个人简介
Education
2001-2002, Postdoctoral scholar, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena (Advisor: Prof. David W.C. MacMillan).
1997-2000, Ph.D., Department of Chemistry, University of Ottawa, Canada (Advisor: Prof. Howard Alper).
1995-1996, Ph.D., Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences (Advisor: Prof. Xi-Yan Lu).
1987-1990, M.Sc., Institute of Pesticide Chemistry, Central China Normal University(Advisor: Prof. Wen-Fang Huang).
1980-1984, B.S., Chemistry Department, Central China Normal University(Advisor: Prof. Kai-Qing Tang).
Career
2014.6 until now, Dean of College of Chemisty, Central China Normal University, Distinguished Professor of Liberal Arts Scholars.
2003.9-2014.6, Professor and doctoral supervisor of Central China Normal University, Guizi Scholar Distinguished Professor.
2002.2-2003.8, Chief Scientist, Materia, Inc., Pasadena, CA, USA.
2001.1-2002.1, Postdoctoral Fellow, Department of Chemistry, California Institute of Technology.
1997.9-2000.12, Teaching/Research Assistant, Department of Chemistry, University of Ottawa, Canada.
1996.3-1997.8, Visiting Scholar, Department of Chemistry, University of Ottawa, Canada.
1994.10-1996.3, Associate Professor, Institute of Pesticide Chemistry, Central China Normal University, China.
1990.4-1994.9, Lecturer, Institute of Pesticide Chemistry, Central China Normal University, China.
1984.7-1990.3, Teaching Assistant, Institute of Pesticide Chemistry, Central China Normal University, China.
近期论文
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Formation of Chiral All-Carbon Quaternary Stereocenters by Photoinduced Cobalt-Catalyzed Enantioselective Radical Coupling Yue Jia#, Kai Zhang#, Liang-Qiu Lu, Ying Cheng*, and Wen-Jing Xiao* 10.1021/acscatal.4c04249
Photoinduced Copper-Catalyzed Three-Component Radical Carboamination of Styrene Derivatives Xiao-Die Huan, Juan Zhang, Wen-Jing Xiao, and Jia-Rong Chen* 10.1002/cctc.202401234
Access to N-α-quaternary chiral morpholines via Cu-catalyzed asymmetric propargylic amination/desymmetrization strategy Peng Chen#, Mao-Mao Zhang#, Li Rao，Yuan-Heng Li, Yue Jia, Ying Tan, Wen-Jing Xiao, Liang-Qiu Lu* 10.1016/j.scib.2024.08.005
Hyperconjugation-Driven Isodesmic Reaction of Indoles and Anilines: Reaction Discovery, Mechanism Study, and Antitumor Application Yu-Qing Xiao#, Kai-Xin Fang#, Zhihan Zhang#, Chen Zhang, Yu-Jie Li, Bao-Cheng Wang, BinJun Zhang, Yu-Qing Jiang, Miao Zhang, Ying Tan,* Wen-Jing Xiao, and Liang-Qiu Lu* 10.1002/anie.202408426
Asymmetric Radical Allylation of β-Keto Esters with Vinyl Cyclopropanes by Dual Photoredox/Nickel Catalysis Wen-Yuan Qu, Xue-Song Zhou, Wen-Jing Xiao*, Jia-Rong Chen* 10.1007/s11426-024-2249-x
A General Copper-Box System for the Asymmetric Arylative Functionalization of Benzylic, Propargylic or Allenylic Radicals Peng-Zi Wang, Zhihan Zhang, Min Jiang, Jia-Rong Chen, Wen-Jing Xiao*10.1002/anie.202411469
