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研究领域

催化化学中的催化氧化领域,包括阐明催化氧化中的基本科学问题如氧化过程中各活性物种间的氧化性能关系及添加助剂如何影响氧化催化剂的反应性能、发展新的催化技术应用于有机废水的治理与利用、从生物资源中获取石油化工的替代品以及实际的工业催化应用等。

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Guochuan Yin*,Understanding the Oxidative Relationships of the Metal Oxo, Hydroxo and Hydroperoxide Intermediates with Manganese(IV) Complex Having Bridged Cyclam: Correlation of the Physicochemical Properties with Reactivity, Acc. Chem. Res., 2013, 46,483-492. Zhou, Li; Song, Wei; Chen, Zhuqi; Guochuan Yin*, Degradation of Organic Pollutants in Wastewater by Bicarbonate-Activated Hydrogen Peroxide with a Supported Cobalt Catalyst, Environ. Sci. & Technol., 2013, 47, 3833-3839. Huajun Guo, Guochuan Yin*, Catalytic Aerobic Oxidation of Renewable Furfural with Phosphomolybdic Acid Catalyst: an Alternative Route to Maleic Acid, J. Phys. Chem., C, 2011, 115, 17516-17522. Song Shi, Yujuan Wang, Aihua Xu, Huajun Wang, Dajian Zhu, Suparna Baksi Roy, Timothy A. Jackson, Daryle H Busch, Guochuan Yin*, Distinct Reactivity Differences of Metal Oxo and Its Corresponding Hydroxo Moieties in Oxidations: Implications from a Manganese(IV) Complex Having Dihydroxide Ligand, Angew, Chem. Intl. Ed. 2011, 50, 7321-7324. Guochuan Yin, Andrew M. Danby, David Kitko, John D. Carter, William M. Scheper and Daryle H. Busch,Oxidative Reactivity Difference Between the Metal Oxo and Metal Hydroxo Moieties: pH Dependent Hydrogen Abstraction by a Manganese(IV) Complex Having Two Hydroxide Ligands, J. Am. Chem. Soc., 2008, 130,16245-16253. Guochuan Yin, Andrew M. Danby, David Kitko, John Carter, William M. Scheper and Daryle H. Busch, Understanding the Selectivity of a Moderate Oxidation Catalyst:Hydrogen Abstraction by a Fully Characterized, Activated Catalyst, the Robust Dihydroxo Manganese (IV) Complex of a Bridged Cyclam, J. Am. Chem. Soc.,2007, 129, 1512-1513. Guochuan Yin, Maria Buchalova, Andrew M Danby, Chris M Perkins, David Kitko, John D Carter, William M Scheper, Daryle H Busch, Olefin Oxygenation by the Hydroperoxide Adduct of a Nonheme Manganese(IV) Complex: Epoxidations by a Metallo-Peracid Produces Gentle Selective Oxidations, J. Am. Chem. Soc., 2005, 127, 17170-17171.

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