肖元晶 - 华东师范大学 - 化学与分子工程学院

个人简介

教育经历 1993.09-1997.07 湖北大学化学与材料科学学院理学学士 1997.09-2002.07 武汉大学化学与分子科学学院理学博士工作经历 2002.09-至今华东师范大学化学与分子工程学院 2011.10-2012.10 美国加州大学圣巴巴拉分校访问学者荣誉及奖励华东师范大学自然科学奖二等奖 2018年度上海大学生实验竞赛优秀指导教师奖

研究领域

基础理论研究方向：高选择性现代有机合成反应设计，多样性导向有机合成方法学研究, 新型催化剂的设计与开发，新型含氟砌块的设计与转化研究，不对称催化。先后参与多项上海市科委重大基础研究项目及国家自然科学基金项目应用化学研究方向：药物及中间体的合成工艺开发

近期论文

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Zongxiang Yu, Jintong Li, Yuxuan Cao, Tingwei Dong, and Yuanjing Xiao*3,Trifluoromethyl Pyrrole Synthesis Based on β,CF3,1,3-Enynamides. J. Org. Chem. 2023, 88, 15501. Juan Feng, Jiayi Shi, Lan Wei, Mingqing Liu, Zhiming Li, * Yuanjing Xiao* and Junliang Zhang*Palladium/PC-Phos-Catalyzed Asymmetric Heck/Tsuji-Trost Reactions of Amino-Tethered 1,3-Cyclohexadiene with Aryl and Alkenyl Halides. Angew. Chem. Int. Ed., 2022, 61,10.1002/anie.202215407. QinZeng, Xinyu Huang, Mingqing Liu, Zongxiang Yu, and Yuanjing Xiao*Synthesis of Trifluoromethylated 4H-Pyran and 4H-Thiopyran via Divergent Reaction of β-CF3-1,3-Enynes with β-Ketothioamides.Org. Lett., 2022, 24, 8186,8191. LanWei, Shiteng Ding, Mingqing Liu, Zongxiang Yu, and Yuanjing Xiao* Synthesis of Trifluoromethylated Pyrazolidines, Pyrazolines and Pyrazoles via Divergent Reaction of β-CF3-1,3-Enynes with Hydrazines. Org. Lett., 2021, 23, 7718,7723. Anjing Hu, Zhan-Ming Zhang, Yuanjing Xiao*, Junliang Zhang* Stereoselective Synthesis of Chiral Sulfinamide Monophosphine Ligands (Ming-Phos)(S, Rs)-M. Org. Synth., 2020, 97, 262-273. Yi Wu, Yuanjing Xiao*, Junliang Zhang* BCl3 Mediated Borylative Cyclization of 2-(1-alkynyl)-2-alken-1-ones. Chin. J. Org. Chem. 2020, 40. cjoc202005025.R1. HuayuCheng, XiaofanZhou, AnjingHu, ShitengDing, YimoWang, Yuanjing Xiao*, Junliang Zhang* Thioether-Functionalized Trifluoromethyl-alkynes, 1, 3-Dienes and Allenes: Divergent Synthesis from Reaction of 2-Trifluoromethyl-1, 3-Conjugated Enynes with Sulfur Nucleophiles. RSC Adv., 2018, 8, 34088–34093. Qin Zeng, Li Zhang,Yuanjing Xiao* and Junliang Zhang* Divergent Access to N-Hydroxypyrroles and Isoxazoles via Gold(I)- or Br,nsted Acid- Catalysed Regioselective Cyclization of N-(2-trifluoromethyl-3-Alkynyl) Oximes. Org. Biomol. Chem., 2018, 16，1375-1380。 Chaoqian Huang, Yu Zeng, Huayu Cheng, Anjing Hu, Lu Liu, Yuanjing Xiao, * and Junliang Zhang*A One-Pot Construction of Halogenated Trifluoromethylated Pyrroles through NXS (X =Br, I) Triggered Cascade. Org. Lett., 2017, 19, 4968-4971. Yu Zeng,Chaoqian Huang, Peiyun Ni, Lu Liu,Yuanjing Xiao*and Junliang Zhang* Silver-Catalyzed Double Hydrocarbonation of 2-Trifluorometh- yl-1,3-Conjugated Enynes with 1,3-Dicarbonyl Compounds: Synthesis of Ring-Trifluoromethylated Cyclopentene. Adv. Synth. Catal. 2017, 359, 3555-3559. Jieru Yang, Xiaofan Zhou, Yu Zeng, Chaoqian Huang, Yuanjing Xiao* and Junliang Zhang*Divergent Synthesis from Reactions of 2-Trifluoromethyl-1,3-Conjugated EnyneswithN-Acetylated 2-Aminomalonates. Org. Biomol. Chem., 2017, 15, 2253-2258. Xiaofan Zhou, Chaoqian Huang, Yu Zeng, Jiarui Xiong, Yuanjing Xiao* and Junliang Zhang* , Silver-Catalysed Tandem Hydroamination and Cyclization of 2-Trifluoromethyl-1,3-Enynes with Primary Amines:A Modular Entry to 4-Trifluoromethyl-3-Pyrrolines. Chem. Commun.,2017, 53, 1084-1087. Bing Xu, Zhan-Ming Zhang, Shan Xu, Bing Liu, Yuanjing Xiao and Junliang Zhang* Copper(I)/Ming-Phos-Catalyzed Asymmetric Intermolecular [3+2] Cycloaddition of Azomethine Ylides with a-Trifluoromethyl a, b-Unsaturated Esters. ACS Catal. 