郑炎松 - 华中科技大学 - 化学与化工学院

个人简介

郑炎松 (Dr. Yan-Song Zheng)，教授，博导。1982年华中师范大学化学系学士，1996年中国科学院化学研究所博士，1999-2001香港大学化学系博士后，2002-2004美国密西西比大学药物化学系访问学者。主持完成了3项国家自然科学基金面上项目，1项教育部留学回国基金和诸多横向课题，2010年获得湖北省自然科学基金三等奖，现正在主持1项国家自然科学基金重大研究计划项目以及1项国家自然科学基金面上项目。在Chem. Soc. Rev., J. Am. Chem. Soc., Angew. Chem. Int. Ed., Chem. Mater, Chem. Commun., Org. Lett.等杂志上发表SCI收录的通讯作者和第一作者论文近百篇，有3篇论文入选ESI高被引论文，H-index 大于20。获得授权发明专利4项。参与编著编写学术专著1本，有机化学教材1本。

研究领域

1.基于聚集诱导发光 (AIE)的园偏振发光 (CPL) 材料研究具有聚集诱导发光 (Aggregation-Induced Emission，AIE) 特性的有机分子，在溶液中没有荧光，在聚集状态下能产生强烈的荧光，在有机发光二极管(OLED)以及生物成像、医学诊断、分子传感器等方面具有重大的应用价值，引起了极大的重视和广泛的关注, 2015年被Thomson Reuters评为在化学与材料科学领域第二大顶级研究前沿。我们首次提出将分子的手性与AIE特性联系起来，进行手性识别，发现手性AIE分子用于手性识别和对映体纯度定量分析具有特别高的选择性，特别高的灵敏度和特别广泛的适用性。 2. AIE大环化合物的合成及分子识别和自助装性能研究将AIE分子连接成大环后，由于环状化合物比开链化合物刚性更强，按照AIE分子内运动受限(RIM) 机理，环状化合物将具有更强的荧光发射强度；环状化合物本身具有洞穴，通过洞穴大小和形状对客体分子的限制，可以显著提高AIE分子作为传感器的选择性。我们对一系列AIE大环分子的研究发现，大环在AIE现象增强、分析检测中灵敏度和选择性提高、客体分子调节荧光发射、超分子催化、AIE机理揭示和证明、四苯乙烯螺旋手性应用、分子储存、分离和释放等方面比开链AIEgen分子具有更大优势，见课题组发表的深度综述论文，Chem. Soc. Rev. 2018, 7452。例如我们发现AIE大环折叠体形成的发光纳米粒子，用十多种硝基芳香烃做淬灭实验时，其荧光更容易被爆炸物TNT淬灭，可用于检测每毫升空气中飞克级TNT, 相当于探测犬的灵敏度，是目前荧光分析方法中灵敏度最高的。 3. 有应用价值的重要有机化合物、药物中间体的合成以及一些药物分子合成方法及路线的改进

近期论文

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Jin-Hua Wang, Hai-Tao Feng, Yan-Song Zheng,* Synthesis of Tetraphenylethylene Pillar[6]arenes and the Selective Fast Quenching of Their AIE Fluorescence by TNT. Chem. Commun., 2014, 50 (77), 11407–11410. Jin-Hua Wang, Hai-Tao Feng, Jun Luo, Yan-Song Zheng,* Monomer Emission and Aggregate Emission of an Imidazolium Macrocycle Based on Bridged Tetraphenylethylene and Their Quenching by C60, J. Org. Chem. 2014, 79 (12), 5746–5751. Song-Song, Jin-Hua Wang, Hai-Tao Feng, Zhi-Hua Zhu, Yan-Song Zheng,* Supramolecular 1 hydrogel based on amphiphilic calix[4]arene and its application in the synthesis of silica nanotubes, ASC Adv. 2014, 4(47), 24909–24913. Jin-Hua Wang, Yi-Chang Chen, Yan-Song Zheng,* Chang-Hong Shen, Selective Nitration of Calix[4]arenes that Easily Gave Inherently Chiral Calix[4]arenes, J. Incl. Phenom. Macro. Chem. 2014, DOI 10.1007/s10847-014-0413-7. Chun Zhang,* Yan-Song Zheng,* et al., Tetraphenylethylene-based expanded oxacalixarene: synthesis, structure, and its supramolecular grid assemblies directed by guests in the solid state.J. Org. Chem. 2014, 79(6), 2729–2732. Song-Song, Hua-Fei Zheng, Dong-Mi Li, Jin-Hua Wang, Hia-Tao Feng, Zhi-Hua Zhu, Yi-Chang Chen, Yan-Song Zheng,* Monomer Emission and Aggregate Emission of TPE Derivatives in the Presence of γ?Cyclodextrin, Org. Lett. 2014, 16 (8), 2170–2173. Hai-Tao Feng, Song-Song, Yi-Chang Chen, Chang-Hong Shen, Yan-Song Zheng,* Self-assembled tetraphenylethylene macrocycle nanofibrous materials for the visual detection of copper(II) in water, J. Mater. Chem. C, 2014, 2, 2353–2359 Hai-Tao Feng, Yan-Song Zheng,* Highly Sensitive and Selective Detection of Nitrophenolic Explosives by Using Nanospheres of a Tetraphenylethylene Macrocycle Displaying Aggregation-Induced Emission, Chem. Eur. J. 2014, 20, 195 – 201. Song Song, Yan-Song Zheng,* Hollow spheres self-assembled by a tetraphenylethylene macrocycle and their transformation to bird nests under ultrasound, Org. Lett., 2013, 15 (4), 820–823. Dong-Mi Li, Yi-Chang Chen, Chun-Zhang, Song Song, Yan-Song Zheng,* Different morphologies of silica synthesized using organic templates from the same class of chiral compounds, J. Mater. Chem. B, 2013, 1, 1622–1627. Yi-Long Duan, Yan-Song Zheng,* A new sensitive and selective fluorescence probe for detection of cyanide, Talanta, 2013, 107, 332–337. Yi-Chang Chen, Huan Wang, Dong-Mi Li, Yan-Song Zheng,* Exceptional acid–base organogelators for a wide variety of organic liquids and their many applications, Eur. J. Org. Chem., 2013, 8, 1521–1529. Ning-Ning Liu, Song Song, Dong-Mi Li, Yan-Song Zheng,* Highly sensitive determination of enantiomer composition of chiral acids based on aggregation-induced emission, Chem. Commun., 2012, 48, 4908–4910. Dong-Mi Li, Huan Wang, Yan-Song Zheng,* Light-emitting property of simple AIE compounds in gel, suspension and precipitates, and application to quantitative determination of enantiomer composition,Chem. Commun.,2012, 48, 3176–3178, cover paper. Hong Huang, Dong-Mi Li, Wei-Zhou Wang, Yi-Chang Chen, Yan-Song Zheng,* Effect of carboxylic acid on micelles of an neutral amphiphilic dendro-calix[4]arene, Org. Biomol. Chem., 2012, 10, 729–735, cover paper. Khalid Khan, Hong Huang, Yan-Song Zheng,*Design, synthesis, and transport potential of a new family of nonionic amphiphilic dendro-calix[4]arene, Curr. Org. Chem., 2012, 16, 2745–2751. Jun Luo, Yan-Song Zheng,* Supramolecular chirality based on calixarenes, Curr. Org. Chem., 2012, 16, 483–506.