曹贵平 - 华东理工大学

研究领域

1、催化剂工程。包括催化剂制备过程机制和工程，催化剂的微-介观结构，催化剂作用下的催化反应工程。 2、聚合物工程。包括新型聚合物的制备、高分子改性反应与方法(如PE、PVC、PS、PP，天然纤维素的物理-化学改性，提高其性能)、高分子材料的微-介观结构，聚合反应工程、高粘聚合体系的脱挥等。 3、工业化学反应器工程。实验室研究成果最终需要转化为实际生产应用，产生社会、经济效益。实验室研究所用的反应器尺寸很小，有的甚至是微型的。在实验室反应器中，过程传递等现象对反应结果的影响很小，甚至可以忽略。但在工业反应器中，物质的传递等工程放大因素往往非常明显，对反应结果往往带来不可忽视的影响。包括针对多样化的化学反应类型，研究反应器原理及其传递特性，研究新型的工业化学反应器，选择、优化、放大工业化学反应器等。如极快速反应工程与反应器、高粘体系反应工程与反应器、固相反应体系工程与反应器。 4、水处理与利用。包括各种工业废水、生活污水、海水淡化等与纯净水获得的相关处理方法和工程、处理过程的材料制备及其结构与性能、热力学和动力学问题等。 5、CO2化学与工程，包括CO2的吸收、捕集、物理-化学利用等。 6、计算化学工程。化学工程除实验研究外，计算研究是重要方法和手段，采用CFD方法研究各类反应器内不同物系的流动传递特征。采用分子模拟方法，研究反应的特征。采用过程模拟方法研究过程特征。

