个人简介

Fellow, American Association for the Advancement of Science, 2014. — Honored for distinguished contributions to the field of bioinorganic chemistry, particularly in the elucidation of structure function relationships critical to biological C-H bond activation. Alfred P. Sloan Fellow, 2006. Beckman Young Investigator, 2004. National Science Foundation Career Award, 2004.

研究领域

Analytical/Biological/Computational /Theoretical/Inorganic/Physical

Analytical Applications of Computers to Chemical Problems Biological Biological, Inorganic, and Physical Chemistry Computational / Theoretical Biological, Inorganic, and Physical Chemistry Inorganic Biological, Inorganic, and Physical Chemistry Physical Biological, Inorganic, and Physical Chemistry

近期论文

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Yosca, T.H.; Behan, R.K.; Krest, C.M.; Onderko, E.L.; Langston, M.L.; Green, M.T.* "Setting an Upper Limit on the Myoglobin Iron(IV)Hydroxide pKa: Insight into Axial Ligand Tuning in Heme Protein Catalysis", Journal of the American Chemical Society, 2014, 136, 9124?9131. Dassama, L.M.K.; Silakov, A.; Krest, CM.; Calixto, J.C; Krebs, C.*; Bollinger, J.M. Jr.*; and Green, M.T.* "A 2.8 ? Fe-Fe Separation in the Fe2III/IV Intermediate (X) from Escherichia coli Ribonucleotide Reductase", Journal of the American Chemical Society, 2013, 135, 16758-16761. Yosca, T.H.; Rittle, J.; Krest, C.M.; Onderko, E.L.; Silakov, A.; Calixto, J.C.; Behan, R.K.; Green, M.T.* "Iron(IV)hydroxide pKa and the Role of Thiolate Ligation in C-H Bond Activation by Cytochrome P450", Science, 2013, 342, 825-829. Rittle, J.; Green, M.T.* "Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics", Science, 2010, 330, 933-937. Younker, J.M.; Krest, C.M.; Jiang, W.; Krebs, C.*; Bollinger, J.M., Jr.*; Green, M.T.* "Structural Analysis of the MnIV/FeIII Cofactor of Chlamydia trachomatis Ribonucleotide Reductase by Extended X-ray Absorption Fine Structure Spectroscopy and Density Functional Theory Calculations", Journal of the American Chemical Society, 2008, 130, 15022-15027. Behan R.K.; Hoffart, L.M.; Stone, K.L.; Krebs, C.; Green, M.T.* "Reaction of Cytochrome P450 with Peroxynitrite Yields Nitrosyl Complex", Journal of the American Chemical Society, 2007, 129, 5855-5859. Stone, K.L.; Behan R.K.; Green, M.T.* "Resonance Raman Spectroscopy of Chloroperoxidase Compound II Provides Direct Evidence for the Existence of an Iron(IV)-Hydroxide", Proceedings of the National Academy of Sciences, 2006, 103, 12307-12310. -- Green, M.T.* "Application of Badger’s Rule to Heme and Non-Heme Iron-Oxygen Bonds: An Examination of Ferryl Protonation States", Journal of the American Chemical Society, 2006, 128, 1902-1906. Hendrich, M.T.*, Gunderson, W., Mehn, M.P., Betley, T.A., Lu, C.C., Behan, R.K., Green, M.T.*, Peters, J.C.*, On the Feasibility of N2 Fixation via a Single Site Fe(I)/Fe(IV) Cycle - Spectroscopic Studies of Fe(I)-N2-Fe(I), Fe(IV)oN, and Related Species, Proceedings of the National Academy of Sciences, 2006, 103, 17107-17112. Green, M.T.*; Dawson, J.H.; Gray, H.B., "Oxoiron(IV) in Chloroperoxidase Compound II is Basic: Implications for P450 Chemistry", Science 2004, 304, 1653-1656.