聂进 - 华中科技大学 - 化学与化工学院

研究领域

长期从事含氟氮超酸弱配位有机阴离子的设计、合成与性能的研究工作。 1. 利用含氟氮超酸弱配位有机阴离子的过渡金属配合物（特别是镧系化合物），开展新型Lewis酸催化剂的研究。开发出一类新型、高效的绿色催化剂，在当量硝化反应、Diels-Alder反应、F-C酰化反应以及酯化反应等重要的有机合成反应中取得到很好的效果。 2. 利用含氟氮超酸弱配位有机阴离子的碱金属化合物，开展新型电解质材料的研究。在国家863计划课题的资助下，设计合成了近300个不同结构的新型低粘度离子液体，系统研究了离子液体结构与性能的关系。将这些含氟氮超酸弱配位有机阴离子的锂盐作为导电盐，在新型锂离子电池电解质、聚合物离子液体电解质以及固体聚合物电解质等方面，开展了一系列系统的基础和应用基础研究。

近期论文

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Composite electrolytes of lithium salt/polymeric ionic liquid with bis(fluorosulfonyl)imideLithium,Solid State Ionics, 2014, 256, 61. Polymeric ionic liquids based on ether functionalized ammoniums andperfluorinated sulfonimides, Polymer, 2014, 55, 3339. Lithium bis(fluorosulfonyl)imide/poly(ethylene oxide) polymerelectrolyte, Electrochim. Acta, 2014, 133, 529. New hydrophobic ionic liquids based on(fluorosulfonyl)(polyfluoro- oxaalkanesulfonyl)imides with various oniums, Electrochim. Acta, 2013, 99, 262. Ionic liquids based on bis(2,2,2-trifluoroethoxysulfonyl)imidewith various oniums, Electrochim. Acta, 2013, 94, 229. Single lithium-ion conducting polymer electrolytes based on poly[(4-styrenesulfonyl)(trifluoromethanesulfonyl)imide] anions, Electrochim. Acta, 2013, 93, 254. Mesoporous silica supported water-stable perfluorobutylsulfonylimideand its catalytic applications in esterification, Microporous and Mesoporous Materials, 2013, 172 , 51. Bis(fluoro- sulfonyl)imide (LiFSI) as conducting salt for nonaqueous liquidelectrolytes for lithium-ion batteries: Physicochemical and electrochemicalproperties,J. Power Sources, 2011 196, 3623. Lithium (fluorosulfonyl)(nonafluorobutanesulfonyl)imide (LiFNFSI) as conductingsalt to improve the high-temperature resilience of lithium-ion cells, Electrochem. Commun., 2011, 13, 265. Ionic liquids and plastic crystals based on tertiary sulfonium and bis(fluorosulfonyl)imide, Electrochim. Acta, 2010, 55, 1221. Efficient Preparation of (Fluorosulfonyl) (pentafluoroethanesulfonyl)imide and Its Alkali Salts, Chem. Lett., 2010, 39, 472. Ionic liquid electrolytes based on multi-methoxyethyl substituted ammoniumsand perfluorinated sulfonimides: preparation, characterization, and properties,Electrochim. Acta, 2010, 55, 7134. Ionic liquids based on (fluorosulfonyl)- (pentafluoroethanesulfonyl)imidewith various oniums,Electrochim. Acta, 2010, 55, 7145. SBA-15-supported poly(4-styrenesulfonyl(perfluorobutylsulfonyl)imide) as heterogeneous Brønsted acid catalyst for synthesis of diindolylmethane derivatives, J.Mol. Cata. A: Chem., 2009, 311, 46. Lanthanide bis[(trifluoromethyl)sulfonyl]imides as reusablecatalysts for mononitration of substituted benzenes inionic liquids, Adv. Synth. Catal,. 2009, 351, 193.