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个人简介

以碳捕集、利用和封存(CCUS)为研究背景,重点研究材料的表界面扩散与反应特性及其在环境领域中的应用。研究兴趣包括碳捕集与转化利用,吸附/催化双功能材料;材料结构和形貌调控;材料表界面功能化;流体在受限空间的分子传递;多孔材料在大气、水体污染物的吸附分离与降解、汽柴油深度吸附脱硫、工业废水重金属深度脱除等应用。主持国家自然科学基金面上项目5项(结题3项),上海市科技创新国际合作项目1项,中石化重大科技攻关子课题,国家973计划项目子课题,获得欧盟第7框架玛丽居里国际合作项目支持,作为研究骨干参与国家863计划、科技支撑项目、自然科学基金重点项目等。已在国内外重要期刊Energ. Environ. Sci., NatureCommun., Angew. Chem., AIChE J., Chem. Eng J等发表研究论文150余篇,中国发明专利20余项和国际PCT专利1项。获2019 年上海市科技进步奖二等奖。培养博士研究生15人,选派5人赴英、美联合培养;已培养硕士研究生35人,其中3人获国家奖学金,5人获上海市优秀毕业生。

研究领域

(1) CO2的捕集与原位转化 碳捕集、利用与封存(CCUS)技术是应对全球气候变化、控制温室气体排放最重要的技术路径,吸附与原位转化技术具有大规模CO2减排的潜力。我们通过理论计算和实验研究相结合的方法,关注吸附/催化双功能材料结构、表面组成以及吸附/催化活性位对CO2吸附和转化过程中的协同作用关系,CO2捕集与转化优化工艺,形成了分子机理研究→实验合成→中试应用的研究平台。 (2) 新型多孔材料的设计与合成 通过分子模拟和实验研究相结合的方法,设计构筑新型多孔材料,包括一维、二维共价有机框架材料(COF)、多孔离子聚合物(PIPs)、新型沸石咪唑酯骨架材料(ZIFs)、改性金属有机框架材料(MOFs)等,关注孔道结构、表面组成以及功能性活性位对吸附分离、催化转化,及其多功能复合材料等。 (3) 电化学与光催化转化多孔材料的设计 设计合成多孔性电催化剂、光催化剂,包括单原子、量子点、COFs、MOFs等催化剂,用于CO2光、电催化转化、电解水氧生成(OER)电催化等、分析阐明催化机制,为催化材料设计提供思路。 (4) 混合基质膜的设计与应用 膜分离技术的关键是制备兼具高通量、高选择性的膜。混合基质膜以聚合物为连续相,通过添加纳米材料调控膜分离特性。以易挥发有机污染物(VOC)的分离为应用背景,从微观分子相互作用和宏观强化分离作用两方面聚焦混合基质膜结构的演化和调控机制;剖析混合基质膜两相界面和纳米多孔颗粒的吸附对VOCs 分离传质的影响,建立混合基质膜分离过程中“溶解-吸附-扩散”的渗透传递新模型;揭示混合基质膜协同强化分离机制。