近期论文

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Ren-Han Zhang, Xue-Kun Li, Gui-Ping Cao *, Yun-Hai Shi, Hong-Lai Liu, Wei-Kang Yuan, Roberts George. An Improved Kinetic Model of Crystallization for Isotactic Polypropyl-ene Induced by supercritical CO2: Introducing Pressure and Temperature Dependence Avrami Equa-tion. Industrial & Engineering Chemistry Research. 2011, 50(18):10509–10515 SCI收录号：000294791000015；EI收录号：20113814345749. Yu-Na Hu, Hao-Yi Wang, Gui-Ping Cao*, Chen Meng, Wei-Kang Yuan. The Adsorption of Toluenediamine from the Wastewater by Activated Carbon in Batch and Fixed Bed Systems. Desalination, 2011, 279:54–60. DOI:10.1016/j.desal.2011.05.073. SCI收录号：000295604200006; EI收录号：20113614311208. Hao-Yi Wang, Yu-Na Hu, Gui-Ping Cao*, Wei-Kang Yuan. Degradation of Propylene Glycol Wastewater by Fenton’s Reagent in A Semi-continuous Reactor. Chemical Engineering Journal. 2011, 170:75 - 81, doi:10.1016/j.cej.2011.03.030. SCI收录号：000291454600011; EI收录号：20111913973030. Zhao-Yang Sun, Ming-Xing Shen, An-Wen Yang, Cong-Qiang Liang, Nan Wang, Gui-Ping Cao*. Introduction of β-Cyclodextrin into Polyaspartic Acid Matrix for Adsorption and Time-Release of Ibuprofen. Chemical Communications. 2011, 47 (3), 1072 – 1074 DOI:10.1039/C0CC03492D (IF=5.504). SCI收录号：000285515200071. Bao-Chuan Meng, Zhao-Yang Sun, Jin-Peng Ma, Hao-Yi Wang, and Gui-Ping Cao*. Selective Hydrodechlorination of CTFE over Palladium-supported Catalysrs: Activity and Deactivation. Catalysis Letters, (2010) 138:68–75. DOI: 10.1007/s10562-010-0370-8. SCI收录号：000279454300012; EI收录号：20102813066254 Zhao-Yang Sun, Ming-Xing Shen, Gui-Ping Cao*, Jie Deng, Yuan Liu, Tao Liu, Ling Zhao, Wei-Kang Yuan. Preparation of bimodal porous copolymer containing β-cyclodextrin and its inclusion adsorption behavior. Journal of Applied Polymer Science. 118(7):2176–2185 (2010), DOI 10.1002/app. SCI收录号：000281821100038; EI收录号： 20103713228437 Gui-Ping Cao*, Tao Liu, George W. Roberts. Predicting the Effect of Dissolved Carbon Dioxide on theGlass Transition Temperature of Poly(Acrylic Acid). Journal of Applied Polymer Science. 115(4):2136-2143(2010). SCI收录号：000272893400026; EI收录号：20100212634284. Hui Huang, Shao-Hong Wang, Shu-Jia Wang, Yu-Jie Wang, Xu-Dong Zhao, Gui-Ping Cao*, and Wei-Kang Yuan. Deactivation Mechanism of Cu/Zn Catalyst Poisoned by Organic Chlorides in Hydro-genation of Fatty Methyl Ester to Fatty Alcohol. Catalysis Letters, 134(3): 351 (2010). SCI收录号：000274615400023 Shu-Guang Zhu, Ning Zhang, Xiang Chen, Gui-Ping Cao*, and Wei-Kang Yuan. The Mechanism and Kinetics for Selective Oxidation of Glyoxal to Produce Glyoxalic Acid by Fenton’s Reacgent. Reaction Kinetics, Reac. Kinet. Mech. Cat, 99(2):325-333 (2010). SCI收录号：000277581700007; EI收录号：20103213127941. Hui Huang, Guiping Cao*, Chunling Fan, Shaohong Wang, Shujia Wang. Effects of Water on Cu/Zn Catalyst for Hydrogenation of Fatty Methyl Ester to Fatty Alcohol. The Korean Journal of Chemical Engineering, 26(6),1574-1579(2009). SCI收录号：000271507300022 Zhao-Yang Sun, Gui-Ping Cao*, Hui Lv, Ling Zhao, Tao Liu, Ludovic Montastruc, Nikov Iordan. Equilibrium of benzidine inclusion adsorption on cyclodextrin copolymer. Journal of Applied Polymer Science. Vol. 114(6): 3882–3888 (2009). SCI收录号：000270746000066 Xu, Xiaochun; Peng, Changjun; Cao, Gui-Ping; Liu, Honglai*; Hu, Ying. Application of a New Lattice Fluid Equation of State based on ChemicalAssociation Theory for Polymer Systems. Ind. Eng. Chem. Res. 2009, 48, 7828–7837. SCI收录号：000268797000040; EI收录号：20093612281466 陈力骅，曹贵平*，张人瀚，何峰，刘涛，赵玲，袁渭康，George W. Roberts. 超临界二氧化碳溶胀聚甲基丙烯酸甲酯的在线可视测量及热力学模拟计算. 化工学报. 2009，60(9):2351~2358. EI收录号：20093912342923 Bin Li, Guo Hua Hu, Gui Ping Cao, Tao Liu, Ling Zhao and Wei Kang Yuan*. Effect of supercr-itical carbon dioxide-assisted nano-scale dispersion of nucleating agents on the crystallization behavior and properties of polypropylene, Journal -of Supercritical Fluids, 44(3):446-456 (2008). SCI收录号：000255092300026 许震中, 曹贵平*, 宋亮, 袁向前, 张明华. 高温及络合稳定剂存在下水热晶化合成TS-2分子筛. 化工学报. 58(7):1828-1833(2007). EI收录号：20073110727052 Bin Li, Guo-Hua Hu, Gui-Ping Cao, Tao Liu, Ling Zhao, Wei-Kang Yuan*. Supercritical Carbon Dioxide-Assisted Dispersion of Sodium Benzoate in Polypropylene and crystallization Behavior of the Resul-ting Polypropylene. Journal of Applied Polymer Science, 102:3212–3220 (2006). SCI收录号：000241004000017; EI收录号：20083311461758 Wei-Xing Zhou*, Bin Li, Tao Liu, Gui-Ping Cao, Ling Zhao and Wei-Kang Yuan, Shape complexity and fractality of fracture surfaces of nucleating agents impregnated isotactic polypropylene swelled with supercritical carbon dioxide, Physic Review E, 73(1)11801 (2006). SCI收录号：000235008500071 LI Bin, CAO Gui-Ping, LIU Ting, LIU Tao, ZHAO Ling, YUAN Wei-Kang*. Preliminary Study on the Characteristics of Isotactic Polypropylene with Nucleating Agent Swollen by Supercritical Carbon Dioxide. Chinese Journal of Chemical Engineering. 13(5):673-677(2005). SCI收录号：000234384000016; EI收录号：2005529617418 Liu Tao, Hu Guo-hua, Tong Gang-sheng, Zhao Ling, Cao Gui-ping, Yuan Wei-kang*. Supercritical Carbon Dioxide Assisted Solid-State Grafting Process of Maleic Anhydride onto Polypropylene. Industrial & Engineering Chemistry Research, 44(12):4292-4299(2005). SCI收录号：000229791000017 Zhou Wei-xing, Li Bin, Liu Tao, Cao Gui-ping, Zhao Ling, Yuan Wei-kang*. Shape complexity and fractality of fracture surfaces of swelled isotactic polypropylene with supercritical