sp3)H‐Selenium Interactions on the 77 Se NMR Quantification of the π‐Accepting Properties of Carbenes Glen P. Junor#, Jan Lorkowski#, Cory M. Weinstein, Rodolphe Jazzar, Cezary Pietraszuk, Guy Bertrand Angew. Chem. Int. Ed. 2020, 59, 22028-22033. DOI: 10.1002/anie.202010744. Angew. Chem. 2020, 132, 22212-22217. DOI: 10.1002/ange.202010744 Stable Carbenes, Nitrenes, Phosphinidenes, and Borylenes: Past and Future Michele Soleilhavoup, Guy Bertrand Chem 2020, 6, 1275-1282. DOI: 10.1016/j.chempr.2020.04.015 Influence of Carbene and Phosphine Ligands on the Catalytic Activity of Gold Complexes in the Hydroamination and Hydrohydrazination of Alkynes Sima yazdani, Glen P. Junor, Jesse Lawrence Peltier, MilanGembicky, Rodolphe Jazzar, Douglas B. Grotjahn, Guy Bertrand ACS Catalysis 2020, 10, 5190-5201. DOI: 10.1021/acscatal.0c01352 Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications Rodolphe Jazzar, Michele Soleilhavoup, Guy Bertrand Chem. Rev. 2020, 120, 4141-4168. DOI: 10.1021/acs.chemrev.0c00043 Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes Alex J. Mantanona, Daniel R. Tolentino, Kristine S. Cay, Milan Gembicky, Rodolphe Jazzar, Guy Bertrand, Jeffrey D. Rinehart Dalton Trans. 2020, 49, 2426-2430. DOI: 10.1039/c9dt04624k Stable abnormal N-heterocyclic carbenes and their applications Samaresh Chandra Sau, Pradip Kumar Hota,Swadhin K. Mandal, Michele Soleilhavoup, Guy Bertrand Chem. Soc. Rev. 2020, 49, 1233-1252. DOI: 10.1039/C9CS00866G

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