Recent advances in C(sp3)–N bond formation via metallaphoto-redox catalysis Juan Zhang,* Xiao-Die Huan, Xin Wang, Guo-Qing Li, Wen-Jing Xiao and Jia-Rong Chen*10.1039/D4CC01969E
Desymmetrization−Addition Reaction of Cyclopropenes to Imines via Synergistic Photoredox and Cobalt Catalysis Xiang-Kui He,⊥ Liang-Qiu Lu,⊥ Bao-Ru Yuan, Jia-Long Luo, Ying Cheng, and Wen-Jing Xiao*10.1021/jacs.4c07096
Photoinduced Copper-Catalyzed Asymmetric Three-Component Radical 1,2-Azidooxygenation of 1,3-Dienes Guo-Qing Li, Zi-Qing Li, Min Jiang, Yu Qian, Zhihan Zhang, Wen-Jing Xiao, and Jia-Rong Chen*10.1002/anie.202405560
Synthesis of S(IV)-Stereogenic Chiral Thio-Oxazolidinones via Palladium-Catalyzed Asymmetric [3+2] Annulations Bao-Cheng Wang+, Fang Hu+, Jiahui Bai+, Fen-Ya Xiong, Peng Chen, Jianye Li, Ying Tan, Yin-Long Guo,* Wen-Jing Xiao, and Liang-Qiu Lu*10.1002/anie.202319728
Visible-Light-Driven Four-Component Radical Relay Aminocarbonylation of Unactivated Alkenes Bin Lu,‡ Feng-Shuo Bao,‡ Zi-Wei He, Wen-Jing Xiao and Jia-Rong Chen*10.1002/cjoc.202300733
Asymmetric Cascade Cyclization of Enynamides with Photogenerated Ketenes via Relay Gold and N-Oxide Catalysis Dan Liu,# Zhen-Cao Shu,# Zhihan Zhang,# Ze-Tian Wang, Liang Wang, Ming-Sheng Xie,* Hai-Ming Guo, Liang-Qiu Lu,* and Wen-Jing Xiao*10.1021/acscatal.3c05731
Controlled generation of ortho-quinone methides and (4+3) cyclization with 2indolylalcohols by dual photoredox/Brønsted acid relay catalysis Dong Liang, Pan-Pan Gao, Zhihan Zhang, Wen-Jing Xiao, Jia-Rong Chen* 10.1016/j.gresc.2024.01.002
Enantioselective Cyanofunctionalization of Aromatic Alkenes via Radical Anions Bin Zhang, Tian-Tian Li, Zhi-Cheng Mao, Min Jiang, Zhihan Zhang, Ke Zhao, Wen-Yuan Qu, Wen-Jing Xiao*, and Jia-Rong Chen* 10.1021/jacs.3c10439
Visible Light Induced Copper-Catalyzed Enantioselective Deaminative Arylation of Amino Acid Derivatives Assisted by Phenol Yue Jia#， Zhihan Zhang#， Guo-Ming Yu, Xuan Jiang*， Liang-Qiu Lu* and Wen-Jing Xiao* DOI：10.1002/anie.202312102
Copper-Catalyzed Asymmetric Radical 1,2-Alkylesterification of 1,3-Dienes with Cycloalkyl Hydroperoxides and Acids Tian-Tian Li, Ying Cheng, Wen-Jing Xiao, De-Qing Shi*, Jia-Rong Chen* DOI: 10.1002/cctc.202301068
Photoinduced Five-Component Radical Relay Aminocarbonylation of Alkenes Bin Lu, Zhihan Zhang, Min Jiang, Dong Liang, Zi-Wei He, Feng-Shuo Bao, Wen-Jing Xiao, and Jia-Rong Chen* DOI: 10.1002/anie.202309460
Emerging Trends in Copper-Promoted Radical-Involved C–O Bond Formations Peng-Zi Wang, Jia-Rong Chen*, and Wen-Jing Xiao* DOI: 10.1021/jacs.3c04879
Diradical ring formation Peng-Zi Wang and Jia-Rong Chen* 10.1038/s41557-023-01263-5
Photoinduced carbene transfer for copper-catalyzed asymmetric [4 + 1] cycloadditions: an entry to chiral indolines bearing quaternary stereocenters Bao-Le Qu, Bin Shi, Lin He, Jun-Wei Shi, Wen-Jing Xiao and Liang-Qiu Lu* 10.1039/D3QO00551H