2017, 7, 210,214. Jieru Yang, Xiaofan Zhou, Yu Zeng, Chaoqian Huang, Yuanjing Xiao* and Junliang Zhang*Synthesis of 2-fluoro-2-pyrrolines via tandem reaction of α-trifluoromethyl-α,β-unsaturatedcarbonyl compounds with N-tosylated2-aminomalonates. Chem.Commun., 2016, 52, 4922. Yanqing Zhang, Yuanjing Xiao* and Junliang Zhang*. Gold(I)-Catalyzed Stereospecific [4+3] Cycloaddition Reaction of Optically Active 1-(1-alkynyl)cyclopropyl Ketone with Nitrones: A Modular Entry to Enantioriched 5,7-Fused Bicyclicfuro[3,4-d]-[1,2]oxazepines. Synthesis, 2016, 48, 512(Feature Article). Peng Chen, Xiao Su, Wei Zhou,Yuanjing Xiao* and Junliang Zhang*. Novel Chiral Sulfinamide Phosphines : Valuable Precursors to Chiral β-Aminophosphines. Tetrahedron,2016, 72, 2700. Jieru Yang, Ao Mao, Zhenting Yue, Wenxuan Zhu, Xuewei Luo, Chuwei Zhu,Yuanjing Xiao* and Junliang Zhang* A simple base-mediated synthesis of diverse functionalized ring-fluorinated 4H-pyran via double direct C-F substitutions,Chem.Commun,2015, 51, 8326. Ziqi Tian, Yuanjing Xiao, Xianggai Yuan, Zuliang Chen, Junliang Zhang* and Jing Ma*. Control of Chemoselectivity by Coordinated Water and Relative Size of Ligands to Metal Cations of Lewis Acid Catalysts for Cycloaddition of an Oxirane Derivative to an Aldehyde: Theoretical and Experimental Study. Organometallics. 2014, 33, 1715. Li Zhang, Qin Zeng, Ao Mao, Ziang Wu, Tian Luo, Yuanjing Xiao* and Junliang Zhang*. NIS-mediated oxidative cyclization of N-(2-trifluoromethyl-3-alkynyl)hydroxylamines:a facile access to 4-trifluoromethyl-5-acylisoxazoles.Org.Biomol. Chem.2014, 12, 8942. Qin Zeng, Li Zhang, Jieru Yang, Bing Xu, Yuanjing Xiao* and Junliang Zhang*. Pyrroles versus Cyclic Nitrones: Catalyst-Controlled Divergent Cyclization of N-(2-perfluoroalkyl-3-alkynyl) hydroxylamines. Chem. Commun. 2014, 50, 4203. Junqing Zhang, Yuanjing Xiao and Junliang Zhang*. Nickel-Catalyzed Annulation of Donor–Acceptor Oxiranes with Imines: Diastereoselective Access to Highly Substituted 2,4-trans- Oxazolidines. Adv. Synth. Catal.2013, 355, 2793. Zuliang Chen, Yuanjing Xiao and Junliang Zhang* . Reaction of Two Differently Functionalized Oxiranes with Nickel Perchlorate :A Modular Entry to Highly Substituted 1,3-Dioxolanes. Eur. J. Org. Chem.2013, 4748. Yuanjing Xiao and Liming Zhang*. Synthesis of Bicyclic Imidazoles via [2 + 3] Cycloaddition between Nitriles and Regioselectively Generated α-Imino Gold Carbene Intermediates.Org. Lett., 2012, 14 (17), 4662. Ze-Yi Yan,Yuanjing Xiao and Liming Zhang*. Gold-Catalyzed One-Step Construction of 2,3-Dihydro-1H-Pyrrolizines with an Electron-Withdrawing group in the 5-position: A Formal Synthesis of 7-Methoxymitosene. Angew. Chem. Int. Ed. 2012, 51, 8624. Yuanjing Xiao, Junliang Zhang*. Tetrasubstituted Allenes by Pd0-Catalyzed Three-Component Tandem Michael Addition / Cross-Coupling Reaction.Chem. Commun. 2010,46, 752. Yuanjing Xiao, Junliang Zhang*. Pd(II)-Catalyzed Domino Reaction of 2-(1-Alkynyl)-2-alken-1-ones with Nucleophiles: Scope, Mechanism and Synthetic Application in the Synthesis of 3,4-Fused Bicyclic Tetrasubstituted Furans. Adv. Synth. Catal. 2009, 351, 617. Yuanjing Xiao, Junliang Zhang*. Furan versus 4H-Pyran: Catalyst-Controlled Regiodivergent Tandem Michael Addition/Cyclization Reaction of 2-(1-Alkynyl)-2-alken-1-ones with 1,3-Dicarbonyl Compounds. Chem. Commun. 2009, 3594. Yanqing Zhang, Zuliang Chen, Yuanjing Xiao, Junliang Zhang*. RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones. Chem. Eur. J. 2009, 15, 5208. Wenbo Li, Yuanjing Xiao, Junliang Zhang*. Alkynyl Group as Activating Group: Base-Catalyzed Diastereo-selective Domino Reactions of Electron-Deficient Enynes. Adv. Synth. Catal. 2009, 351, 3083. Yuanjing Xiao, Junliang Zhang*. Tetrasubstituted Furans by a Pd(II)-Catalyzed Three-Component Michael Addition /Cyclization /Cross-Coupling Reaction. Angew. Chem. Int. Ed. 2008, 47, 1903. Xiuzhao Yu,Hongjun Ren,Yuanjing Xiao, Junliang Zhang*. Efficient Assembly of Allenes, 1,3-Dienes, and 4H-Pyrans by Catalytic Regioselective Nucleophilic Addition to Electron-Deficient 1,3-Conjugated Enynes. Chem. Eur. J. 2008, 14, 8481.

学术兼职

Journal of Heterocyclics (ISSN 2639-6734)，编委