研究领域
金属-有机骨架(MOF)材料的设计合成与性质研究
以刚性带有多官能团修饰的配体为有机构筑基元‚过渡金属离子或者簇为无机构筑基元‚通过扩散、水/溶剂热或者离子热等合成方法‚设计合成具有功能化孔道‚高比表面积的金属-有机多孔材料‚并研究其在气体吸附分离‚催化等方面的性质。
近期论文
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Thomas C. W. Mak*, Xiao-Li Zhao, Quan-Ming Wang, Guo-Cong Guo, “Synthesis and structural characterization of silver(I) double and multiple salts containing the acetylenediide dianion”, Coord. Chem. Rev., 2007,251, 2311-2333.
Xiao-Li Zhao, Quan-Ming Wang and Thomas C. W. Mak*, “Betaine-induced assembly of neutral infinite columns and chains of linked silver(I) polyhedra with embedded acetylenediide”, Chem. Eur. J., 2005, 11, 2094- 2102.
Xiao-Li Zhao and Thomas C. W. Mak*, “Ligand-induced disruption of polyhedral C2@Agn cage assembly in silver acetylenediide complexes”, Organometallics, 2005, 24, 4497-4499.
Xiao-Li Zhao, Lin-Ping Zhang and Thomas C. W. Mak*, “Polyhedral C2@Agn cages distorted by ancillary pyridine N-oxide ligands in silver-acetylenediide complexes”, Dalton Trans., 2006, 3141-3146.
Xiao-Li Zhao and Thomas C. W. Mak*, “Silver cages with encapsulated acetylenediide as building blocks for hydrothermal synthesis of supramolecular complexes with n-cyanopyridine and pyridine-n-carboxamide (n = 3, 4)”, Dalton Trans., 2004, 3212-3217.
Xiao-Li Zhao, Quan-Ming Wang and Thomas C. W. Mak* “Self-assembled silver polyhedra with embedded acetylide dianion stabilized by perfluorocarboxylate and 4-hydroxyquinoline ligands”, Inorg. Chem., 2003, 42, 7872-7876.
Xiao-Li Zhao and Thomas C. W. Mak*, “Supramolecular assembly of some polynuclear silver(I) complexes with encapsulated acetylenediide dianion and potentially exo-bidentate ligands”, Polyhedron, 2006, 25, 975-982.
Xiao-Li Zhao and Thomas C. W. Mak, “4,4’-Bipyridine and bis(4-pyridyl)propane as bridging ligands in the supramolecular assembly of silver(I) polyhedra containing embedded acetylenediide”, Polyhderon, 2005, 24, 940-948.
Liang Zhao, Xiao-Li Zhao and Thomas C. W. Mak*, “Assembly of Infinite Silver(I) Columns, Chains and Bridged Aggregates with Supramolecular Synthon Bearing Substituted Phenylethynides”, Chem. Eur. J., 2007, 13, 5927 .
Li-Juan Zhang, Xiao-Li Zhao, Ji-Qing Xu* and Tie-Gang Wang, “A novel two-dimensional structure containing the first antimony- substituted polyoxovandium clusters: [{Co(en)2}2SbIII8VIV14O42(H2O)]·6H2O”, Dalton Trans., 2002, 3275-3276.