Photoinduced copper-catalyzed asymmetric radical three-component cross-coupling of 1,3-enynes with oxime esters and carboxylic acids Guo-Qing Li, Fan-Rong Meng, Wen-Jing Xiao and Jia-Rong Chen* DOI: 10.1039/D3QO00513E
Asymmetric [3 + 2] Photocycloaddition of β-Keto Esters and Vinyl Azides by Dual Photoredox/Nickel Catalysis Xue-Song Zhou, Zhihan Zhang, Wen-Yuan Qu, Xiao-Peng Liu, Wen-Jing Xiao,* Min Jiang,* and Jia-Rong Chen*DOI:10.1021/jacs.3c02485
Electrochemical Reactors Enable Divergent Site Selectivity in the C-H Carboxylation of N-Heteroarenes Peng-Zi Wang, Wen-Jing Xiao*, and Jia-Rong Chen*DOI: 10.1002/anie.202302227
Dynamic Kinetic Reductive Conjugate Addition for Construction of Axial Chirality Enabled by Synergistic Photoredox/Cobalt Catalysis Wei Xiong,# Xuan Jiang,# Wen-Cheng Wang, Ying Cheng, Liang-Qiu Lu, Ke Gao,* and Wen-Jing Xiao*DOI: 10.1021/jacs.2c13538
Dearomatization-Rearomatization Reaction of Metal-Polarized Aza-ortho-Quinone Methides Bao-Cheng Wang,‡ Li Rao,‡ Kai-Xin Fang,‡ Bao-Le Qu, Fen-Ya Xiong, Ying Feng, Ying Tan,* Liang-Qiu Lu,* Wen-Jing Xiao DOI: 10.1002/anie.202301592
Advances in the construction of axially chiral biaryl-contained medium-sized rings via asymmetric catalysi Baole Qu, Lin He, Junwei Shi, Liangqiu Lu*, Wenjing Xiao,*DOI: 10.1360/SSC-2022-0244
Photoinduced Cobalt-Catalyzed Desymmetrization of Dialdehydes to Access Axial Chirality Hao Jiang,‡ Xiang-Kui He,‡ Xuan Jiang,‡ Wei Zhao, Liang-Qiu Lu, Ying Cheng,* and Wen-Jing Xiao*DOI: 10.1021/jacs.3c00462
Cobalt-Catalyzed Asymmetric Phospha-Michael Reaction of Diarylphosphine Oxides for the Synthesis of Chiral Organophosphorus Compounds Yu, X.-H.; Lu, L.-Q.; Zhang, Z.-H.; Shi, D.-Q.* and Xiao, W.-J. Org. Chem. Front., 2022, Article ASAP DOI: 10.1039/D2QO01483A
Taming Chiral Quaternary Stereocenters via Remote H-Bonding Stereoinduction in Palladium-Catalyzed (3+2) Cycloadditions Xiao, Y.-Q.; Li, M.-M.; Zhou, Z.-X.; Li, Y.-J.; Cao, M.-Y.; Liu, X.-P.; Lu, H.-H.; Li, R.; Lu, L.-Q.*; Beauchemin, A. M. and Xiao, W.-J. Angew. Chem. Int. Ed. 2022, In press. DOI: 10.1002/anie.202212444
Light-empowered contra-thermodynamic stereochemical editing Wang, P.-Z.; Xiao, W.-J.*; Chen, J.-R.* Nature Reviews Chemistry, 2022, In press. DOI: 10.1038/s41570-022-00441-2
Construction of axially chiral compounds via catalytic asymmetric radical reaction Liang, D.; Xiao, W.-J.; Sami, L.* and Chen, J.-R.* Green Synthesis and Catalysis 2022, 3, 212-218. DOI: 10.1016/j.gresc.2022.06.003
De Novo Construction of Chiral Aminoindolines by Cu-Catalyzed Asymmetric Cyclization and Subsequent Discovery of an Unexpected Sulfonyl Migration Wang, B.-C.; Fang, T.-T.; Xiong, F.-Y.; Chen, P.; Fang, K.-X.; Tan, Y.*; Lu, L.-Q.* and Xiao, W.-J. J. Am. Chem. Soc. 2022, ASAP. DOI: 10.1021/jacs.2c08090
Visible-Light-Induced Photoredox-Catalyzed Selective 1,4-Difluoroalkylesterification of 1-Aryl-1,3-dienes Bi, M.-H.;Cheng, Y.; Xiao, W.-J. and Chen, J.-R.* Org. Lett., 2022, 24, 7589-7594. DOI: 10.1021/acs.orglett.2c03020
