邓桂胜 - 湖南师范大学 - 化学化工学院

研究领域

有机合成、金属有机化学、元素有机化学。目前主要从事Lewis酸调控的烯醇钛试剂的区域及立体选择性反应、有机活性中间体的合成及催化选择性反应、官能团化叶立德的合成及反应、有机铟化学等方面的研究。

近期论文

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Guisheng Deng, Xue Tian, Zaohui Qu and Jianbo Wang*, “Lewis Acids Controlled Regioseletive 1,2 and 1,4 Reaction of a,b-Unsaturated carbonyl Compounds with Ti (IV) Enolates Derived from a-Diazo-b-ketocarbonyl Compounds”, Angew. Chem. Int. Ed. Egl, 2002, 41(15), 2773-2776. Changqing Dong, Guisheng Deng, Jianbo Wang*, “New Approaches to Polysubstituted Pyrroles and g-Lactams Based on Nucleophilic Addition of Ti(IV) Enolates Derived from a-Diazo-b-keto Carbonyl Compounds to N-Tosylimines”, Journal of Organic Chemistry, 2006, 71(15), 5560-5564. Long Wu, Jia Zeng, Guisheng Deng, Fei Guo, Nan Li, Xiaojun Liu, Xiusheng Chu, Ding Li*, “Inactivation of Thiolase by 2-Alkynoyl-CoA via Its Intrinsic Isomerase Activity”, Organic Letters, 2007, 9(20), 3877-3880. Guisheng Deng*, Baihua Xu and Jianbo Wang, “A new method for the synthesis of 2-cyclopenten-1-one-5-carboxylic ester derivatives via Rh2(OAc)4-mediated intramolecular C-H insertion reaction of 4Z-b-vinyl-a-diazo b-ketoesters”, Tetrahedron, 2005, 61, 10811-10817. Guisheng Deng*, Baihua Xu and Chunyu Liu, “DMP-Mediated One-pot Oxidative Olefination of Silyl Ethers”, Tetrahedron, 2005, 61, 5818-5821. Guisheng Deng*, Honghua Mo, Jing Luo, Jingyuan Zou, “Highly diastereoselective Mannich-type reaction of titanium enolate derived from 2′-hydroxypropiophenone”, Canadian Journal of Chemistry, 2012, 90(6), 542-550. Guisheng Deng*, Jing Luo, “Silver(I)-Catalyzed Reaction of Terminal Alkynes with (Diacetoxyiodo)benzene: A Convenient, Efficient and Clean Preparation of a-Acetoxy Ketones”, Tetrahedron, 2013, 69(29), 5937-5944.