近期论文

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Bin Shao, Zhi-QiangWang, Xue-QingGong*, Honglai Liu, FengQian, P. Hu, Jun Hu* Synergistic promotions between CO2 capture and in-situ conversion on Ni-CaO composite catalyst, Nature Communications, 2023, 14: 996-1002。 Shuhao An, Xuewen Li, Shuaishuai Shang, Ting Xu, Shuai Yang, Cheng-Xing Cui, Changjun Peng, Honglai Liu, Qing Xu*, Zheng Jiang*, Jun Hu*, One Dimensional Covalent Organic Frameworks for 2e-Oxygen Reduction Reaction, Angew. Chem. Int. Ed. 2023, 62, e202218742. Wei Xie, Zheyi Sun, Zijun Bian, Honglai Liu, Jun Hu*. Open metal sites in bimetallic Vanadium/Chromium organic framework for enhancing adsorptive desulfurization performance. Chemical Engineering Journal 2023, 142989. Sun Z, Shao B, Zhang Y, Zihao Gao, Meihong Wang, Honglai Liu, Jun Hu* Integrated CO2 capture and methanation from the intermediate-temperature flue gas on dual functional hybrids of AMS/CaMgO||NixCoy. Separation and Purification Technology, 2023, 307: 122680. Shuaishuai Shang, Shuhao An, He Li, Jianping Li, Shenping Zhang, Changjun Peng, Honglai Liu and Jun Hu*, Designed sulfonate-based covalent organic frameworks with dual functions of recognition and encapsulation. J. Mater. Chem. A, 2023, 11, 7539-7544. Shuaishuai Shang, Shenni Li, Changjun Peng, Honglai Liu, and Jun Hu*. Building Internal Electric Fields in porous ionic polymers for fast photocatalytic degradation of tetracycline hydrochloride. J. Mater. Chem. C, 2023, 11, 7397-7404. Wei Xie, Yiping Guo, Jianping Li, Honglai Liu, Jun Hu*, Hydrophobicity regulation by a facial bromine substitution in MIL-47(V) for highly selective adsorptive desulfurization, AIChE Journal, 2022. 10. 2. Yiping Guo, Wei Xie, He Li, Jianping Li, Jun Hu*, Honglai Liu. Construction of hydrophobic channels on Cu(I)-MOF surface to improve selective adsorptive desulfurization performance in presence of water. Separation and Purification Technology 2022, 285, 120287. Shao,B.; Zhang,Y.; Sun,Z.; Li,J.; Gao,Z.; Xie,Z.; Hu,J.*; Liu,H., CO2 capture and in-situ conversion: recent progresses and perspectives. Green Chemical Engineering, 2022. 11. 09 Fenghongkang Pan, Kai Huang, Pengfei Liu, Cheng Lian,* Honglai Liu, Jun Hu,*, In situ Electroactivated Fe-NiOOH Nanoclusters on Carbon Quantum Dots for Efficient Large-Scale Oxygen Production, Small Structures, 2022, 3 (11), 2200094. Bin Shao, Guihua Hu, Khalil A. M. Alkebsi, Guanghua Ye, Xiaoqing Lin, Wenli Du, Jun Hu,* Meihong Wang,* Honglai Liu and Feng Qian, Heterojunction- redox catalysts of FexCoyMg10CaO for high-temperature CO2 capture and in situ conversion in the context of green manufacturing, Energy Environ. Sci., 2021, 14, 2291–2301. Fenghongkang Pan, Tian Jin, Weiwei Yang, He Li, Yueqiang Cao, Jun Hu*, Xinggui Zhou, Honglai Liu, and Xuezhi Duan*, Theory-guided design of atomic Fe–Ni dual sites in N, P-co-doped C for boosting oxygen evolution reaction, Chem Catalysis 2021, 1, 734–745 Wang, C., Guo, F., Li, H., Xu, J., Hu, J.*, Liu, H., Wang, M. A Porous Ionic Polymer Bionic Carrier in a Mixed Matrix Membrane for Facilitating Selective CO2 Permeability. J. Membr. Sci. 2021, 598, 117677 Shenping Zhang, Yimeng Wang, Zan Cao, Jian Xu, Jun Hu*, Yuan Huang, Changzheng Cui, Honglai Liu, Hualin Wang. Simultaneous enhancements of light-harvesting and charge transfer in UiO-67/CdS/rGO composites toward ofloxacin photo-degradation. Chem. Eng. J. 2020, 598 122771. Xiaoqing Lin, Bin Shao, Jichu Zhu, Fenghongkang Pan, Jun Hu,* Meihong Wang,* and Honglai Liu, In Situ Electromagnetic Induction Heating for CO2 Temperature Swing Adsorption on Magnetic Fe3O4/N-Doped Porous Carbon, Energy Fuels 2020, 34, 14439−14446

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