张琪 - 华东理工大学

研究领域

新型板状催化剂制备及微型重整器的研发：区别于普通的涂层法制备一体化催化剂，采用阳极氧化法制备新型多孔一体化氧化铝载体催化剂。将该技术引入到微型重整器流道设计中，将提高催化剂的可塑性，增加反应器的传热及启动性，降低生产成本。目前，主持国家自然科学基金1项，上海市科技启明星计划1项，教育部留学回国人员基金1项及中央高校探索基金2项，致力于二甲醚水蒸气重整技术及微型反应器的开发，VOCs催化剂燃烧催化剂的开发的研究工作。  复杂反应系统模拟、仿真：对于复杂反应系统进行动力学模拟，建立合理的动力学模型推断反应机理。通过MATLAB及COMOSOL等软件，进行耦合传热、传质及反应的瞬时（transient）反应器模拟，可用于讨论反应器的流道设计、操作工况及启动性能等问题。目前主持国家自然科学基金1项，上海市优秀青年教师基金1项。  二氧化碳吸附捕集：针对非平衡甲烷水蒸汽重整制氢体系，利用CO2吸附强化平衡移动，强化甲烷水蒸汽重整反应的思想，主要从事新型吸附剂的制备及吸附动力学行为的研究、吸附/催化强化反应行为研究及反应系统一体化研究。目前主持国家自然科学基金项目1项，上海市自然科学基金项目1项。

近期论文

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Zhang Q, Han D, Liu Y, Ye Q, Zhu Z. Analysis of CO2 sorption/desorption kinetic behaviors and reaction mechanisms on Li4SiO4 [J]. AIChE J., 2013, 59: 901-911. Zhang Q, Xu J, Fan F, Sun D, Xu G, Zhang S, Zhu Z. Application of porous anodic alumina monolith catalyst in steam reforming of dimethyl ether: Cu/γ-Al2O3/Al catalyst degradation behaviors and catalytic activity improvement by pre-competition impregnation method [J]. Fuel Process. Technol., 2014, 119: 52-59. Zhang Q, Li T, Kameyama H,. Pt structured catalysts prepared using a novel competitive impregnation method for the catalytic combustion of propionic acid [J]. Catal.Commun.,2014,56: 27-31. Zhang Q, Sun D, Fan F, Zhang Q, Zhu Z. A novel monolith catalyst of plate-type anodic alumina for the hydrolysis of dimethyl ether [J]. Catal. Commun., 2013, 34: 64-68. Zhang Q, Fan F, Xu G, Ye D, Wang W, Zhu Z. Steam reforming of dimethyl ether over a novel anodic γ-Al2O3 supported copper bi-functional catalyst [J]. Int. J. Hydrogen Energy,2013,38: 10305-10314. Zhang Q, Jiang Z, Sun D, Han D, Zhu Z. Effect of crystalline state of anodized porous Al2O3/Al as supports by hydration [J]. J. Inorg. Mater., 2012, 27: 693-698. Zhang S, Zhang Q, Wang H, Ni Y, Zhu Z. Absorption behaviors study on doped Li4SiO4 under a humidified atmosphere with low CO2 concentration [J]. Int. J. Hydrogen Energy, In Press. Fan F, Zhang Q, Xu J, Ye Q, Kameyama H, Zhu Z. Catalytic behavior investigation of a novel anodized Al2O3/Al monolith in hydrolysis of dimethyl ether [J]. Catal. Today,2013, 216: 194-199. Zhang Q, Zhu X, Kameyama H. Numerical investigations on the development of compact plate Reformers: comparison of different assignments of reformers’ chambers [J]. AIChE J., 2008, 54(10): 2707-2716. Zhang Q, Takahashi H., Nagaya M, Kameyama H. Simulation and experimental analysis on the development of the co-axial cylinder methane steam reformer using the electrically heated alumite catalyst [J]. Int. J. Hydrogen Energy, 2007, 32(16):3870-3879. Zhang Q, Guo Y, Zhou L. Kameyma H. Dynamics simulations of a novel heat-exchange methane reformer using an electrically heated alumite catalyst [J].化学工学論文集,2008, 34(1): 113-118. Zhang Q, Guo Y, Zhou L, Kameyama H. Development of the methane steam reformer using an electrically heated alumite catalyst: Start-up performance investigated by the numerical and experimental analysis [J]. J. Chem. Eng. Japan, 2007, 40(6):487-496. Zhang Q, Sakurai M, Kameyama H. Performance simulations of a compact plate methane steam reformer using electrically heated alumite catalyst [J]. J. Chem. Eng. Japan, 2007, 40(4):319-328 . Zhou L, Guo Y, Zhang Q, Tran T. Sakurai M. Kameyama H. A novel catalyst with plate-type anodic alumina supports, Ni/NiAl2O4/γ-Al2O3/ alloy, for steam reforming of methane [J]. Applied Catalysis A, 2008, 347(2):200-207. Wang L, Zhang Q, Sakurai M. Kameyama H. Development of a Pt/TiO2 catalyst on an anodic alumite film for catalytic decomposition of formaldehyde at room temperature [J]. Catalysis Communications, 2007, 8(12):2171-2175.