Vedernikov, Andrei - University of Maryland - Department of Chemistry & Biochemistry

个人简介

Doctor of Science degree, Department of Chemistry, Division of Organic Chemistry, Kazan State University (KSU), Russia, 2000 Ph.D. degree, Department of Chemistry, KSU, 1986 Graduate student, KSU, 1983-1986 M.S. degree, Summa cum Laude, KSU, 1983

研究领域

“Green” synthetic strategies: the use of O2 and H2O2 for selective C‑H and CC functionalization. Organotransition metal chemistry, experimental and computational (DFT). Organometallic reaction mechanisms. Homogeneous catalysis with transition metal complexes

近期论文

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Liu, W.-G.; Sberegaeva, A.V.; Nielsen, R.J.; Goddard, W.A. III, Vedernikov, A.N. "The Mechanism of O2 Activation and Methanol Production by (di(2-pyridyl)methanesulfonate)PtIIMe(OHn)(2-n)- Complex from Theory with Validation from Experiment", J. Am. Chem. Soc. 2014, 136, 2335-2341. Sberegaeva, A.V.; Liu, W.-G.; Nielsen, R.J.; Goddard, W.A. III, Vedernikov, A.V. "Mechanistic Study of the Oxidation of a Methyl Platinum(II) Complex with O2 in Water: PtIIMe–to–PtIVMe and PtIIMe–to–PtIVMe2 Reactivity", J. Am. Chem. Soc. 2014, 136, 4761-4768. Pal, S.; Zavalij, P.Y.; Vedernikov, A.N. "Oxidative C(sp3)-H Bond Cleavage, C-C and C=C Coupling at a Boron Center with O2 as Oxidant Mediated by Platinum(II)", Chem. Comm. 2014, 50, 5376-5378. Vedernikov, A.N. "Mechanism of the Kumada – Corriu Cross-Coupling Catalyzed by Low-Coordinate Bis-Amido Nickel Complexes: Identification of NiI, NiII and NiIII Catalytic Intermediates", ChemCatChem 2014, 6, 2490-2492. Oloo, W.N.; Zavalij, P.Y.; Vedernikov, A.N. "PdIV Monohydrocarbyls: Mechanistic Study of the Ligand-Enabled Oxidation of PdII Complexes with H2O2 in Water", Organometallics, 2013, 32, 5601-5614. Wang, D.; Zavalij, P.Y.; Vedernikov, A.N. "Aerobic C-H Acetoxylation of 8-Methylquinoline in PdII – Pyridinecarboxylic Acids Systems: Some Structure – Reactivity Relationships", Organometallics, 2013, 32, 4882- 4891. Dubinsky-Davidchik, I.S.; Goldberg, I.; Vigalok, A.; Vedernikov, A.N. "Unprecedented 1,3-migration of the aryl ligand in metallacyclic aryl -naphthyl Pt(IV) difluorides to produce -arylnaphthyl Pt(II) complexes", Chem. Comm. 2013, 49, 3446-3448. Vedernikov, A.N. "PdII/PdIV redox couple mediated C-X Bond Formation" In C-H and C-X Bond Functionalization. Transition Metal Mediation. RSC Publishing: 2013, 108-121. Dubinsky-Davidchik, I.S.; Potash, S.; Goldberg, I.; Vigalok, A.; Vedernikov, A.N. "Electrophilic Fluorination of Organoplatinum(II) Iodides: Iodine and Platinum Atoms As Competing Fluorination Sites", J. Am. Chem. Soc. 2012, 134, 14027-14032. Pal, S.; Vedernikov, A.N. "Oxidation of Dimethyldi(2-pyridyl)borato PtIIMen Complexes, n = 1, 0, with H2O2: Tandem B-to-Pt Methyl Group Migration and Formation of C-O Bond", Dalton Trans. 2012, 41, 8116-8122. Kocak, F.; Downing, D.; Zavalij, P.; Lam, Y.-F.; Vedernikov, A.; Eichhorn, B. "The Surprising Acid-Base and Ion- Sequestration Chemistry of Sn94-: HSn93-, Ni@HSn93- and the Sn93- Ion Revisited", J. Am. Chem. Soc. 2012, 134, 9733-9740. Vedernikov, A.N., "Direct Functionalization of M-C (M = PtII, PdII) Bonds Using Environmentally Benign Oxidants, O2 and H2O2", Acc. Chem. Res. 2012, 45, 803-813. Khusnutdinova, J.R.; Newman, L.; Vedernikov, A.N. "Selective and Efficient Oxidation of Ethylene to Ethylene Glycol Acetates with H2O2 Catalyzed by Pd(OAc)2 – Di(2-pyridiyl)ketone – Di(2-pyridyl)methanesulfonate System", J. Organomet. Chem. 2011, 696, 3998-4006. Khusnutdinova, J.R.; Zavalij, P.Y.; Vedernikov, A.N. "Allylic C-H Deprotonation of Olefins with PtII(OH) to Form 3- Allyl PtII Complexes in Water and Aprotic Organic Solvents", Organometallics 2011, 30, 3392-3399. Khusnutdinova, J.R.; Maiorana, A.S.; Zavalij, Vedernikov, A.N. "Stoichiometric Aerobic Aminohydroxylation of Ethylene Mediated by dpms – Platinum Complexes (dmps = di(2-pyridyl)methanesulfonate)", Inorg. Chim. Acta 2011, 369, 274-286.