Selective Three-Component 1,2-Aminoalkoxylation of 1-Aryl-1,3-dienes by Dual Photoredox and Copper Catalysis Wu, Y.-L.;Jiang, M.; Rao, L.; Cheng, Y.; Xiao, W.-J. and Chen, J.-R.* Org. Lett., 2022, 24, 7470-7475. DOI: 10.1021/acs.orglett.2c03124
Construction of axial chirality via asymmetric radical trapping by cobalt under visible light Jiang, X.; Xiong, W.; Deng, S.; Lu, F.-D.; Jia, Y.; Yang, Q.; Xue, L.-Y.; Qi, X.-T.; Tunge, J. A.; Lu, L.-Q.* and Xiao, W.-J.* Nat., Catal. 2022, 5, 788-797. DOI: 10.1038/s41929-022-00831-1
Copper-Catalyzed Three-Component Photo-ATRA-Type Reaction for Asymmetric Intermolecular C–O Coupling Wang, P.-Z.; Liang, Y.-J.; Wu, X.; Guan, W.*; Xiao, W.-J.* and Chen, J.-R.* ACS Catal. 2022, 12, 10925–10937. DOI: 10.1021/acscatal.2c03576
Photoinduced C–O bond cleavage for copper-catalyzed allenyl radical cyanation Lu, F.-D.; Shu, Z.-C.; He, G.-F.; Bai, J.-C.; Lu, L.-Q.* and Xiao, W.-J.* Org. Chem. Front., 2022, 9, 5259-5263. DOI: 10.1039/D2QO00938B
Switchable Radical Carbonylation by Philicity Regulation Lu, B.; Xu, M.-H.; Qi, X.-T.; Jiang, M.; Xiao, W.-J.* and Chen, J.-R.* J. Am. Chem. Soc. 2022, 144, 14923–14935. DOI: 10.1021/jacs.2c06677
N-Heterocyclic Carbene (NHC)-Catalyzed Desymmetrization of Biaryldialdehydes to Construct Axially Chiral Aldehydes Zhao, W.; Liu, J.; He, X.-K.; Jiang, H.; Lu, L.-Q.* and Xiao, W.-J.* Chinese Journal of Organic Chemistry, 2022, 42,2504-2514. DOI: 10.6023/cjoc202203048
High-order dipolar annulations with metal-containing reactive dipoles Zhang, M.-M.;† Qu, B.-L.;† Shi, B.;† Xiao, W.-J. and Lu, L.-Q.* Chem. Soc. Rev. 2022, 51, 4146-4174. DOI: 10.1039/D1CS00897H
Photoassisted Cobalt-Catalyzed Asymmetric Reductive Grignard-Type Addition of Aryl Iodides Jiang, X.; Jiang, H.; Yang, Q.; Cheng, Y.; Lu, L.-Q.*; J. A. Tunge and Xiao, W.-J.* J. Am. Chem. Soc. 2022, 144, 8347-8354. DOI: 10.1021/jacs.2c02481
Synthesis of Chiral Endocyclic Allenes by Palladium-Catalyzed Asymmetric Annulation Followed by Cope Rearrangement Shi, B.; Liu, J.-B.; Wang, Z.-T.; Wang, L.; Lan, Y.; Lu, L.-Q.* and Xiao, W.-J. Angew. Chem. Int. Ed. 2022, 61, e202117215. DOI: 10.1002/anie.202117215
Catalytic Asymmetric Construction of Axially and Centrally Chiral Heterobiaryls by Minisci Reaction Liang, D.; Chen, J.-R.; Tan, L.-P.; He, Z.-W. and Xiao, W.-J.* nJ. Am. Chem. Soc. 2022, 144, 6040-6049. DOI: 10.1021/jacs.2c01116
Photoredox-Catalyzed and Copper(II) Salt-Assisted Radical Addition/Hydroxylation Reaction of Alkenes, Sulfur Ylides, and Water Dong-Mei Yan, Shuang-Hua Xu, Hao Qian, Pan-Pan Gao, Ming-Hang Bi, Wen-Jing Xiao*, and Jia-Rong Chen*DOI: 10.1021/acscatal.2c00638
Photoredox-Enabled Chromium-Catalyzed Alkene Diacylations Jing Liu,# Liang-Qiu Lu,# Yi-Xin Luo, Wei Zhao, Peng-Chao Sun, Wei-Wei Jin, Xiao-Tian Qi,* Ying Cheng,* and Wen-Jing Xiao*DOI: 10.1021/acscatal.1c05672
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